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Abstract To achieve the EU climate and energy objectives, a transition towards a future sustainable energy system is needed. The integration of the huge potential for industrial waste heat recovery into smart energy system represents a main opportunity to accomplish these goals. To successfully implement this strategy, all the several stakeholders' conflicting objectives should be considered. In this paper an evolutionary multi-objective optimization model is developed to perform a sustainability evaluation of an energy system involving an industrial facility as the waste heat source and the neighbourhood as district heating network end users. An Italian case study of heat recovery from a steel casting facility shows how the model allows to properly select the district heating network set of users to fully exploit the available waste energy. Design directions such as the thermal energy storage capacity can be also provided. Moreover, the model enables the analysis of the trade-off between the stakeholders’ different perspectives, allowing to identify possible win-win solutions for both the industrial sector and the citizenship.

Abstract This paper presents a non-stoichiometric equilibrium model for the simulation of biomass downdraft gasifiers. The chemical equilibrium is determined by minimizing the Gibbs free energy. Five elements characterize the biomass and 15 chemical species are considered in the syngas. The model calculates the lower heating value of the syngas and the relative abundances of gasification products. An advantage of this model is that it can easily calculate not only the concentrations of the main gasification products, but also the concentrations of minor product, especially the pollutant chemical species containing Nitrogen and Sulfur. To analyse the model behaviour, a sensitivity analysis on process parameters is presented. The model is validated by comparing its results with the results of simulation carried out with a stoichiometric model and with experimental data found in literature. Finally, the model is applied to the study of the gasification of forest waste.

As part of the Copenhagen Accord, individual countries have submitted greenhouse gas reduction proposals for the year 2020. This paper analyses the implications for emission reductions, the carbon price, and abatement costs of these submissions. The submissions of the Annex I (industrialised) countries are estimated to lead to a total reduction target of 12-18% below 1990 levels. The submissions of the seven major emerging economies are estimated to lead to an 11-14% reduction below baseline emissions, depending on international (financial) support. Global abatement costs in 2020 are estimated at about USD 60-100 billion, assuming that at least two-thirds of Annex I emission reduction targets need to be achieved domestically. The largest share of these costs are incurred by Annex I countries, although the costs as share of GDP are similar for Annex I as a group and the seven emerging economies as a group, even when assuming substantial international transfers from Annex I countries to the emerging economies to finance their abatement costs. If the restriction of achieving two-thirds of the emission reduction target domestically is abandoned, it would more than double the international carbon price and at the same time reduce global abatement costs by almost 25%.

Improving access to safe drinking water can result in multi-dimensional impacts on people's livelihood. This has been aptly reflected in the Millennium Development Goals (MDG) as one of the major objectives. Despite the availability of diverse and complex set of technologies for water purification, pragmatic and cost-effective use of the same is impeding the use of available sources of water. Hence, in country like India simple low-energy technologies such as solar still are likely to succeed. Solar stills would suffice the basic minimum drinking water requirements of man. Solar stills use sunlight, to kill or inactivate many, if not all, of the pathogens found in water. This paper provides an integrated assessment of the suitability of domestic solar still as a viable safe water technology for India. Also an attempt has been made to critically assess the operational feasibility and costs incurred for using this technology in rural India.

Abstract Given the need to reduce the CO2 emissions coming from the manufacturing sector, it is important, for planning purposes, to know which countries and which manufacturing sub-sectors have the greatest potential for reducing energy use. Using data from the International Atomic Energy Agency and the United Nations Industrial Development Organization, the authors estimate trends in global decoupling of energy use and manufacturing value added, compare energy-use intensity in six country groups and estimate the potential for reducing energy use and CO2 emissions under two scenarios and compare selected sub-sector energy intensity and estimate the potential for reducing energy use CO2 emissions. The comparison of energy intensities across country groups and among countries suggests that there still remains significant potential to reduce energy use and associated CO2 emissions. The analysis of four sub-sectors in developing and transition economies also shows similar but varied potential for reducing energy use and associated CO2 emissions.

