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Societal relations in rural areas have entered into a new stage of adjustment over the past decade. However, the adjustment, which might bring about profound societal changes in countryside as well as in China as a whole, have not been paid much attention and very few studies have been conducted from the perspective of ecological resource crises. We use the case of a village as an example to show how water pollution, as one of the contributory factors, possibly affect the transition of clans and societal changes in Chinese villages. Through observation and interviews, we find that there is an apparent rise of “New Clanism” within clans, which gradually abandons the tradition of supremacy of clan interests and places family or individual interests at top priority. We also find that clan boundaries get increasingly obscure since the integrity of clans is undermined by the rise of new interest groups across clans, but the boundaries remain relatively clear due to the consistency (albeit incomplete) of clan interests. Some new clan élites and representatives of new interest groups get involved in village governance, which indicates that their goals have shifted from natural resources to social or political capital. The significance of our findings is that they provide not only a unique perspective for the interaction between society and resources, but also some new ideas for the future study of rural China at the environment-social interface.

The decarbonisation of heating in the United Kingdom is likely to entail both the mass adoption of heat pumps and widespread development of district heating infrastructure. Estimation of the spatially disaggregated heat demand is needed for both electrical distribution network with electrified heating and for the development of district heating. The temporal variation of heat demand is important when considering the operation of district heating, thermal energy storage and electrical grid storage. The difference between the national and urban heat demands profiles will vary due to the type and occupancy of buildings leading to temporal variations which have not been widely surveyed. This paper develops a high-resolution spatiotemporal heat load model for Great Britain (GB: England, Scotland a Wales) by identifying the appropriate datasets, archetype segmentation and characterisation for the domestic and nondomestic building stock. This is applied to a thermal model and calibrated on the local scale using gas consumption statistics. The annual GB heat demand was in close agreement with other estimates and the peak demand was 219 GWth. The urban heat demand was found to have a lower peak to trough ratio than the average national demand profile. This will have important implications for the uptake of heating technologies and design of district heating.

SummaryInequality has recently become a major concern in economics. Leaving aside its social and economic effects is also possible to trace its environmental consequences, which this article attempts to assess. The indicator to be measured is the household's carbon footprint (CF) for different social groups. The deep economic crisis in the Spanish economy between 2008 and 2013 has increased consumption inequality and doubled the number of households below the poverty line. When focusing on domestic consumption, we found that the shopping basket of all income groups has very similar emissions intensities; therefore, the differences among the household CFs depend mainly on the scale effect (i.e., the size of consumption). However, when international trade is also considered, we found that the emission intensity of imports is bigger than the intensity of all the respective domestic goods. Therefore, the share of imported goods and services by social class will be an important determinant of the respective total CF. Before the crisis, households with higher incomes imported 30% of their total consumption items whereas households with lower income imported only 20% of their consumption. During the crisis, the imports of medium‐high‐income households fell to 20%, whereas low‐ and middle‐income families maintained the same import share, which contributed to the reduction of the total household CF.

Nowadays, the issues related with environment preservation assume an increasing importance. Progressively, more sustainable solutions/techniques are being developed to combat environmental destruction. The decision to include themes related to the environment in the curriculum of technological courses in higher education aims to promote more sustainable behaviors and in an indirect way, increase the environmental literacy of the population. Thus, this study aims to evaluate the environmental literacy focusing on four topics, i.e., air pollution, water pollution, global warming, and energy resources. For this purpose, a questionnaire was developed and applied to a convenience sample, formed by individuals of both genders, aged between 20 and 81 years old. The questionnaire intended to collect data to characterize the sample and assess the literacy regarding environmental issues. In order to carry out the environmental literacy assessment, the respondents were asked to express their degree of agreement with some statements related with the environmental themes mentioned above. The data collected was analyzed using data mining tools. The results suggest that the population’s literacy is satisfactory in relation to some issues, but insufficient in relation to others, equally important, but less disseminated.

The oxidation of water is essential to the sustainable production of fuels using sunlight or electricity, but designing active, stable and earth-abundant catalysts for the reaction is challenging. Now, a complex containing five iron atoms is shown to efficiently oxidize water by mimicking key features of the oxygen-evolving complex in green plants.

