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Abstract Additional experimental data concerning the kinetics of Ni-Mo codeposition were obtained by investigating cathodic polarization using a rotating disc electrode. The Ni-Mo alloys were deposited from an ammonium citrate bath. The alloy deposition was controlled by activation in the case of low values of the cathode potential and by diffusion in the case of higher values. The hydrogen discharge was found to be diffusion controlled. The inductive influence of nickel results in depolarization of the reduction of molybdenum which cannot be deposited separately. An increase in the disc rotation speed caused an increase in the maximum cathode efficiency and in the molybdenum content of the alloy.

Abstract Additional experimental data concerning the kinetics of Ni-Mo codeposition were obtained by investigating cathodic polarization using a rotating disc electrode. The Ni-Mo alloys were deposited from an ammonium citrate bath. The alloy deposition was controlled by activation in the case of low values of the cathode potential and by diffusion in the case of higher values. The hydrogen discharge was found to be diffusion controlled. The inductive influence of nickel results in depolarization of the reduction of molybdenum which cannot be deposited separately. An increase in the disc rotation speed caused an increase in the maximum cathode efficiency and in the molybdenum content of the alloy.

Abstract A CFD modelling study has been undertaken to examine the co-firing of pulverised coal and biomass with particular regard to the burnout of the larger diameter biomass particles. Computations were based on a research combustion facility that replicates an industrial coal-fired power station. Three percent, by mass, of pinewood was blended with a bituminous UK coal, and the effects of the wood particle size and shape on the burnout of the combined wood and coal char were investigated. The effect of varying the devolatilisation and char combustion rate constants for the biomass component in the blend was also investigated. It was concluded that the combustion of small (200 μm) wood particles was rapid but the rate of combustion of larger particles was dependent on their composition, size, and shape.

Abstract A CFD modelling study has been undertaken to examine the co-firing of pulverised coal and biomass with particular regard to the burnout of the larger diameter biomass particles. Computations were based on a research combustion facility that replicates an industrial coal-fired power station. Three percent, by mass, of pinewood was blended with a bituminous UK coal, and the effects of the wood particle size and shape on the burnout of the combined wood and coal char were investigated. The effect of varying the devolatilisation and char combustion rate constants for the biomass component in the blend was also investigated. It was concluded that the combustion of small (200 μm) wood particles was rapid but the rate of combustion of larger particles was dependent on their composition, size, and shape.

The Severn Estuary has the world's second largest tide range and a barrage across the estuary, located just seawards of Cardiff in Wales and Weston in the South West England, has been proposed for over half a century, with the objective of extracting large amounts of tidal energy. A Severn Barrage, as previously proposed by the Severn Tidal Power Group (STPG), would be the largest renewable energy project for tidal power generation in the world, if built as proposed, and would generate approximately 5% of the UK's electricity needs. However, concerns have been raised over the environmental impacts of such a barrage, including potential increase in flood risk, loss of intertidal habitats etc. In addressing the challenges of maximizing the energy output and minimizing the environmental impacts of such a barrage, this research study has focused on using a Continental Shelf model, based on the modified Environmental Fluid Dynamics Code (EFDC) with a barrage operation module (EFDC_B), to investigate both the far and near field hydrodynamic impacts of a barrage for different operating scenarios. Three scenarios have been considered to simulate the Severn Barrage, operating via two-way generation and using different combinations of turbines and sluices. The first scenario consisted of 216 turbines and 166 sluices installed along the barrage; the second consisted of 382 turbines with no sluices; and the third consisted of 764 turbines and no sluices. The specification of the sluice gates and turbines are the same for all scenarios. The model results indicate that the third scenario has the best mitigating effects for the far-field and near-field flood risks caused by a barrage and produces the most similar results of minimum water depth and maximum velocity distributions to those obtained from simulating the natural conditions of the estuary, i.e. the current conditions. The results also show that the flow patterns around the barrage are closest to those for the existing natural conditions with minimal slight changes in the estuary. Thus, the results clearly indicate that the environmental impacts of a Severn Barrage can be minimized if the barrage is operated for two-way generation and under the third scenario. Although it appears that the energy output for the third scenario is less than that obtained for the other two scenarios, if very low head (VLH) turbines are used, then the third scenario could generate more energy as more turbines could be cited along the barrage structure. Therefore, the study shows that a Severn Barrage, operating in two-way generation and with 764 turbines (ideally VLH turbines), would be the best option to meet the needs of maximizing the energy output, but having a minimal impact on environmental changes in the estuary and far-field.

