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Bromine and chlorine are almost ubiquitous in waste of electrical and electronic equipment (WEEE) and the knowledge of their content in the plastic fraction is an essential step for proper end of life management. The aim of this study is to compare the following analytical methods: energy dispersive X-ray fluorescence spectroscopy (ED-XRF), ion chromatography (IC), ion-selective electrodes (ISEs), and elemental analysis for the quantitative determination of chlorine and bromine in four real samples taken from different WEEE treatment plants, identifying the best analytical technique for waste management workers. Home-made plastic standard materials with known concentrations of chlorine or bromine have been used for calibration of ED-XRF and to test the techniques before the sample analysis. Results showed that IC and ISEs, based upon dissolution of the products of the sample combustion, have not always achieved a quantitative absorption of the analytes in the basic solutions and that bromine could be underestimated since several oxidation states occur after combustion. Elemental analysis designed for chlorine determination is subjected to strong interference from bromine and required frequent regeneration and recalibration of the measurement cell. The most reliable method seemed to be the non-destructive ED-XRF. Calibration with home-made standards, having a similar plastic matrix of the samples, enabled us to carry out quantitative determinations, which have been revealed to be satisfactorily accurate and precise. In all the analyzed samples a total concentration of chlorine and/or bromine between 0.6 and 4 w/w% was detected, compromising the feasibility of a mechanical recycling and suggesting the exploration of an alternative route for managing these plastic wastes.

Recycled waste materials obtained from industrial and agricultural processes are becoming promising thermal and acoustic insulating solutions in building applications; their use can play an important role in the environmental impact reduction. The aim of the present paper is the evaluation of the thermal performance of recycled waste panels consisting of cork scraps, rice husk, coffee chaff, and end-life granulated tires, glued in different weight ratios and pressed. Six panels obtained from the mixing of these waste materials were fabricated and analyzed. In particular, the scope is the selection of the best compromise solutions from the thermal and environmental points of view. To this aim, thermal resistances were measured in laboratory and a Life Cycle Assessment (LCA) analysis was carried out for each panel; a cross-comparative examination was performed in order to optimize their properties and find the best panels solutions to be assembled in the future. Life Cycle Analysis was carried out in terms of primary Embodied Energy and Greenhouse Gas Emissions, considering a ‘‘cradle-to-gate” approach. The obtained thermal conductivities varied in the 0.055 to 0.135 W/mK range, in the same order of magnitude of many traditional systems. The best thermal results were obtained for the panels made of granulated cork, rice husk, and coffee chaff in this order. The rubber granulate showed higher values of the thermal conductivity (about 0.15 W/mK); a very interesting combined solution was the panel composed of cork (60%), rice husk (20%), and coffee chaff (20%), with a thermal conductivity of 0.08 W/mK and a Global Warming Potential of only 2.6 kg CO2eq/m2. Considering the Embodied Energy (CED), the best solution is a panel composed of 56% of cork and 44% of coffee chaff (minimum CED and thermal conductivity).

This work evaluates, for the first time, the possibility of producing multifunctional alkali-activated composites combining ultra-low density, low thermal conductivity, high acoustic absorption, and good moisture buffering capacity. The composites were prepared using cork as a lightweight aggregate. This novel material might promote energy savings and tackle the CO2 emissions of the building sector, while simultaneously improve the comfort for inhabitants (e.g. humidity levels regulation and sound pollution reduction). The composites apparent density (as low as 168 kg/m3) and thermal conductivity (as low as 68 mW/m K) are amongst the lowest ever reported for alkali-activated materials (AAM) composites and foams, while their sound absorption ability is comparable to the best performing AAM foams reported to date, but in addition these eco-friendly composites also show good ability to passively adjust the humidity levels inside buildings. The multifunctional properties shown by the cork – AAM composites set them apart from other conventional building materials and might contribute to the global sustainability of the construction sector. Peer Reviewed

The lack of real integration between the different dimensions of sustainability is highlighted in the literature as one of the main hindrances to lessening the environmental risks and impacts of large-scale development projects. This paper discusses a hypothesis concerning the problems of integration between the different dimensions of sustainability in socio-environmental research into such projects. Differences in modes of knowledge production and the relationships of these with prevailing social positions constitute the crux of the argument. Endeavours to improve translational knowledge and mixed research methodologies (seeking the semi-standardization of research processes) are put forward as approaches to overcoming the above-mentioned obstacles.

Most of the world’s mountain glaciers have been retreating for more than a century in response to climate change. Glacier retreat is evident on all continents, and the rate of retreat has accelerated during recent decades. Accurate, spatially explicit information on the position of glacier margins over time is useful for analyzing patterns of glacier retreat and measuring reductions in glacier surface area. This information is also essential for evaluating how mountain ecosystems are evolving due to climate warming and the attendant glacier retreat. Here, we present a non-comprehensive spatially explicit dataset showing multiple positions of glacier fronts since the Little Ice Age (LIA) maxima, including many data from the pre-satellite era. The dataset is based on multiple historical archival records including topographical maps; repeated photographs, paintings, and aerial or satellite images with a supplement of geochronology; and own field data. We provide ESRI shapefiles showing 728 past positions of 94 glacier fronts from all continents, except Antarctica, covering the period between the Little Ice Age maxima and the present. On average, the time series span the past 190 years. From 2 to 46 past positions per glacier are depicted (on average: 7.8).

A natural holm oak forest was selectively thinned to test thinning as a tool to reduce tree mortality, increase productivity, and reverse the recent regression of the dominant species (Quercus ilex) induced by climate change. Thinning increased aboveground productivity and reduced stem mortality in this Mediterranean forest during four years just after thinning, contributing to the maintenance of forest functioning under changing climatic conditions. Q. ilex was the only species positively affected by the thinning: stem growth increased for all stem sizes, and mortality was significantly lower in thinned plots. On the contrary, mortality rates of Phillyrea latifolia and Arbutus unedo were not significantly lower. Stem growth increased for P. latifolia only in the smallest stem-size class. Our results highlight the suitability of selective thinning for improving the forest productivity and ensuring the conservation of Mediterranean coppices. Other benefits of selective thinning, such as a decrease in the risk of fire dispersion and an increase in the water supply for human populations, are also discussed.