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Atmospheric methane (CH4) is a potent greenhouse gas, and its mole fraction has more than doubled since the preindustrial era. Fossil fuel extraction and use are among the largest anthropogenic sources of CH4 emissions, but the precise magnitude of these contributions is a subject of debate. Carbon-14 in CH4 (14CH4) can be used to distinguish between fossil (14C-free) CH4 emissions and contemporaneous biogenic sources; however, poorly constrained direct 14CH4 emissions from nuclear reactors have complicated this approach since the middle of the 20th century. Moreover, the partitioning of total fossil CH4 emissions (presently 172 to 195 teragrams CH4 per year) between anthropogenic and natural geological sources (such as seeps and mud volcanoes) is under debate; emission inventories suggest that the latter account for about 40 to 60 teragrams CH4 per year. Geological emissions were less than 15.4 teragrams CH4 per year at the end of the Pleistocene, about 11,600 years ago, but that period is an imperfect analogue for present-day emissions owing to the large terrestrial ice sheet cover, lower sea level and extensive permafrost. Here we use preindustrial-era ice core 14CH4 measurements to show that natural geological CH4 emissions to the atmosphere were about 1.6 teragrams CH4 per year, with a maximum of 5.4 teragrams CH4 per year (95 per cent confidence limit)—an order of magnitude lower than the currently used estimates. This result indicates that anthropogenic fossil CH4 emissions are underestimated by about 38 to 58 teragrams CH4 per year, or about 25 to 40 per cent of recent estimates. Our record highlights the human impact on the atmosphere and climate, provides a firm target for inventories of the global CH4 budget, and will help to inform strategies for targeted emission reductions.

Anode with good electrocatalytic capabilities is more specifically required to reduce the ohimic losses during microbial fuel cell (MFC) operation. Highly conductive polymers viz., Polyaniline (PANi) and Polyaniline/Carbon nanotube (PANi/CNT) composite were prepared by in situ oxidative chemical polymerization method. Anodes were fabricated independently by coating PANi and CNT/PANi composites on the surface of SSM. The fabricated electrodes were evaluated as anode against stainless steel mess (SSM) as cathode during MFC operation. Maximum bioelectricity generation was observed in SSM-PANi/CNT-anode with power density of 48 mW/m2 and COD removal efficiency of 80% compared with SSM-PANi-anode (38 mW/m2; 65%) and SSM-anode (28 mW/m2; 58%). Bioelectrochemical characterization of the electrode materials using cyclic voltammetry and electrochemical impedance spectroscopy showed high electrocatalytic activity of PANi/CNT composite electrode. The study concluded the efficiency of PANi/CNT composite electrodes as bioanode in operation of MFCs towards achieving increased bioelectricity production along with wastewater treatment.

AbstractThis paper presents an experimental assessment of a blended fatigue‐extreme controller for load control employing trailing edge flaps on a lab‐scale wind turbine. The controller blends between a repetitive model predictive controller that targets fatigue loads and a dedicated extreme load controller, which consists of a simple on‐off load control strategy. The Fatigue controller uses the flapwise blade root bending moments of the three blades as input sensors. The Extreme controller additionally uses on‐blade angle of attack and velocity measurements as well as acceleration measurements to detect extreme events and to allow for a fast reaction. The experiments are conducted on the Berlin Research Turbine within the large wind tunnel of the TU Berlin. In order to reproduce test cases with deterministic extreme wind conditions that follow industry standards, the wind tunnel was redesigned. The analyzed test cases are extreme direction change, extreme coherent gust, extreme operating gust and extreme coherent gust with direction change. The test cases are analyzed by on‐blade angle of attack and velocity measurements. The load control performance of the Blended controller is compared to the pure fatigue oriented and the pure extreme load controller. The Blended controller achieves a maximum flapwise blade root bending moment reduction of 23%, which is comparable to the reduction achieved by the Extreme controller.

This review presents recent advancements in high-voltage rechargeable aqueous batteries employing water-in-salt and modified water-in-salt electrolytes.

In the search for a nontoxic replacement of the commonly employed CdS buffer layer for Cu(In,Ga)(S,Se) $_\mathrm{2}$ based solar cells, chemically deposited Zn(O,S) thin films are a most promising choice. In this paper, we address the usually slow deposition speed of Zn(O,S) in a newly developed ammonia-free chemical bath process, resulting in a deposition of 30 nm in 3 min with good homogeneity on 30 cm × 30 cm sized substrates. Solar cells with buffer layers prepared from this process match the efficiency of CdS reference cells. In a second step, we address the light-soaking post-treatment, still needed for maximum efficiencies. By addition of aluminum to the deposition process, the initial efficiencies can be increased slightly. With the addition of boron, the light-soaking post-treatment is rendered unnecessary, while maintaining high efficiencies above 15%, surpassing reference cells with CdS buffer.