Abstract We evaluate the contribution of technological change in reducing CO 2 emissions in the Italian pulp and paper industry during the first and second phases of application of the European Union Emission Trading System (EU-ETS). We decompose the variation in emission and emission intensity into three different types of effects: a composition effect, a technique effect and a scale effect. The composition effect measures the change in emissions and emissions intensity due to a shift in production towards products that cause less emissions. The technique effect measures the change per each type of product, thereby accounting for technology improvements in the production of each type of good produced. The scale effect singles out the reduction in total emission due to an overall reduction in output. We show that the first phase of the application of EU-ETS has led to a reduction in both emissions and emission intensity due to the composition effect. The technological change has had a limited negative impact on emissions in the first phase, while in the second phase there has been limited technology improvement in the industry. However, the figures of the scale effect show that the larger reduction in emission is due to the overall decrease in output.

Coal will continue to be the main energy source in China for the immediate future, although the environmental pollution and ecological impacts of each stage in the full life cycle of coal mining, transportation, and combustion generate large quantities of external costs. The Late Permian coals in southwestern (SW) China usually contain high amounts of fluorine (F), arsenic (As), and ash, which together with high-F clays cause abnormally high levels of endemic fluorosis, As poisoning, and lung cancer in areas where coal is mined and burned. In this paper, we estimate the external costs of the life cycle of coal. The results show that the externalities of coal in SW China are estimated at USD 73.5 billion or 284.3 USD/t, which would have accounted for 6.5 % of the provincial GDP in this area in 2018. The external cost of human health accounts for 87.2% of the total external costs, of which endemic skeletal fluorosis diseases and related lung cancers have the most important impact. Our study provides a more precise estimate of externalities compared with its counterparts in other provinces in China. Therefore, several policy recommendations would be proposed to internalize the external cost.

Biodiesel is a fuel generally consisting of a mixture of fatty acid methyl esters (FAMEs) which is used in alternative or in combination with petroleum diesel for its environmental benefits. Biodiesel is conveniently manufactured from vegetable oils by transesterification of triglycerides with methanol. However, the process brings about the concurrent formation of glycerol, which may become an oversupplied chemical if biodiesel production keeps growing. A novel biodiesel-like material (abbreviated as DMC-BioD) was developed by reacting soybean oil with dimethyl carbonate (DMC), which avoided the co-production of glycerol. The main difference between DMC-BioD and biodiesel produced from vegetable oil and methanol (MeOH-biodiesel) was the presence of fatty acid glycerol carbonate monoesters (FAGCs) in addition to FAMEs. In the following study, details regarding synthesis and composition of DMC-BioD are provided along with physical properties relevant for its use as a fuel. In addition, the production of potential pyrogenic contaminants was investigated by analytical pyrolysis and compared with those from MeOH-biodiesel, and the model compounds tristearin, triolein, trilinolein and oleic acid glycerol carbonate ester (OAGC). The presence of FAGCs influenced both fuel and flow properties, while the distribution of main pyrogenic compounds, including polycyclic aromatic hydrocarbons (PAHs), was little affected. Benefits and drawbacks of DMC as a candidate transmethylating reagent for producing biofuel from renewable resources and alternative co-products (glycerol carbonate and glycerol dicarbonate) are discussed.

Abstract The present work focuses on the numerical simulation of Moderate or Intense Low oxygen Dilution combustion condition, using the Partially-Stirred Reactor model for turbulence-chemistry interactions. The Partially-Stirred Reactor model assumes that reactions are confined in a specific region of the computational cell, whose mass fraction depends both on the mixing and the chemical time scales. Therefore, the appropriate choice of mixing and chemical time scales becomes crucial to ensure the accuracy of the numerical simulation prediction. Results show that the most appropriate choice for mixing time scale in Moderate or Intense Low oxygen Dilution combustion regime is to use a dynamic evaluation, in which the ratio between the variance of mixture fraction and its dissipation rate is adopted, rather than global estimations based on Kolmogorov or integral mixing scales. This is supported by the validation of the numerical results against experimental profiles of temperature and species mass fractions, available from measurements on the Adelaide Jet in Hot Co-flow burner. Different approaches for chemical time scale evaluation are also compared, using the species formation rates, the reaction rates and the eigenvalues of the formation rate Jacobian matrix. Different co-flow oxygen dilution levels and Reynolds numbers are considered in the validation work, to evaluate the applicability of Partially-Stirred Reactor approach over a wide range of operating conditions. Moreover, the influence of specifying uniform and non-uniform boundary conditions for the chemical scalars is assessed. The present work sheds light on the key mechanisms of turbulence-chemistry interactions in advanced combustion regimes. At the same time, it provides essential information to advance the predictive nature of computational tools used by scientists and engineers, to support the development of new technologies.