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Biodiesel is a fuel generally consisting of a mixture of fatty acid methyl esters (FAMEs) which is used in alternative or in combination with petroleum diesel for its environmental benefits. Biodiesel is conveniently manufactured from vegetable oils by transesterification of triglycerides with methanol. However, the process brings about the concurrent formation of glycerol, which may become an oversupplied chemical if biodiesel production keeps growing. A novel biodiesel-like material (abbreviated as DMC-BioD) was developed by reacting soybean oil with dimethyl carbonate (DMC), which avoided the co-production of glycerol. The main difference between DMC-BioD and biodiesel produced from vegetable oil and methanol (MeOH-biodiesel) was the presence of fatty acid glycerol carbonate monoesters (FAGCs) in addition to FAMEs. In the following study, details regarding synthesis and composition of DMC-BioD are provided along with physical properties relevant for its use as a fuel. In addition, the production of potential pyrogenic contaminants was investigated by analytical pyrolysis and compared with those from MeOH-biodiesel, and the model compounds tristearin, triolein, trilinolein and oleic acid glycerol carbonate ester (OAGC). The presence of FAGCs influenced both fuel and flow properties, while the distribution of main pyrogenic compounds, including polycyclic aromatic hydrocarbons (PAHs), was little affected. Benefits and drawbacks of DMC as a candidate transmethylating reagent for producing biofuel from renewable resources and alternative co-products (glycerol carbonate and glycerol dicarbonate) are discussed.

Abstract The present work focuses on the numerical simulation of Moderate or Intense Low oxygen Dilution combustion condition, using the Partially-Stirred Reactor model for turbulence-chemistry interactions. The Partially-Stirred Reactor model assumes that reactions are confined in a specific region of the computational cell, whose mass fraction depends both on the mixing and the chemical time scales. Therefore, the appropriate choice of mixing and chemical time scales becomes crucial to ensure the accuracy of the numerical simulation prediction. Results show that the most appropriate choice for mixing time scale in Moderate or Intense Low oxygen Dilution combustion regime is to use a dynamic evaluation, in which the ratio between the variance of mixture fraction and its dissipation rate is adopted, rather than global estimations based on Kolmogorov or integral mixing scales. This is supported by the validation of the numerical results against experimental profiles of temperature and species mass fractions, available from measurements on the Adelaide Jet in Hot Co-flow burner. Different approaches for chemical time scale evaluation are also compared, using the species formation rates, the reaction rates and the eigenvalues of the formation rate Jacobian matrix. Different co-flow oxygen dilution levels and Reynolds numbers are considered in the validation work, to evaluate the applicability of Partially-Stirred Reactor approach over a wide range of operating conditions. Moreover, the influence of specifying uniform and non-uniform boundary conditions for the chemical scalars is assessed. The present work sheds light on the key mechanisms of turbulence-chemistry interactions in advanced combustion regimes. At the same time, it provides essential information to advance the predictive nature of computational tools used by scientists and engineers, to support the development of new technologies.

Commercial buildings are responsible for a significant share of the energy requirements of European Union countries. Related consumptions due to heating, cooling, and lighting appear, in most cases, very high and expensive. Since the real estate is renewed with a very small percentage each year and current trends suggest reusing the old structures, strategies for improving energy efficiency and sustainability should focus not only on new buildings, but also and especially on existing ones. Architectural renovation of existing buildings could provide an opportunity to enhance their energy efficiency, by working on the improvement of envelopes and energy supply systems. It has also to be noted that the measures aimed to improve the energy performance of buildings should pay particular attention to the cost-effectiveness of the interventions. In general, there is a lack of well-established methods for retrofitting, but if a case study achieves effective results, the adopted strategies and methodologies can be successfully replicated for similar kinds of buildings. In this paper, an iterative methodology for energy retrofit of commercial buildings is presented, together with a specific application on an existing office building. The case study is particularly significant as it is placed in an urban climatic context characterized by cold winters and hot summers; consequently, HVAC energy consumption is considerable throughout the year. The analysis and simulations of energy performance before and after the intervention, along with measured data on real energy performance, demonstrate the validity of the applied approach. The specifically developed design and refurbishment methodology, presented in this work, could be also assumed as a reference in similar operations.

The decentralization of the production sector crisis following industries in the suburbs have generated a multitude of empty containers in the medium-large Italian cities, which are abandoned, unsafe, and often dangerous for the community. From this arises the need to recover them and transform them into something else. This is not always possible or interesting for the subjects involved in the transformation. When the abandoned space is (even if only partially) polluted, then any hypothesis of transformation is stopped due to the high impact of decontamination costs, which greatly compromise the profitability of the investment. This paper deals with this issue focusing on a complex case study involving the abandoned area and the buildings of a former paint mill in the center of a typical city in the Turin metropolitan area. The suggested hypothesis is to act only on building components and external areas without any ground modification because of its contamination. Moreover, the new planned use (energy production from renewable sources to supply part of the public administration’s needs) does not foresee neither a stable presence of people nor a further consumption of land. The technical analysis of community energy needs and the subsequent economic and financial study lead to a financial sustainability over a period of about 25 years.

