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Micro- and nanoscale patterned monolayers of plasmonic nanoparticles were fabricated by combining concepts from colloidal chemistry, self-assembly, and subtractive soft lithography. Leveraging chemical interactions between the capping ligands of pre-synthesized gold colloids and a polydimethylsiloxane stamp, we demonstrated patterning gold nanoparticles over centimeter-scale areas with a variety of micro- and nanoscale geometries, including islands, lines, and chiral structures (e.g., square spirals). By successfully achieving nanoscale manipulation over a wide range of substrates and patterns, we establish a powerful and straightforward strategy, nanoparticle chemical lift-off lithography (NP-CLL), for the economical and scalable fabrication of functional plasmonic materials with colloidal nanoparticles as building blocks, offering a transformative solution for designing next-generation plasmonic technologies.

AbstractThe Ru‐catalyzed cleavage of title aryloxy arylethanols (I) as model compounds for lignin‐like substructures is smoothly achieved to give aromatic ketones (II) and phenol derivatives in good yields.

Microbial electrochemical technologies (METs) constitute the core of a number of emerging technologies with a high potential for treating urban wastewater due to a fascinating reaction mechanism—the electron transfer between bacteria and electrodes to transform metabolism into electrical current. In the current work, we focus on the model electroactive microorganism Geobacter sulfurreducens to explore both the design of new start-up procedures and electrochemical operations. Our chemostat-grown plug and play cells, were able to reduce the start-up period by 20-fold while enhancing chemical oxygen demand (COD) removal by more than 6-fold during this period. Moreover, a filter-press based bioreactor was successfully tested for both acetate-supplemented synthetic wastewater and real urban wastewater. This proof-of-concept pre-pilot treatment included a microbial electrolysis cell (MEC) followed in time by a microbial fuel cell (MFC) to finally generate electrical current of ca. 20 A·m−2 with a power of 10 W·m−2 while removing 42 g COD day−1·m−2. The effective removal of acetate suggests a potential use of this modular technology for treating acetogenic wastewater where Geobacter sulfurreducens outcompetes other organisms.

Abstract The albedo of a roof determines the fraction of incoming sunlight that is reflected, which affects heat transfer into the building and exchange of energy between the built environment and the atmosphere. While the albedo of individual roofs can be easily measured, roof albedo at the city scale is unknown. In this paper we characterize the albedos of roofs in seven cities in California: Los Angeles, Long Beach, Bakersfield, San Francisco, San Jose, Sacramento, and San Diego. The fraction of urban area covered by roofs ranged by city from 10% to 25%. City-wide average roof albedo ranged from 0.17 ± 0.08 to 0.20 ± 0.11 (mean ± standard deviation) for five of the cities; values were higher in Sacramento (0.24 ± 0.11) and San Diego (0.29 ± 0.15). Buildings with small roofs were found to constitute a large fraction of city roof area and to have low mean albedos. This suggests that efforts to increase urban albedo through the use of reflective roofs should include small roofs, which are presumably mostly residential. Roof albedos derived for Bakersfield were used in a regional climate model (Weather Research and Forecasting Model) to estimate temperature changes attainable by converting the current stock of roofs to “cool” high albedo roofs. It was found that seasonal mean afternoon (15:00 LST) temperatures could be reduced by up to 0.2 °C during both the summer and winter. Changes in precipitation were not significant at the 95% confidence level.

Atmospheric mercury (Hg) cycling is sensitive to climate-driven changes, but links with various teleconnections remain unestablished. Here, we revealed the El Niño-Southern Oscillation (ENSO) influence on gaseous elemental mercury (GEM) concentrations recorded at a background station in East Asia using the Hilbert-Huang transform (HHT). The timing and magnitude of GEM intrinsic variations were clearly distinguished by ensemble empirical mode decomposition (EEMD), revealing the amplitude of the GEM concentration interannual variability (IAV) is greater than that for diurnal and seasonal variability. We show that changes in the annual cycle of GEM were modulated by significant IAVs at time scales of 2-7 years, highlighted by a robust GEM IAV-ENSO relationship of the associated intrinsic mode functions. With confirmation that ENSO modulates the GEM annual cycle, we then found that weaker GEM annual cycles may have resulted from El Niño-accelerated Hg evasion from the ocean. Furthermore, the relationship between ENSO and GEM is sensitive to extreme events (i.e., 2015-2016 El Niño), resulting in perturbation of the long-term trend and atmospheric Hg cycling. Future climate change will likely increase the number of extreme El Niño events and, hence, could alter atmospheric Hg cycling and influence the effectiveness evaluation of the Minamata Convention on Mercury.

Trace elements can have profound adverse effects on the health of people burning coal in homes or living near coal deposits, coal mines, and coal-burning power plants. Trace elements such as arsenic emitted from coal-burning power plants in Europe and Asia have been shown to cause severe health problems. Perhaps the most widespread health problems are caused by domestic coal combustion in developing countries where millions of people suffer from fluorosis and thousands from arsenism. Better knowledge of coal quality characteristics may help to reduce some of these health problems. For example, information on concentrations and distributions of potentially toxic elements in coal may help delineate areas of a coal deposit to be avoided. Information on the modes of occurrence of these elements and the textural relations of the minerals in coal may help to predict the behavior of the potentially toxic trace metals during coal cleaning, combustion, weathering, and leaching.

Microbial fuel cell (MFC) has received much attention in the last decade as a promising technology to simultaneously generate electricity and decontaminate wastewater. This study aims to quantitatively review the published literature on MFC, published in the period of 1970–2020, based on the Web of Science (WoS) database. For the first time in literature, a comprehensive quantitative review of MFC has been conducted by employing the technique of bibliometric and content analyses. A total of 11,397 publications have been retrieved from WoS, out of which 81.6% are research articles. The evaluation in the field of MFC has been mapped in various categories, such as publication history, publication distribution, subject category distribution, leading journals, leading countries and leading organizations in MFC research. Additionally, content analysis has been conducted to unearth the research trends in MFC; and some hot research topics in MFC have been spotted. Results depict that the period 2011–2020 has been the most appreciating era for MFC research, as it contributed 87% of the total publications. Among the subject categories, energy fuel and microbiology lead with contributions of 26.5% for each, butthe overall growth of the energy fuel category in the last decade has been the highest. Out of 1,147 journals publishing MFC research, Bioresource Technology is the leading one; and countries like China, USA and India are the main hub of MFC research with 26.47%, 16.95% and 7.69% contributions in publications, respectively. The hottest topics in MFC research are nanoparticles, catalysts, air electrodes, graphene electrodes, power enhancement, air cathode and nitrogen removal. Moreover, major research areas are engineering, energy fuels and biotechnology with each contribution 26.5% of the total publications.