The Severn Estuary has the world's second largest tide range and a barrage across the estuary, located just seawards of Cardiff in Wales and Weston in the South West England, has been proposed for over half a century, with the objective of extracting large amounts of tidal energy. A Severn Barrage, as previously proposed by the Severn Tidal Power Group (STPG), would be the largest renewable energy project for tidal power generation in the world, if built as proposed, and would generate approximately 5% of the UK's electricity needs. However, concerns have been raised over the environmental impacts of such a barrage, including potential increase in flood risk, loss of intertidal habitats etc. In addressing the challenges of maximizing the energy output and minimizing the environmental impacts of such a barrage, this research study has focused on using a Continental Shelf model, based on the modified Environmental Fluid Dynamics Code (EFDC) with a barrage operation module (EFDC_B), to investigate both the far and near field hydrodynamic impacts of a barrage for different operating scenarios. Three scenarios have been considered to simulate the Severn Barrage, operating via two-way generation and using different combinations of turbines and sluices. The first scenario consisted of 216 turbines and 166 sluices installed along the barrage; the second consisted of 382 turbines with no sluices; and the third consisted of 764 turbines and no sluices. The specification of the sluice gates and turbines are the same for all scenarios. The model results indicate that the third scenario has the best mitigating effects for the far-field and near-field flood risks caused by a barrage and produces the most similar results of minimum water depth and maximum velocity distributions to those obtained from simulating the natural conditions of the estuary, i.e. the current conditions. The results also show that the flow patterns around the barrage are closest to those for the existing natural conditions with minimal slight changes in the estuary. Thus, the results clearly indicate that the environmental impacts of a Severn Barrage can be minimized if the barrage is operated for two-way generation and under the third scenario. Although it appears that the energy output for the third scenario is less than that obtained for the other two scenarios, if very low head (VLH) turbines are used, then the third scenario could generate more energy as more turbines could be cited along the barrage structure. Therefore, the study shows that a Severn Barrage, operating in two-way generation and with 764 turbines (ideally VLH turbines), would be the best option to meet the needs of maximizing the energy output, but having a minimal impact on environmental changes in the estuary and far-field.

Abstract In this work, we intend to solve the equations governing two laminar isothermal or non-isothermal coaxial plane jets with variable density in an ambient fluid at rest in order to study the initial conditions influence (i.e. the nozzles ejection conditions) on the jet characteristic parameters. A finite difference method is developed to solve the dimensionless Navier–Stokes and energy equations resulting from some assumptions. The discussion about the results relates primarily to the concentration core length according to the nozzles thicknesses ratios. The influences of the gas velocity and temperature resulting from the external nozzle are also examined. This made it possible to deduce correlations of practical use between these parameters in order to apply them in engineering processes.

Abstract In this work, we intend to solve the equations governing two laminar isothermal or non-isothermal coaxial plane jets with variable density in an ambient fluid at rest in order to study the initial conditions influence (i.e. the nozzles ejection conditions) on the jet characteristic parameters. A finite difference method is developed to solve the dimensionless Navier–Stokes and energy equations resulting from some assumptions. The discussion about the results relates primarily to the concentration core length according to the nozzles thicknesses ratios. The influences of the gas velocity and temperature resulting from the external nozzle are also examined. This made it possible to deduce correlations of practical use between these parameters in order to apply them in engineering processes.

Abstract The rapid increase in energy demand and the limited resources of fossil fuel as well as the environmentally damaging effects, drive the world to find new options for sustainable electricity generation, which is represented by renewable energies. Concentrating solar power (CSP) is one of the most promising technologies in the field of electricity generation to tackle this issue with a competitive cost in the future. This paper presents an investigation of the potential of implementation of CSP plants in Libya. The socio-economic context, current energy situation of the country and different types of CSP plants are discussed. Moreover, an assessment of site parameters required for CSP plants including solar resources, land use and topography, water resources and grid connections are investigated in detail. In addition, thermo-economic simulation of a 50 MW parabolic trough power plant is performed. The simulation is conducted based on meteorological data measured by the weather station installed at the Centre for Solar Energy Research and Studies (CSERS) in Tajoura city. The performance results are compared with the reference plant Andasol-1 in Spain. Even though the proposed plant is located on the North coast where solar resources are at their minimum compared with other regions of the country, the outcome of the study proves that Libya is not only suitable but it can be economically competitive in the implementation of CSP technology.