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Abstract Double and added double stage organic Rankine cycle systems are configured to recover exhaust gas waste heat of dual fuel engines. To evaluate the performance of the models proposed here, energy, exergy and economic analyses are performed. Several working fluids are evaluated for recommendation for double and added double stage organic Rankine cycle systems. In the double stage organic Rankine cycle, cycle 1 and cycle 2 are connected in parallel. Working fluids R123, R141b, and R601 are used in cycle 1, and R245fa, R236ea, and R1233zd in cycle 2. In the double stage organic Rankine cycle, the working fluid combinations of R601-R1233zd, R601-R245fa and R123-R245fa show better performance when considering power, heat transfer area and payback period, which are 1760 kW, 2108.9 m2 and 4.21 year, respectively for R601-R245fa. In the added double stage organic Rankine cycle, cycle 1 and cycle 2 are connected in two stages and cycle 1 and cycle 3 in parallel. The net power of the working fluid combinations of R123-R245fa and R123-R1233zd are 1799 kW and 1782 kW, respectively, which are higher than those of the others. Further, for R123-R245fa, the heat transfer area and payback period are 3352 m2 and 6.20 year, respectively, which is better compared to those of other working fluid combinations.

In this study, levulinic acid (LA) was produced from rice straw biomass in co-solvent biphasic reactor system consisting of hydrochloric acid and dichloromethane organic solvent. The modified protocol achieved a 15% wt LA yield through the synergistic effect of acid and acidic products (auto-catalysis) and the designed system allowed facile recovery of LA to the organic phase. Further purification of the resulting extractant was achieved through traditional column chromatography, which yielded a high purity LA product while recovering ∼85% wt. Upon charcoal treatment of the resultant fraction generated an industrial grade target molecule of ∼99% purity with ∼95% wt recovery. The system allows the solvent to be easily recovered, in excess of 90%, which was shown to be able to be recycled up to 5 runs without significant loss of final product concentrations. Overall, this system points to a method to significantly reduce manufacturing cost during large-scale LA preparation.

Abstract Hydrogen is considered a potential game changer for world energy systems and a solution to climate change concerns, as it generates zero waste and it is suited for power generation and transportation. Despite its several advantages, there are significant technical challenges in deploying a stable hydrogen economy including improving its process efficiencies, lowering production costs, maintaining cost-effective transmission and distribution, and exploiting inexpensive and sustainable feedstocks. In this context, a detailed study was conducted to analyze the production sources, technologies, storage and transport systems, and global potential exportable feedstocks to produce hydrogen. A comprehensive analysis of current hydrogen production technologies with their energy efficiencies and hydrogen selling prices was reported in this study. Various hydrogen production technologies with their capital investments and CO2 emissions were also presented. Potential feedstocks for hydrogen production were identified and analyzed through a product space model, which characterizes a network of global exportable products based on their similarities and productive knowledge. It was established that the hydrogen production feedstocks and sources currently used are primarily available in six countries: the United States of America, France, Russia, Sweden, the Netherlands, and Spain. Broadly, the results revealed that the United States of America and Russia shared the highest hydrogen feedstock exports, indicating a higher probability of hydrogen production in these countries. Except for Russia, all the studied countries fell in the most desired quadrant, indicating that they can move in all product space directions to exploit unexplored hydrogen feedstocks for better sustainable economic growth.

Energy conservation potential of the evaporative roof cooling technique for a cinema house in a composite climate (characterized by Delhi) has been evaluated. Thermal loads due to heat conduction through the building envelope, the required ventilation and the occupants have been taken into account. Life-cycle-cost analysis has been employed to evaluate the cost effectiveness of this energy conservation technique. It is seen that evaporative cooling on the roof leads to a net saving of 14% in the initial investment and 17% in the annual cost.

