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Nordhaus (1973) has in his seminal contribution addressed two emerging questions in the field of energy economics. First, how do current market prices of natural resources reflect true scarcity fro...

Abstract Water transport control is the major issue of direct methanol fuel cell. High water flow rates through the fuel cell imply extra water feeding at the anode and flooding at the cathode. In the present work, water transport and flooding in the direct methanol fuel cell are investigated through both experimental and modeling analyses and an interpretation of such phenomena is proposed. The model is validated on the experimental data of two different fuel cells in an extensive range of operating conditions. The analysis elucidates that water transport through the cathode diffusion layer is determined by vapor diffusion, slightly affected by current density, and by liquid water permeation proportional to current density, that occurs when liquid pressure in the electrode exceeds a threshold value. To simulate the effects of cathode diffusion layer flooding two mechanisms must be considered simultaneously: superficial pore obstruction, proportional to liquid water concentration in cathode channel, and bulk pore obstruction, proportional to liquid water permeation. The modeling analysis proposes the correlations to reproduce the effects of cathode flooding and permits to discuss the onset and magnitude of such phenomenon and the influence of micro-porous layer.

A systematic resilience and flexibility analysis of future power systems to address the impacts of climate change and Renewable Energy penetration is becoming increasingly important, as it is expected to have a great effect on the demand and supply portfolios. Depending on the intrinsic characteristics of each power system, different aspects have to be considered in the analysis since this cannot be universal for all power systems. To highlight this, the paper presents two different case studies pertaining to the Great Britain and Cyprus networks respectively. Firstly, the resilience of the Great Britain transmission network to future demand and supply scenarios (2020, 2030 and 2050) is evaluated using a reduced version of the current Great Britain transmission network. Subsequently, the future flexibility requirements of the isolated network of Cyprus are appropriately benchmarked against future energy mix scenarios that involve conventional generation and renewable energy penetration.

The reclosing time of a transmission line has a distinct influence on system stability. A new method of calculating the optimal reclosing time based on the transient energy function (TEF) is presented in this paper. It has been shown that an optimal reclosing time can be used to set the autoreclosing device so that the system stability or power-transfer capability can be significantly improved. Though power-system TEF is based on classical models, the results from simulation studies of a real system (46 generators and 230 buses) with complex models show that the optimal reclosing time calculated using TEF can be used effectively.

Progress is reported on understanding the interfacial processes that influence the surface treatment and finishing of aluminium and its alloys for practical application, i.e. in the aerospace sector. Using model and commercial alloys, the effects of alloying elements in the matrix and as separate phases on the anodising behaviour may be separated. The insight gained enables informed control of the anodizing conditions for the tailoring of porous anodic film growth in environmentally-friendly electrolytes for protection of the aerospace alloy substrate; further outer, open pore morphologies may also be readily developed for adhesive bonding applications, whilst maintaining protection of the alloy. Progressing further, anodizing conditions have been developed that offer the required control, but with much reduced energy costs and carbon footprint; the previous have been assisted by rapid screening using electrochemical approaches.

The rotary regenerator (also called the heat wheel) is an important component of energy intensive sectors, which is used in many heat recovery systems. In this paper, a model-based analysis of a rotary regenerator is carried out with a major emphasis given to the development and implementation of mathematical models for the thermal analysis of the fluid and wheel matrix. The effect of heat conduction in the direction of the fluid flow is taken into account and the influence of variations in rotating speed of the wheel as well as other characteristics (ambient temperature, airflow and geometric size) on dynamic responses are analysed. The numerical results are compared with experimental measurements and with theoretical predications of energy efficiencies. (c) 2005 Elsevier B.V. All rights reserved.

AbstractNitrous oxide (N2O) is a potent greenhouse gas and causes stratospheric ozone depletion. While the emissions of N2O from soil are widely recognized, recent research has shown that terrestrial plants may also emit N2O from their leaves under controlled laboratory conditions. However, it is unclear whether foliar N2O emissions are universal across varying plant taxa, what the global significance of foliar N2O emissions is, and how the foliage produces N2O in situ. Here we investigated the abilities of 25 common plant taxa, including trees, shrubs and herbs, to emit N2O under in situ conditions. Using 15N isotopic labeling, we demonstrated that the foliage‐emitted N2O was predominantly derived from nitrate. Moreover, by selectively injecting biocide in conjunction with the isolating and back‐inoculating of endophytes, we demonstrated that the foliar N2O emissions were driven by endophytic bacteria. The seasonal N2O emission rates ranged from 3.2 to 9.2 ng N2O–N g−1 dried foliage h−1. Extrapolating these emission rates to global foliar biomass and plant N uptake, we estimated global foliar N2O emission to be 1.21 and 1.01 Tg N2O–N year−1, respectively. These estimates account for 6%–7% of the current global annual N2O emission of 17 Tg N2O–N year−1, indicating that in situ foliar N2O emission is a universal process for terrestrial plants and contributes significantly to the global N2O inventory. This finding highlights the importance of measuring foliar N2O emissions in future studies to enable the accurate assigning of mechanisms and the development of effective mitigation.