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The influence of compost on the growth of bean plants irrigated with As-contaminated waters and its influence on the mobility of As in the soils and the uptake of As (as NaAs(III)O2) by plant components was studied at various compost application rates (3·10(4) and 6·10(4) kg ha(-1)) and at three As concentrations (1, 2 and 3 mg kg(-1)). The biomass and As and P concentrations of the roots, shoots and beans were determined at harvest time, as well as the chlorophyll content of the leaves and nonspecific and specifically bound As in the soil. The bean plants exposed to As showed typical phytotoxicity symptoms; no plants however died over the study. The biomass of the bean plants increased with the increasing amounts of compost added to the soil, attributed to the phytonutritive capacity of compost. Biomass decreased with increasing As concentrations, however, the reduction in the biomass was significantly lower with the addition of compost, indicating that the As phytotoxicity was alleviated by the compost. For the same As concentration, the As content of the roots, shoots and beans decreased with increasing compost added compared to the Control. This is due to partial immobilization of the As by the organic functional groups on the compost, either directly or through cation bridging. Most of the As adsorbed by the bean plants accumulated in the roots, while a scant allocation of As occurred in the beans. Hence, the addition of compost to soils could be used as an effective means to limit As accumulation in crops from As-contaminated waters.

The influence of compost on the growth of bean plants irrigated with As-contaminated waters and its influence on the mobility of As in the soils and the uptake of As (as NaAs(III)O2) by plant components was studied at various compost application rates (3·10(4) and 6·10(4) kg ha(-1)) and at three As concentrations (1, 2 and 3 mg kg(-1)). The biomass and As and P concentrations of the roots, shoots and beans were determined at harvest time, as well as the chlorophyll content of the leaves and nonspecific and specifically bound As in the soil. The bean plants exposed to As showed typical phytotoxicity symptoms; no plants however died over the study. The biomass of the bean plants increased with the increasing amounts of compost added to the soil, attributed to the phytonutritive capacity of compost. Biomass decreased with increasing As concentrations, however, the reduction in the biomass was significantly lower with the addition of compost, indicating that the As phytotoxicity was alleviated by the compost. For the same As concentration, the As content of the roots, shoots and beans decreased with increasing compost added compared to the Control. This is due to partial immobilization of the As by the organic functional groups on the compost, either directly or through cation bridging. Most of the As adsorbed by the bean plants accumulated in the roots, while a scant allocation of As occurred in the beans. Hence, the addition of compost to soils could be used as an effective means to limit As accumulation in crops from As-contaminated waters.

Engineered cementitious composites (ECCs) are special types of fibre-reinforced cementitious composites (FRCC) with higher strain capacity which can be achieved with low fibre volume as low as 2% and total elimination of coarse aggregates. Due to the outstanding performance of ECCs, they are suitable for various construction and repair applications. However, in order for ECCs to achieve their properties; a high amount of binder which is primarily composed of Portland cement (PC) is used alongside a special type of ultrafine silica sand (USS) which is different from the conventional natural fine aggregates. The production of PC is known to be detrimental to the environment due to its high carbon dioxide emissions coupled with the high consumption of natural resources. Thus, the high use of PC content in ECCs posed a sustainability threat. Similarly, the USS used in ECCs are not readily available everywhere and are expensive. The processing of the USS coupled with its transportation over long distances would also increase the cost and embodied carbon of ECCs. Hence, in order to promote more development and applications of ECCs for various applications; this dissertation aims to provide innovative ways to improve the sustainability of ECCs and their performances. This dissertation offers four solutions to improve the sustainability of ECCs which are (i) use of unconventional industrial by-products as partial replacement of PC (ii) total replacement of PC in ECCs with alternative sustainable binders (iii) replacement of USS in ECCs with recycled materials and (iv) the use of supplementary cementitious materials to replace a high volume of PC. The findings from this study revealed sustainable ECCs with acceptable mechanical and durability performance can be achieved with the use of alternative binders or replacement of the conventional USS used in ECC mixtures. The sustainability and cost assessment of the ECCs indicated that the incorporation of industrial by-products such as blast furnace slag (BFS) especially at higher content is beneficial to reducing the negative environmental impact and economic burden associated with ECCs compared to the conventional ECC. The sustainability index and cost index of the ECCs further showed that the use of BFS is more beneficial when the sustainability and cost of the ECCs are compared with the corresponding performance. Similarly, the use of recycled materials as an alternative to USS was found to result in a significant reduction in the embodied carbon and cost of ECCs. The use of recycled materials such as expanded glass (EG) as aggregates in ECCs was also found to improve the thermal insulation properties of ECCs making such ECC suitable for the production of building envelope elements.

