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Abstract The kinetics of methane hydrate decomposition was studied using a semibatch stirred-tank reactor. The decomposition was accomplished by reducing the pressure on a hydrate slurry in water to a value below the three-phase equilibrium pressure at the reactor temperature. The data were obtained at temperatures from 274 to 283 K and pressures from 0.17 to 6.97 MPa. The stirring rates were high enough to eliminate mass-transfer effects. Analysis of the data indicated that the decomposition rate was proportional to the particle surface area and to the difference in the fugacity of methane at the equilibrium pressure and the decomposition pressure. The proportionality constant showed an Arrhenius temperature dependence. An estimate of the hydrate particle diameters in the experiments permitted the development of an intrinsic model for the kinetics of hydrate decomposition.

The design and assessment of net-zero buildings commonly focus exclusively on the operational phase, ignoring the embodied environmental impacts over the building life cycle. An analysis is presented on the consequences of integrating embodied impacts into the assessment of the environmental advantageousness of net-zero concepts. Fundamental issues needing consideration in the design process - based on the evaluation of primary energy use and related greenhouse gas emissions - are examined by comparing three net-zero building design and assessment cases: (1) no embodied impacts included, net balance limited to the operation stage only; (2) embodied impacts included but evaluated separately from the operation stage; and (3) embodied impacts included with the operation stage in a life cycle approach. A review of recent developments in research, standardization activities and design practice and the presentation of a case study of a residential building in Norway highlight the critical importance of performance indicator definitions and system boundaries. A practical checklist is presented to guide the process of incorporating embodied impacts across the building life cycle phases in net-zero design. Its implications are considered on overall environmental impact assessment of buildings. Research and development challenges, as well as recommendations for designers and other stakeholders, are identified.

It is well known that the efficiency of PV modules decreases with increasing module temperatures. Many studies have paid attention to the development and validation of heuristic models to calculate the PV module temperature in higher latitudes, however only a few focus on the thermal behaviour of PV modules in tropical regions of the world, where constantly high temperatures prevail. Also, little is known about the effect of including wind speed in these thermal models. This study evaluates three of such models - one that excludes wind, and two others including the wind influence - using hourly data for two tropical locations. Results show that the average hourly wind speeds in Singapore and Jayapura (Indonesia) are low and therefore the influence of the wind on the PV module temperature is minor. The three evaluated models produce about the same results with RMSE between 1.5-3.8 °C during daytime, which corresponds to a deviation in power output in the range of 0.3-1.6 %, depending on the PV module technology.

AbstractThe surface oxygen exchange on oxides with high oxygen ion mobility is modelled with a two step reaction with adsorbed mono-atomic oxygen species as intermediate. Interpretation of the Po2 dependence of the exchange rates, following from this model, indicates that these adsorbed oxygen atoms are singly charged.For the stabilized δ-Bi2O3 solid electrolyte a good agreement has been found between the isotope exchange model and the electrochemical study of the oxygen exchange using gold electrodes. For the mixed La-Sr cobaltite perovskite a change in the surface exchange reaction is observed going from room temperature to 600°C. Indications are that above 450°C the bulk exchange is rate limiting with a (Po2)−1 dependence while below this temperature it is assumed that the dissociative adsorption is rate limiting with a (Po2)1/2 dependence.

Artículos en revistas Numerical models of transmission-constrained electricity markets are used to inform regulatory decisions. How robust are their results? Three research groups used the same data set for the northwest Europe power market as input for their models. Under competitive conditions, the results coincide, but in the Cournot case, the predicted prices differed significantly. The Cournot equilibria are highly sensitive to assumptions about market design (whether timing of generation and transmission decisions is sequential or integrated) and expectations of generators regarding how their decisions affect transmission prices and fringe generation. These sensitivities are qualitatively similar to those predicted by a simple two-node model. info:eu-repo/semantics/publishedVersion

Domestic heating represents the most dominant energy function in Dutch households nowadays. Using district heat from CHP (combined heat and power) by means of a NGCC (natural gas-fired combined cycle) plants is generally acknowledged as an effective option to reduce primary energy consumption for heating. However, methods to calculate energy savings from CHP differ widely. This paper compares a number of different methods, including the method from the EU CHP Directive, to estimate primary energy savings in comparison with the typically used domestic gas-fired condensing boiler. Real hourly CHP plant performance data is used. An estimation of the CO2 mitigation cost of delivering district heat to Dutch dwellings is made. We find that supplying dwellings with district heat from an NGCC-CHP saves energy, regardless of the calculation method and for a rather wide range of reference efficiencies. CO2 mitigation costs are acceptable from a social perspective (at discount rates up to 4%, excluding fuel taxes) and negative from a private perspective (at discount rates up to 10%, including fuel taxes).

Escalating energy costs are an increasing concern for South Asian farmers growing rice and wheat in rotation. Millions of people in the IGP (Indo-Gangetic Plains) depend on this cropping system for food and income security. CT (conservation tillage) practices, including mechanical BP (bed planting), PTOS (power-tiller operated seeding), and ST (strip tillage), are advocated by donors and development organizations as profitable, high yielding, and energy-efficient alternatives to TT (traditional tillage). However, most studies on the EUE (energy input use efficiency) of CT originate from researcher-controlled and on-station experiments. Comparatively little information is available on the EUE of CT practices as farmers apply them in their own fields, and under their own management decisions. This research responds to this gap, and analyzes EUE of each of these three CT options, compared to TT, by surveying 328 rice-wheat farmers in north-western Bangladesh. Concentrating on wheat production, we employed a non-parametric benchmarking technique involving slack-based measures of technical efficiency, along with a fractional regression model to identify and compute the wasteful use of energy. PTOS achieved the highest EUE score (0.92), followed closely by BP and ST (both 0.91), whereas TT (0.68) was significantly (p <0.001) different and lower than the CT practices.