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This paper examines the hypothesis that there is a single economic market for the international steam coal industry and investigates the degree of steam coal market integration over time. A regression test of convergence is employed to test for group convergence within a panel of steam coal exporting countries. The long-run relations between international steam coal prices are tested through cointegration analysis and the Kalman Filter analysis is employed to examine the convergence path of the price series. Monthly Free on Board (F.O.B.) prices for Australia, China, Colombia, Indonesia, Poland and South Africa between January 1995 and July 2007 are used. Considering the outcomes of the three econometric techniques as a whole, we conclude that the international steam coal market is generally integrated.

It is now recognized that analytical chemistry must also be a target for green principles, in particular chromatographic methods which typically use relatively large volumes of hazardous organic solvents. More generally, high performance liquid chromatography (HPLC) is employed routinely for quality control of complex mixtures in various industries. Acetonitrile and methanol are the most commonly used organic solvents in HPLC, but they generate an impact on the environment and can have a negative effect on the health of analysts. Ethanol offers an exciting alternative as a less toxic, biodegradable solvent for HPLC. In this work we demonstrate that replacement of acetonitrile with ethanol as the organic modifier for HPLC can be achieved without significantly compromising analytical performance. This general approach is demonstrated through the specific example analysis of a complex plant extract. A benchmark method employing acetonitrile for the analysis of Bidens pilosa extract was statistically optimized using the Green Chromatographic Fingerprinting Response (GCFR) which includes factors relating to separation performance and environmental parameters. Methods employing ethanol at 30 and 80°C were developed and compared with the reference method regarding their performance of separation (GCFR) as well as by a new metric, Comprehensive Metric to Compare Liquid Chromatography Methods (CM). The fingerprint with ethanol at 80°C was similar to or better than that with MeCN according to GCFR and CM. This demonstrates that temperature may be used to replace harmful solvents with greener ones in HPLC, including for solvents with significantly different physiochemical properties and without loss in separation performance. This work offers a general approach for the chromatographic analysis of complex samples without compromising green analytical chemistry principles.

Low-salinity water injection emerges to be a cost-effective and environmentally friendly enhanced oil recovery technique. Furthermore, additives, such as the surfactant and nanoparticles in combina...

Abstract This paper aims to present a feasibility study of the innovative plant for methanol synthesis from carbon dioxide-sequestered by fossil fuel power plant and hydrogen, which is produced by water electrolyzer employing the over-production on the electrical grid. The thermo-economic analysis is performed in the framework of the MefCO2 H2020 EU project and it is referred to the German economic scenario, properly taking into account the real market costs and cost functions for different components of the plant. Three different plant capacities for methanol production (4000 10,000 and 50,000 ton/year) have been investigated, assuming an average cost for electrical energy to feed electrolysers and analyzing the influence of the most significant parameters (oxygen selling option, methanol selling price and electrolysers’ capital cost) on the profitability of the plant. The analysis has been performed in W-ECoMP, software for the thermo-economic analysis and plant optimization developed by the University of Genoa.

Abstract: The dynamics of reformation and replacement of gas hydrates were studied under nonequilibrium conditions. It was found that the reformation of gas hydrates is largely affected by the state of the gas‐water system and the restarting temperature. This suggests that the effects are caused by changes in the structure of the aqueous solution at a molecular level. Pure samples of CH4 gas hydrate were synthesized from ice crystals and the dissociated solution using the reformation method. Replacement of CO2 gas hydrate is achieved within a short duration in the solid‐phase sample of CH4 gas hydrate, if the pressure and temperature is precisely controlled in a pressure vessel.

Abstract The commonly used transmutation rate of minor actinides in nuclear reactors is decomposed into four components, overall fission rate, Pu production rate, MA production rate, and element production rate. The physical meanings of these factors are described. The transmutation rates of minor actinides in two types of highly-moderated PWRs, a MOX fueled Na cooled fast reactor, and a metal fueled Pb cooled fast reactor are interpreted using the four components. The metal fueled Pb cooled fast reactor can incinerate minor actinides most (79kg/GWth/year), and this amount is about 4 times larger than the thermal reactors. The thermal reactors have large relative overall fission rates for 241 Am and have a potential for the incineration of 241 Am.

Abstract The present work attempts to devise an efficient method utilizing an on-grid photovoltaic-thermal heat pump water heater (PV-THPWH) integrated with a real-time variable frequency controller to achieve the goal of energy-efficient buildings. The prime focus is to reduce the grid's dependence on the compressor's energy-intensive operation by employing a feedback-controlled variable frequency drive (VFD). Additionally, the possibilities involved with addressing the electrical and thermal energy requirements of an energy-efficient building was investigated utilizing the proposed system. R-32 refrigerant in the photovoltaic-thermal (PV-T) evaporator coils of the heat pump assembly help to cool the photovoltaic (PV) panel while delivering the absorbed heat in the condenser to heat water contained inside the storage tank. Outdoor experiments and theoretical investigations of the combined system were carried out to appraise the dynamic behavior under varying solar irradiation and ambient temperature conditions. The observations conveyed that the PV-THPWH system succeeded in reducing the PV panel operating temperature by 25%, which resulted in a 20% increment in PV power output. Also, the performance indicators, such as the instantaneous energy efficiency and instantaneous PV efficiency, were found to increase by 15% and 34%, respectively, resulting in an average coefficient of performance of 6.4. For a clear sky day, the recorded total PV energy output was 4.67 units, while the VFD compressor consumption was 3.42 units, and the surplus 1.25 units were sent to the grid. Furthermore, the economic analysis reported a payback period of 2.3 years for the developed PV-THPWH system.

Analytical and experimental studies of a brushless, exciterless, single-phase, sinusoidal-wave synchronous machine operating as a generator or a motor, derived from a three-phase machine, are reported. One phase armature winding of the three-phase machine is used as an auxiliary stator winding of the single-phase machine and is used to supply the exciting power for the other two-phase armature windings acting as the load winding of the single-phase machine. A 1.5 kW, 200 V, 60 Hz, four-pole synchronous machine was used the experiments. It is shown that the waveforms of the armature terminal voltage and the load current are nearly sinusoidal. The advantages of the single-phase machine as a portable generator or small-load motor are discussed. >