The chemical characteristics of mine tailings, organic amendments (doses), and plants are the critical factors that must be evaluated and monitored to ensure the sustainability of phytostabilization. The aim of this study was to evaluate the mobility of copper (Cu) in mine tailings (MT) of the Zone Central of Chile to which commercial humic substances were added, examining their effect on the uptake of Atriplex halimus. Two commercial humic substances (HS1 and HS2) extracted from leonardite (highly oxidized lignite), of different pH and total organic carbon, were evaluated by adsorption curve for Cu. In columns, soluble Cu, pH, and electrical conductivity in leachates were evaluated for MT, MT + HS1, and MT + HS2, and HS1 and HS2 in doses of 120 mg kg-1. In pot assay, seeds were germinated directly in MT and cultivated for 140 days with the addition of HS2 in 120 and 240 mg kg-1. Mine tailing presents high concentration of Cu (2016 ± 223 mg kg-1, pH 6.3 ± 0.1). The results of sequential extraction indicate that Cu is associated with the sulfide fraction of low risk of mobility. The amount of Cu sorbed by HS1 was higher than that sorbed by HS2, and both humic substances showing better fit to the Freundlich than Langmuir model. Lixiviation of Cu was significantly lower in MT + HS1 (0.166 ± 0.043 mg kg-1) and MT + HS2 (0.157 ± 0.018 mg kg-1) than in MT (0.251 ± 0.052 mg kg-1). Copper concentration in plants reached 185.8 ± 37.8 mg kg-1 in the roots and 32.6 ± 7.4 mg kg-1 in the aerial parts cultivated in MT without effect of the humic substance addition in Cu uptake nor growth. Copper concentrations in the aerial parts were adjusted to sufficient or normal levels in plant. A good management of mine tailings through phytostabilization could consider an adequate mixture of humic substances (to avoid leaching of metals) and an organic amendment that provides essential nutrients and increases biomass generation.

AbstractSolar fuels offer a promising approach to provide sustainable fuels by harnessing sunlight1,2. Following a decade of advancement, Cu2O photocathodes are capable of delivering a performance comparable to that of photoelectrodes with established photovoltaic materials3–5. However, considerable bulk charge carrier recombination that is poorly understood still limits further advances in performance6. Here we demonstrate performance of Cu2O photocathodes beyond the state-of-the-art by exploiting a new conceptual understanding of carrier recombination and transport in single-crystal Cu2O thin films. Using ambient liquid-phase epitaxy, we present a new method to grow single-crystal Cu2O samples with three crystal orientations. Broadband femtosecond transient reflection spectroscopy measurements were used to quantify anisotropic optoelectronic properties, through which the carrier mobility along the [111] direction was found to be an order of magnitude higher than those along other orientations. Driven by these findings, we developed a polycrystalline Cu2O photocathode with an extraordinarily pure (111) orientation and (111) terminating facets using a simple and low-cost method, which delivers 7 mA cm−2 current density (more than 70% improvement compared to that of state-of-the-art electrodeposited devices) at 0.5 V versus a reversible hydrogen electrode under air mass 1.5 G illumination, and stable operation over at least 120 h.

There is a widely believed myth that replacing the use of fossil fuels largely by renewable forms of energy is, with a possible exception of nuclear power, critically dependent on the development of appropriate new technologies. Accordingly, it is held that decarbonizing straight away is particularly difficult and expensive. There was a time when this idea had an element of reality, but this is no longer the case. Unfortunately, belief in this myth is shared by those in positions of influence. This paper serves to document that this presumed reality no longer holds, although the misconception may have been based on fact in the past. Whilst the survey of the available technology offered concentrates on electricity supply, it also documents that manufacture of synthetic fuels via hydrogen obtained by electrolysis of water and CO2 integrates smoothly with electricity grid stabilization as well as reducing the CO2 content of the atmosphere. The likely price and cost development in the energy market is also reviewed. In addition the role of CCS, in practice mainly capture from the air and industrial processes other than power generation is reviewed against the background of the cost effective generation of electricity by harvesting renewable forms of energy.