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© 2020 Elsevier Ltd Free cooling of buildings uses the nocturnal outdoor air as a heat sink via a ventilation process. This could be performed by storing the night coolness for use during the daytime as appropriate. Due to the latent heat capacity, phase change material (PCM) could play anessential role in the effective operation of the free cooling systems by shifting the daytime peak load to the night. However, there is a scarceness on the technology application in hot climates. This paper presents results of a parametric investigation into the application of PCMs as thermal energy storage (TES) to provide sustainable cooling to buildings in hot arid climate by making use of the night-time free cooling. The proposed TES medium comprises an arrangement of metallic modules filled with RT28HC PCM. Numerous geometrical configurations and operational parameters have been assessed. A transient CFD simulation has been employed using ANSYS Fluent software. Validation of the numerical results with experimental data has shown a good agreement. The results have demonstrated that the temperature difference between the PCM and the air, at appropriate air flow rate would have a significant impact on the performance of the system. A free cooling system based on the proposed arrangement has the potential to meet around 42% of a typical building cooling load and has the ability to save up to 67% of building cooling energy load in summer season compared to conventional air-conditioning systems in hot arid climates.

Decarbonizing the building sector is extremely important to mitigating climate change as the sector contributes 40% of the overall energy consumption and 36% of the total greenhouse gas emissions in the world. Net-zero energy buildings are one of the promising decarbonization attempts due to their potential of decreasing the use of energy and increasing the total share of renewable energy. To achieve a net-zero energy building, it is necessary to decrease the energy demand by applying efficiency enhancement measures and using renewable energy sources. Net-zero energy buildings can be classified into four models (Net-Zero Site Energy buildings, Net-Zero Emissions buildings, Net-Zero Source Energy buildings, and Net-Zero Cost Energy buildings). A variety of technical, financial, and environmental factors should be considered during the decision-making process of net-zero energy building development, justifying the use of multi-criteria decision analysis methods for the design of net-zero energy buildings. This paper also discussed the contributions of renewable energy generation (hydropower, wind energy, solar, heat pumps, and bioenergy) to the development of net-zero energy buildings and reviewed its role in tackling the decarbonization challenge. Cost-benefit analysis and life cycle assessment of building designs were reviewed to shape the priorities of future development. It is important to develop a universal decision instrument for optimum design and operation of net-zero energy buildings.

Biomass plays an important role in the world primary energy supplies, currently providing ∼14% of the world's primary energy needs and being the fourth largest contributor following coal, oil and natural gas. Over the past decade, domestic biomass heating has received more governmental and public supports than ever before in many developed countries, such as the UK. Although biomass combustion releases some combustion pollutants, biomass is renewable and produces little net CO 2 emissions to the atmosphere. Owing to the low sulphur and low nitrogen contents of many biomass materials, substituting biomass for fossil fuels, particularly coal, can reduce SO x and NO x emissions. This study investigated flue gas emissions, particularly carbon monoxide and nitrogen oxides, of a domestic biomass boiler under various operating conditions. The biomass boiler used in this study satisfies the current EU regulation (EN 303-05) on emissions of domestic biomass boilers. Emissions of the boiler had been measured not only under normal combustion conditions, but also under 'idle' combustion conditions when the boiler was not in but was ready for full operation. The experimental results are analysed and presented in this paper. Copyright The Author 2010. Published by Oxford University Press. All rights reserved. For Permissions, please email: journals.permissions@oxfordjournals.org, Oxford University Press.

Abstract: The dynamics of reformation and replacement of gas hydrates were studied under nonequilibrium conditions. It was found that the reformation of gas hydrates is largely affected by the state of the gas‐water system and the restarting temperature. This suggests that the effects are caused by changes in the structure of the aqueous solution at a molecular level. Pure samples of CH4 gas hydrate were synthesized from ice crystals and the dissociated solution using the reformation method. Replacement of CO2 gas hydrate is achieved within a short duration in the solid‐phase sample of CH4 gas hydrate, if the pressure and temperature is precisely controlled in a pressure vessel.

