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Dolomite-based binders are characterised by interesting technical and environmental features. For their synthesis, sources of both CaO and MgO are required. The idea developed in this work is to couple the synthesis of dolomite-based binders, starting from a natural dolomite, through the concept of concentrated solar energy (needed to drive the endothermal dolomite calcination process) in fluidised bed reactors. To this end, a fluidised bed system, where the concentrated solar radiation is mimicked by the use of Xe-lamps (short-arc), has been set up and operated. Natural dolomite (sieved in the 420-590 ?m size range) was calcined at a nominal temperature of 850 °C, and bed temperature profiles during solar-driven calcination were investigated. Then, four binders were prepared by mixing slaked dolomite (obtained from the hydration of solar calcined dolomite) with either blast furnace slag or coal fly ash as supplementary cementitious materials. The binders were hydrated for curing times ranging from 7 to 56 days. X-ray fluorescence, X-ray diffraction and combined differential thermal and thermogravimetric analyses were employed as characterisation techniques both to analyse the chemical composition of starting materials and to investigate the evolution of the hydration in the four systems.

The influence of compost on the growth of bean plants irrigated with As-contaminated waters and its influence on the mobility of As in the soils and the uptake of As (as NaAs(III)O2) by plant components was studied at various compost application rates (3·10(4) and 6·10(4) kg ha(-1)) and at three As concentrations (1, 2 and 3 mg kg(-1)). The biomass and As and P concentrations of the roots, shoots and beans were determined at harvest time, as well as the chlorophyll content of the leaves and nonspecific and specifically bound As in the soil. The bean plants exposed to As showed typical phytotoxicity symptoms; no plants however died over the study. The biomass of the bean plants increased with the increasing amounts of compost added to the soil, attributed to the phytonutritive capacity of compost. Biomass decreased with increasing As concentrations, however, the reduction in the biomass was significantly lower with the addition of compost, indicating that the As phytotoxicity was alleviated by the compost. For the same As concentration, the As content of the roots, shoots and beans decreased with increasing compost added compared to the Control. This is due to partial immobilization of the As by the organic functional groups on the compost, either directly or through cation bridging. Most of the As adsorbed by the bean plants accumulated in the roots, while a scant allocation of As occurred in the beans. Hence, the addition of compost to soils could be used as an effective means to limit As accumulation in crops from As-contaminated waters.

Abstract Orange Peel Waste (OPW) is a widely produced residue whose management is complicated by its physical and chemical properties. Anaerobic digestion (AD), which is commonly used for the treatment and exploitation of many biodegradable wastes, is inefficient on OPW due to the presence of essential oils (mainly d -Limonene) as well as the low pH, which cause the process to be unstable. Here we explore the effect of alkaline pre-treatment of OPW and of the addition of granular activated carbon (GAC) and Zero Valent Iron (ZVI) in improving AD in two semi-continuous reactors at a laboratory scale. The addition and pre-treatment of ZVI/GAC were shown to help process stability up to a loading of 3 kgVS·m−3·d−1 and to increase methane production even at a sub-optimal pH. The investigation of the bacterial community, by high-throughput sequencing, has also increased our insight on their involvement in AD in the presence of ZVI, including its biotic oxidation. In addition, direct interspecies electron transfer was shown to play a role in the reactor supplemented with ZVI.

AbstractThe potential impacts of future climate scenarios on water balance and flow regime are presented and discussed for a temporary river system in southern Italy. Different climate projections for the future (2030–2059) and the recent conditions (1980–2009) were investigated. A hydrological model (Soil and Water Assessment Tool) was used to simulate water balance at the basin scale and streamflow in a number of river sections under various climate change scenarios, based on different combinations of global and regional models (global circulation models and regional climate models). The impact on water balance components was quantified at the basin and subbasin levels as deviation from the baseline (1980–2009), and the flow regime alteration under changing climate was estimated using a number of hydrological indicators. An increase in mean temperature for all months between 0.5–2.4 °C and a reduction in precipitation (by 4–7%) was predicted for the future. As a consequence, a decline of blue water (7–18%) and total water yield (11–28%) was estimated. Although the river type classification remains unvaried, the flow regime distinctly moves towards drier conditions and the divergence from the current status increases in future scenarios, especially for those reaches classified as I‐D (ie, intermittent‐dry) and E (ephemeral). Hydrological indicators showed a decrease in both high flow and low flow magnitudes for various time durations, an extension of the dry season and an exacerbation of extreme low flow conditions. A reduction of snowfall in the mountainous part of the basin and an increase in potential evapotranspiration was also estimated (4–4.4%). Finally, the paper analyses the implications of the climate change for river ecosystems and for River Basin Management Planning. The defined quantitative estimates of water balance alteration could support the identification of priorities that should be addressed in upcoming years to set water‐saving actions.

Thermokinetics of Biochar production.

Wild microalgae (prokaryotic and eukaryotic photosynthetic microorganisms) - phytoplankton - is at the base of the food chain, supporting aquatic primary production. Microalgae are an ideal platform for the large-scale production of biomass because they are fast-growing, solar-powered 'biofactories' with low nutrient requirements. The variety of high-value bioproducts comes from microalgal species due to their wide physiological and functional diversity. Over the last 60 years, microalgal biotechnology has shown a range of applications: from the traditional extensive biomass production in human and animal nutrition, soil conditioning in agriculture, technologies for waste-water treatment, products for cosmetics and pharmacy, and most recently to the possible production of a 'third' generation of biofuels.