Abstract Due to the various restrictions on the energy performance of public office buildings, it is essential to obtain occupancy information for not only evaluating but also regulating the building energy performance. There is still a lack of information and standard, however, for occupancy density due to the limitations on data collection and the lack of reliable data. Therefore, this study aimed to determine the optimal occupancy density for reducing the energy consumption in public office buildings. Towards this end, this study used various statistical methods, such as correlation analysis, decision tree, and Mann-Whitney U test, based on the actual occupancy data from public office buildings in South Korea. This study was conducted in three steps: (i) establishment of the database; (ii) determination of the optimal occupancy density using the statistical approach; and (iii) application of the proposed occupancy density using building energy policies. As a result, it was shown that buildings with an occupancy density above 31.41 m2/person could save up to 50.3% energy on average compared to those with an occupancy density below 31.41 m2/person. The analysis results showed that the proposed occupancy density could help in deciding the appropriate occupancy density for reducing the energy consumption of public office buildings.

Abstract Waste heat recovery has attracted a significant attention because of the world growth in energy demand. In this paper, we report the study on an energy recovery system utilizing low-grade waste heat below 100 °C. This system called a thermal-driven electrochemical generator is composed of reverse electrodialysis (RED) power generation and thermal separation using waste heat. We especially focus on the experimental characterization of the RED process with ammonium bicarbonate (NH4HCO3) solution, which is known to be easily decomposed at the temperature around 60 °C. We characterized this NH4HCO3-RED system with various parameters including the concentration difference, the membrane type, the inlet flow rate, and the compartment thickness. We found the best power density at the concentrated solution of 1.5 mol L−1 and the diluted solution of 0.01 mol L−1. The maximum power density increases as the inlet flow rate increases or the compartment thickness decreases owing to the decrease in the internal resistance. We obtained the excellent power density of 0.77 W m−2, compared with the previous studies.

Abstract Small hydropower projects (SHPs), though generally considered more environmentally benign and socially acceptable as compared to large projects, yet their overall sustainability is under suspicion in the Himalayan regions. Almost all SHPs in this region are being developed as run of the river mode which generally causes less/no submergence and quite less displacement of people as compared to large reservoir based hydropower production mode. However, in the absence of proper planning and monitoring mechanism, these projects are causing implacable tunnelling of hills, choking of streams, conversion of streams into dry ditches and long term socio-environmental impacts. This paper presents a SHP development study from hydro rich Beas river basin of Himachal Pradesh, a state nestled in western Himalayan region of India. In depth field studies, focus group discussions with the project affected people and interaction with project proponents of five SHPs in this region suggest that sustainability issues with respect to SHPs are not small vis-a-vis size of their installed capacity. There is an urgent need to take steps to include SHPs having an installed capacity of above 10 MW into the ambit of environment clearance process which is absent in many countries of the world at present.

Abstract The diesel engine is being widely used in day to day life in both mobile and stationary applications. The main drawback is the release of harmful gasses like HC, CO, NOx and particulate matter into the atmosphere. This affects both human beings and environment to a great extent and should be controlled effectively. This paper reviews the works on the control of diesel particulate matter in both pre-combustion and post-combustion techniques employed in the past few decades. The initial part of this review will discuss particulate matter composition and its structure. Then the various physical processes involved in the formation of particulate matter are discussed. Effects of fuel composition and its structure on soot formation are reported. Hazardous effects of particulate matter on both human beings and the environment are reviewed. Use of biodiesel water emulsified fuel as a fuel to control soot formation is highlighted. This review also highlights control of particulate matter by varying injection parameters like injection pressure, injection timing and auxiliary air injection. Multiple fuel injections within the same cycle to control NOx and particulate matter are also discussed. The conventional control technique of particulate matter by using Diesel particulate filter and its types are also compared with the new technologies. Various regeneration concepts to burn the collected soot are also highlighted. The major part of this review focuses on pre-combustion techniques to control particulate matter. This review paper, it is hoped, will be very useful for the researchers working on the control of diesel particulate matter.