Sustainability of agro-food supply chains has recently become the subject of greater interest from consumers, firms, governmental organizations and academia as the environment continues to deteriorate. One of the most critical factors influencing the sustainability of an agro-food supply chain is its network design. A particularly challenging aspect in this context is the broad range of influencing indicators associated with the Triple Bottom Line (TBL) of sustainability that need to be considered. However, many of these indicators could not be fully integrated or measured by single-step optimization problems. This paper presents a critical literature review of operational research methods for the design of sustainable supply chains. A novel two-stage hybrid solution methodology is proposed. In the first stage, a partner selection is performed using a hybrid multi criteria decision making based on Analytic Hierarchy Process (AHP) method and the Ordered Weighted Averaging (OWA) aggregation method. The result obtained in the first stage is used in the second stage to develop a multi-objective mathematical model to optimize the design of the supply chain network. This approach allows the simultaneous consideration of all three dimensions of sustainability including carbon footprint, water footprint, number of jobs created and the total cost of the supply chain design. The proposed approach generates a Pareto frontier to aid users in making decisions. Numerical experiments are completed utilizing data from an agro-food company to demonstrate the efficiency and effectiveness of the proposed solution methodology. The analyzes of the numerical results provide important organizational, practical and policy insights on (1) the impact of financial and environmental sustainability on supply chain network design (2) the tradeoff analysis between environmental emission, water footprint, societal implications and associated cost for making informed decision on supply chain investment.

Abstract This study demonstrates the possibility to use energy-cost optimal building designs based on life cycle approach. There is a lack of studies that cover the comprehensive assessment of both embodied energy (EE) and operational energy (OE) in a single optimization problem. The primary goal of the current study is to compare the optimized results of using OE+EE together and OE only. The optimization is performed on a case study building (townhouse) in Finland with three structural alternatives (i.e., reinforced concrete (RC); cross-laminated timber (CLT) and Steel). Different options for insulation thickness of external wall, roof, floor and window types were considered as decision variables as the scope of the present study is on building envelope. The objectives of the optimization are to minimize life cycle energy (LCE) and life cycle costs (LCC). The LCE difference between the most and least energy efficient solution on the pareto front is greater in case of the OE optimization, compared to OE+EE optimization. For all studied structures, the EE of the optimal solutions from OE+EE optimization ranges 16%–23% of LCE. Many of the non-dominated optimal solutions obtained from the OE+EE optimization shows a higher U-value for the building envelope components compared to the optimal solutions from the OE optimization. A relationship between both OE and EE with the overall thermal resistance of the building envelope is discussed to obtain a deeper understanding of such differences in U-value for the optimal solutions obtained from the OE+EE and OE optimization.

To find an appropriate method for sulfate-rich wastewater containing ethanol and acetate with COD/sulfate ratio of 1, a UASB reactor was operated for more than 180 days. The influences of HRT (hydraulic retention time) and OLR (organic loading rate) on organics and sulfate removal, gas production, and electrons utilization were investigated. The sludge activity and microorganism composition were also determined. The results indicated that this system removed more than 80% of COD and 30% of sulfate with HRT above 6h and OLR below 12.3 gCOD/L d. Further HRT decrease caused volatile fatty acids accumulation and performance deterioration. Except at HRT of 2h, COD and electron flow were mostly utilized by methane-producing archaea (MPA), and methane yield remained in the range of 0.18-0.24 LCH4/gCOD. Methane was mainly generated by Methanosaeta concilii GP6 with acetate as substrate, whereas sulfate was mainly reduced by incomplete-oxidizing Desulfovibrio species with ethanol as substrate.

Abstract Two office layouts with high and low levels of thermal control were compared, respectively traditional cellular and contemporary open plan offices. The traditional Norwegian practice provided every user with control over a window, blinds, door, and the ability to adjust heating and cooling. Occupants were expected to control their thermal environment to find their own comfort, while air conditioning was operating in the background to ensure the indoor air quality. In contrast, in the British open plan office, limited thermal control was provided through openable windows and blinds only for occupants seated around the perimeter of the building. Centrally operated displacement ventilation was the main thermal control system. Users’ perception of thermal environment was recorded through survey questionnaires, empirical building performance through environmental measurements and thermal control through semi-structured interviews. The Norwegian office had 35% higher user satisfaction and 20% higher user comfort compared to the British open plan office. However, the energy consumption in the British practice was within the benchmark and much lower than the Norwegian office. Overall, a balance between thermal comfort and energy efficiency is required, as either extreme poses difficulties for the other.