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In this study, levulinic acid (LA) was produced from rice straw biomass in co-solvent biphasic reactor system consisting of hydrochloric acid and dichloromethane organic solvent. The modified protocol achieved a 15% wt LA yield through the synergistic effect of acid and acidic products (auto-catalysis) and the designed system allowed facile recovery of LA to the organic phase. Further purification of the resulting extractant was achieved through traditional column chromatography, which yielded a high purity LA product while recovering ∼85% wt. Upon charcoal treatment of the resultant fraction generated an industrial grade target molecule of ∼99% purity with ∼95% wt recovery. The system allows the solvent to be easily recovered, in excess of 90%, which was shown to be able to be recycled up to 5 runs without significant loss of final product concentrations. Overall, this system points to a method to significantly reduce manufacturing cost during large-scale LA preparation.

In this study, levulinic acid (LA) was produced from rice straw biomass in co-solvent biphasic reactor system consisting of hydrochloric acid and dichloromethane organic solvent. The modified protocol achieved a 15% wt LA yield through the synergistic effect of acid and acidic products (auto-catalysis) and the designed system allowed facile recovery of LA to the organic phase. Further purification of the resulting extractant was achieved through traditional column chromatography, which yielded a high purity LA product while recovering ∼85% wt. Upon charcoal treatment of the resultant fraction generated an industrial grade target molecule of ∼99% purity with ∼95% wt recovery. The system allows the solvent to be easily recovered, in excess of 90%, which was shown to be able to be recycled up to 5 runs without significant loss of final product concentrations. Overall, this system points to a method to significantly reduce manufacturing cost during large-scale LA preparation.

Abstract Newer generation sources and loads are posing new challenges to the conventional power system protection schemes. Adaptive and intelligent protection methodology, based on advanced measurement techniques and intelligent fault diagnosis such as machine learning (ML), is found to be useful to meet these challenges. A large number of research works are reported on ML-based power system fault diagnosis. However, ML techniques are evolving at a very fast pace, and an inclusive, as well as state-of-the-art review on ML-based power system fault diagnosis, is not available in the literature. Given this need and growing trend towards ML, the study presented in this paper aims to provide a comprehensive review of ML-based power system fault diagnosis. At first, efforts have been made to enlist the issues present in conventional fault diagnosis which led to the popularity of ML techniques. Also, a baseline framework and workflow for ML-based fault diagnosis are presented. Next, various unsupervised and supervised learning techniques have been discussed separately which have been used by several researchers for fault diagnosis. The discussion throughout is supported with tabulated facts for fault detection, classification and localization works with techniques used, different simulation tools used, and their application system. The advantages and disadvantages of all the techniques of fault diagnosis have also been discussed which will help the readers in the selection of techniques for their research. A brief review of reinforcement learning and transfer learning is also given as they are gaining popularity in power system-related studies and have the potential to be used for fault diagnosis. Finally, the research trends, some key issues, and directions for future research have been highlighted.

Abstract Newer generation sources and loads are posing new challenges to the conventional power system protection schemes. Adaptive and intelligent protection methodology, based on advanced measurement techniques and intelligent fault diagnosis such as machine learning (ML), is found to be useful to meet these challenges. A large number of research works are reported on ML-based power system fault diagnosis. However, ML techniques are evolving at a very fast pace, and an inclusive, as well as state-of-the-art review on ML-based power system fault diagnosis, is not available in the literature. Given this need and growing trend towards ML, the study presented in this paper aims to provide a comprehensive review of ML-based power system fault diagnosis. At first, efforts have been made to enlist the issues present in conventional fault diagnosis which led to the popularity of ML techniques. Also, a baseline framework and workflow for ML-based fault diagnosis are presented. Next, various unsupervised and supervised learning techniques have been discussed separately which have been used by several researchers for fault diagnosis. The discussion throughout is supported with tabulated facts for fault detection, classification and localization works with techniques used, different simulation tools used, and their application system. The advantages and disadvantages of all the techniques of fault diagnosis have also been discussed which will help the readers in the selection of techniques for their research. A brief review of reinforcement learning and transfer learning is also given as they are gaining popularity in power system-related studies and have the potential to be used for fault diagnosis. Finally, the research trends, some key issues, and directions for future research have been highlighted.

AbstractElevated CO2 concentration has been reported to decrease grain nutrient concentrations and thus worsen nutritional deficiency and hidden hunger. One nutritional aspect is mineral content, yet mineral bioavailability can be limited by the presence of phytic acid. Given that future climate scenarios predict elevated global temperature driven by elevated atmospheric CO2 concentrations, we used Temperature by Free‐Air CO2 Enrichment (T‐FACE) field experiments to investigate whether elevated temperature alters the effects of elevated CO2 on grain mineral concentrations, grain mineral yields, and their bioavailability in a range of wheat and rice genotypes. We found that the negative effects of elevated CO2 were compensated for by positive effects of elevated temperature. As a result, the combined elevated CO2 and elevated temperature increased concentrations of some minerals by up to ~15% in both rice and wheat relative to control conditions. Moreover, the combined elevated CO2 and elevated temperature did not significantly change total yields of some minerals despite lower grain yields. The combined CO2 and temperature elevation increased phytic acid concentration in rice by 18.1% but decreased it in wheat by 3.5%. The mineral bioavailability, estimated as the mole ratio of phytic acid to minerals in rice and wheat grains, was limited by the combined CO2 and temperature elevation in only a few cases. Our results indicate that under future climate conditions of elevated temperature and CO2, the nutritional quality of rice and wheat with respect to minerals may remain unchanged.