Engineered cementitious composites (ECCs) are special types of fibre-reinforced cementitious composites (FRCC) with higher strain capacity which can be achieved with low fibre volume as low as 2% and total elimination of coarse aggregates. Due to the outstanding performance of ECCs, they are suitable for various construction and repair applications. However, in order for ECCs to achieve their properties; a high amount of binder which is primarily composed of Portland cement (PC) is used alongside a special type of ultrafine silica sand (USS) which is different from the conventional natural fine aggregates. The production of PC is known to be detrimental to the environment due to its high carbon dioxide emissions coupled with the high consumption of natural resources. Thus, the high use of PC content in ECCs posed a sustainability threat. Similarly, the USS used in ECCs are not readily available everywhere and are expensive. The processing of the USS coupled with its transportation over long distances would also increase the cost and embodied carbon of ECCs. Hence, in order to promote more development and applications of ECCs for various applications; this dissertation aims to provide innovative ways to improve the sustainability of ECCs and their performances. This dissertation offers four solutions to improve the sustainability of ECCs which are (i) use of unconventional industrial by-products as partial replacement of PC (ii) total replacement of PC in ECCs with alternative sustainable binders (iii) replacement of USS in ECCs with recycled materials and (iv) the use of supplementary cementitious materials to replace a high volume of PC. The findings from this study revealed sustainable ECCs with acceptable mechanical and durability performance can be achieved with the use of alternative binders or replacement of the conventional USS used in ECC mixtures. The sustainability and cost assessment of the ECCs indicated that the incorporation of industrial by-products such as blast furnace slag (BFS) especially at higher content is beneficial to reducing the negative environmental impact and economic burden associated with ECCs compared to the conventional ECC. The sustainability index and cost index of the ECCs further showed that the use of BFS is more beneficial when the sustainability and cost of the ECCs are compared with the corresponding performance. Similarly, the use of recycled materials as an alternative to USS was found to result in a significant reduction in the embodied carbon and cost of ECCs. The use of recycled materials such as expanded glass (EG) as aggregates in ECCs was also found to improve the thermal insulation properties of ECCs making such ECC suitable for the production of building envelope elements.

<p>The non-perennial streams and rivers are predominant in the Mediterranean region and play an important ecological role in the ecosystem diversity in this region. This class of streams is particularly vulnerable to climate change effects that are expected to amplify further under most climatic projections. Understanding the potential response of the hydrologic regime attributes to climatic stress helps in planning better conservation and management strategies. Bouregreg watershed (BW) in Morocco, is a strategic watershed for the region with a developed non-perennial stream network, and with typical assets and challenges of most Mediterranean watersheds. In this study, a hybrid modeling approach, based on the Soil and Water Assessment Tool (SWAT) model and Indicator of Hydrologic Alteration (IHA) program, was used to simulate the response of BW's stream network to climate change during the period: 2035-2050. Downscaled daily climate data from the global circulation model CNRM-CM5 were used to force the hybrid modeling framework over the study area. Results showed that, under the changing climate, the magnitude of the alteration will be different across the stream network; however, almost the entire flow regime attributes will be affected. Under the RCP8.5 scenario, the average number of zero-flow days will rise up from 3 to 17.5 days per year in some streams, the timing of the maximum flow was calculated to occur earlier by 17 days than in baseline, and the timing of the minimal flow should occur later by 170 days in some streams. The used modeling approach in this study contributed in identifying the most vulnerable streams in the BW to climate change for potential prioritization in conservation plans.</p>

<p>The non-perennial streams and rivers are predominant in the Mediterranean region and play an important ecological role in the ecosystem diversity in this region. This class of streams is particularly vulnerable to climate change effects that are expected to amplify further under most climatic projections. Understanding the potential response of the hydrologic regime attributes to climatic stress helps in planning better conservation and management strategies. Bouregreg watershed (BW) in Morocco, is a strategic watershed for the region with a developed non-perennial stream network, and with typical assets and challenges of most Mediterranean watersheds. In this study, a hybrid modeling approach, based on the Soil and Water Assessment Tool (SWAT) model and Indicator of Hydrologic Alteration (IHA) program, was used to simulate the response of BW's stream network to climate change during the period: 2035-2050. Downscaled daily climate data from the global circulation model CNRM-CM5 were used to force the hybrid modeling framework over the study area. Results showed that, under the changing climate, the magnitude of the alteration will be different across the stream network; however, almost the entire flow regime attributes will be affected. Under the RCP8.5 scenario, the average number of zero-flow days will rise up from 3 to 17.5 days per year in some streams, the timing of the maximum flow was calculated to occur earlier by 17 days than in baseline, and the timing of the minimal flow should occur later by 170 days in some streams. The used modeling approach in this study contributed in identifying the most vulnerable streams in the BW to climate change for potential prioritization in conservation plans.</p>

The complexity of reality can be better represented by models able to involve uncertainty and time patterns. We present a general formulation of a stochastic dynamic multiobjective optimization model and we provide different solution concepts based on its transformation into different deterministic equivalent models. We provide two applications to sustainable decision making in portfolio management and optimal workforce allocation.

The complexity of reality can be better represented by models able to involve uncertainty and time patterns. We present a general formulation of a stochastic dynamic multiobjective optimization model and we provide different solution concepts based on its transformation into different deterministic equivalent models. We provide two applications to sustainable decision making in portfolio management and optimal workforce allocation.