This paper elaborates different hybrid energy scenarios for applications in small or medium residential building facilities in typical Mediterranean climate conditions. Proposed hybrid energy solutions are based on the split air conditioning units as they are the most used individually energy sources able to cover heating and cooling demands in residential building facilities in considered climate conditions. Four different hybrid energy options have been analysed as they represent highly efficient energy solutions that could reduce overall energy consumption as well as also carbon dioxide emissions from residential sector. For each proposed energy solution a technical aspect was addressed, as well as also an economic aspect through obtained LCOE analysis. Therefore, the proposed and analysed hybrid energy concepts turned out to be a viable energy solution for residential applications as calculated LCOE was competitive with current retail prices of electricity on the EU market. The calculated LCOE ranged from 0.036 €/kWh up to 0.159 €/kWh, depending from the considered hybrid energy solution. The solution with the modified split heat pump system turned out to be most favourable. However, as each solution is characteristic one an additional evaluation framework was developed. Finally, the results of this study could be useful as examples of good practice as well as also a useful guidance for policy makers.

Global mitigation pathways play a critical role in informing climate policies and targets that are in line with international climate goals. However, it is not possible to directly compare modelled results with national inventories used to assess progress under the UNFCCC due to differences in how land-based fluxes are accounted for.National inventories consider carbon flux on managed land using an area-based approach with managed land-areas determined by nations. Emissions scenarios consider a different managed land area and are calibrated against data from detailed global carbon cycle models that account for natural (indirect) and anthropogenic (direct) fluxes separately by design. To disentangle the direct and indirect components of land-based carbon fluxes, we use a reduced complexity climate model with explicit treatment of the land-use sector, OSCAR, one of the models used by the Global Carbon Project. We find the discrepancy between model and NGHGI-based accounting methods globally to be 4.4 ± 1.0 Gt CO2 yr-1 averaged over the 2000-2020 time period, which is in line with existing estimates. We then apply OSCAR to the set of pathways assessed by the IPCC to quantify how this gap evolves over time and estimate how key mitigation benchmarks change.Across both 1.5°C and 2°C scenarios, LULUCF emissions pathways aligned with NGHGI accounting practices show a strong increase in the total land sink until around mid-century. However, the ‘NGHGI alignment gap’  decreases over this period, converging in the 2050-2060s for 1.5°C scenarios and 2070s-2080s for 2°C scenarios. The convergence is primarily a result of the simulated stabilization and then decrease of the CO2-fertilization effect as well as background climate warming reducing the overall effectiveness of the land sink, which in turn reduces the indirect removals considered by NGHGIs. These dynamics lead to land-based emissions reversing their downward trend in most NGHGI-aligned scenarios by mid-century, and result in the LULUCF sector becoming a net-source of emissions by 2100 in about 25% of both 1.5°C and 2°C scenarios.Assessing emission pathways using LULUCF definitions from national inventory accounting results in downward revisions to emissions benchmarks derived from scenarios. NGHGI-aligned pathways result in earlier net-zero CO2 emissions by around 2-5 years for both 1.5°C and 2°C scenarios, and 2030 emission reductions relative to 2020 are enhanced by about 5 percentage points for both pathway categories. When incorporating the additional land removals considered by NGHGIs, the assessed cumulative net CO2 emissions to global net-zero CO2 also decreases systematically by 15-18% for both 1.5°C and 2°C scenarios.We find that increasing removals from direct fluxes in 1.5C scenarios overtake estimated removals using NGHGI conventions in the near term. However, by midcentury, the strengthening of direct removals is balanced by weakening of indirect removals, meaning that, on average, carbon removal on land accounted for using NGHGI conventions in 1.5C scenarios results in about half of the LULUCF removals in current policy scenarios. We discuss the implications of our results for future Global Stocktakes and market mechanisms under the Paris Agreement.

Abstract The general acceptance of the CO2 geological storage by stakeholders passes through the assessment and mitigation of risks, potentially induced or increased by the disposal activity. Injection of moderate to large quantities of CO2 in the sub-surface may unbalance local stress and trigger earthquakes if faults are critically stressed, condition that is not easily verifiable. Pilot sites are therefore the best way to proceed further in order to address such challenging issues. In such cases, the reconnaissance of faults and seismicity in the sub-surface, before the onset of activity, is mandatory. In this paper, we present studies carried out in the site where the Sotacarbo Fault Lab is going to be installed. This facility will be located in a very low seismic hazard region of central Mediterranean, where reports on historical large earthquakes are poor. We show results from a series of experiments aimed to monitor the background seismicity around the pilot site. As expected, seismicity is almost absent down to small magnitude close to the future injection-test well. Further seismic imaging of the sub-surface layers obtained by ambient noise tomography offers the ability to resolve the presence of a seismicity-free fault located in the first 200 m below the surface, of which the last episode of activity is difficult to assess. Our results encourage the use of this site to follow the response of the system to injection of small quantity of CO2.

This paper provides an initial analysis of the EU ETS based on the installation-level data for verified emissions and allowance allocations in the first trading year. Those data, released on May 15, 2006, and subsequent updates revealed that CO2 emissions were about 4% lower than the allocated allowances. The main objective of the paper is to shed light on the extent to which over-allocation and abatement have taken place in 2005. We propose a measure by which over-allocation can be judged and provide estimates of abatement based on emissions data and indicators of economic activity as well as trends in energy and carbon intensity. Finally, we discuss the insights and implications that emerge from this tentative assessment.