With respect to the ecological relevance of endpoints, biomass as an endpoint might be promising regarding ecotoxicological assessments of benthic communities. In a freshwater microcosm study the effect of two cadmium (Cd) concentrations (50 and 400 mg Cd kg(-1) dw) on biomass and abundance of a benthic community were investigated over a period of seven months. Specifically, the sensitivity of both endpoints in distinguishing differential effects was compared. While bacteria were found to be unaffected by Cd, abundance and biomass of protozoans and metazoans decreased. In a short-term comparison, differences between control and Cd treatments were, overall, more pronounced for flagellate biomass and for metazoan abundance with strong differences between the taxonomic groups; furthermore, over the long-term, the differences among organisms and endpoints changed. Based on toxicant sensitivity, the reasonably low variance of the data and the workload involved, biomass can provide a useful additional endpoint in microcosm studies.

AbstractMononuclear trivalent lanthanide complexes with formula [Ln(L)(NO3)3] [in which L=4,4‐difluoro‐8‐(2′:2′′;6′′:2′′′‐terpyridin‐4′′‐yl)‐1,3,5,7‐tetramethyl‐2,6‐diethyl‐4‐bora‐3a,4a‐diaza‐s‐indacene (Boditerpy)] are reported for Ln=Yb, Nd, Er, La and Gd. According to the crystal structure of the Yb complex, the lanthanide ion is bound to the terdentate terpyridine and the inner coordination sphere of the nine‐coordinate lanthanide ion is completed by three bidentate nitrate anions. The coordination polyhedron can be described as a distorted tricapped antiprism. The terpyridine chelate is almost planar and tilted by nearly 60° from the indacene subunit. FT‐IR spectra confirm the bidentate binding mode of the nitrate anions for the other complexes. NMR and ES‐MS spectra (through characteristic isotopic patterns) confirm the chemical formulation. The complexes have high molar absorption coefficients in the visible spectral region (65 000 M−1 cm−1 at 529 nm) and display sizeable NIR luminescence (900 to 1600 nm, for Ln=Yb, Nd and Er), upon irradiation through the electronic state of the indacene moiety at 514 nm. Crystal‐field splitting was analysed at low temperature. The quantum yield of the Yb solution (10−4 M) in dichloromethane amounts to 0.31 %, corresponding to a sensitisation efficacy of the ligand of ca. 63 %.

AbstractThis study was conducted to address algal toxins using potassium permanganate through the control of biomass growth of algae under following conditions value 25±1 °C illumination intensity value 245microeinstein/m2/s, using the culture media Chu-10 Modified for the purpose of development algae. We treated algal toxins belonging to groups of Neurotoxins, Hepatotoxins, Pyriproxyfen, Emodin, Brevetoxins-10 (A) and Cytotoxins using concentrations of potassium permanganate represented by 2, 4, 8 and 16mg/l with alum concentration for each concentration of 30mg/l, as the removal rate reached to 100% of the toxin blooms in concentrations of 8 and 16mg/l respectively, through the examination of algal toxins mediated by GC–MASS compared to the standard, which diagnosed a range of algal toxins with C2H3C12NO formulas of synthetic C9H13NO2, C18H27NO3, C11H12N2O6, C11H17N3O, C10H17N3O, C9H15Br2NO, CH4N2O2, C11H17NO2, C13H9BrN2O3, C3H7NO4S, C20H29NO3, C15H10O5, C4H8O2 and C2H2Cl3NO the concentrations 2 and 4mg/l turned toxic compounds into non-toxic compounds represented by C7H6O2, C5H6N2O, C12H11ClO4, C6H6O2, C12H10O4, C10H17N, C4H6O2 and C5H6N2O. The results showed reduced primary productivity of algae chlorophyll a result of substance to stop chloroplast for vital activity through the influence of the concentration of potassium permanganate values 0.571, 1.142, 0.583 and 1.713mg/l respectively, compared to the standard of 114.2mg/l. As diagnosed types of Algae producing toxins are represented by Microcystis aeruginosa, Microcystis flosaquae, Oscillatoria amoena, Oscillatoria amphibian, Oscillatoria boryana, Oscillatoria limnetica, Oscillatoria perornata, Phormidium ambiguum, Lyngbya digueti, Lyngbya major, Lyngbya nordgaadii, Lyngbya spirulinoides, Nostoc carneum, Nostoc spongiforme, Anabaena augstumalis, Chroococcus indicus and Chroococcus minor, as the dry weight of live Algae producing toxins is 17.342g/l.