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In this study, levulinic acid (LA) was produced from rice straw biomass in co-solvent biphasic reactor system consisting of hydrochloric acid and dichloromethane organic solvent. The modified protocol achieved a 15% wt LA yield through the synergistic effect of acid and acidic products (auto-catalysis) and the designed system allowed facile recovery of LA to the organic phase. Further purification of the resulting extractant was achieved through traditional column chromatography, which yielded a high purity LA product while recovering ∼85% wt. Upon charcoal treatment of the resultant fraction generated an industrial grade target molecule of ∼99% purity with ∼95% wt recovery. The system allows the solvent to be easily recovered, in excess of 90%, which was shown to be able to be recycled up to 5 runs without significant loss of final product concentrations. Overall, this system points to a method to significantly reduce manufacturing cost during large-scale LA preparation.

Abstract A new formulation for the evaporation, flashing, condensation processes taking place in the effects of thermal desalination systems which simulates the operation of both forward and parallel/cross configurations is coupled with an exergo-economic model based on the SPECO method. The thermo-economic model uses accurate properties for the seawater, brine, pure water and vapour and is solved with an equation solver which does not require the development of a specific solution algorithm as in most previous studies. This flexible model is used to analyze the influence of the number of effects N and the temperature difference ΔT e between effects on the technical and economic performance of multi-effect desalination systems with ejector vapour compression. In particular, it is shown that the performance calculated by an earlier black-box approach is not attainable by technically and economically realistic systems. It is also shown that for each feed configuration and a given number of effects there exists an optimum value of ΔT e which minimizes the cost of the produced potable water. This last result forms the basis of a procedure that combines black-box results with the optimum value of ΔT e and can be used to select the appropriate system for any specific application.

Abstract: The dynamics of reformation and replacement of gas hydrates were studied under nonequilibrium conditions. It was found that the reformation of gas hydrates is largely affected by the state of the gas‐water system and the restarting temperature. This suggests that the effects are caused by changes in the structure of the aqueous solution at a molecular level. Pure samples of CH4 gas hydrate were synthesized from ice crystals and the dissociated solution using the reformation method. Replacement of CO2 gas hydrate is achieved within a short duration in the solid‐phase sample of CH4 gas hydrate, if the pressure and temperature is precisely controlled in a pressure vessel.

Abstract The 2013/2017 Nankai Trough (Japan) and 2017 Shenhu Area (China) offshore methane hydrate production tests showed the world the possibility and feasibility of the oceanic methane hydrate production by depressurization. However, the relatively low gas production rate still remained as one of the critical bottlenecks for the economical utilization. This study chose the Nankai Trough as a target area, and aimed at the gas recovery enhancement from the methane hydrate reservoir using vertical wells. A traditional single-vertical-well system and a new dual-vertical-well system were proposed, and special production strategies of the aggressive depressurization and permeability improvement were applied to these two systems for the effectiveness verification. Based on the 15-year simulation results, it was found that the middle low-permeability silt-dominated layers in the reservoir held the key to the gas recovery enhancement, and for the single-vertical-well system, the permeability improvement in this sublayer seemed more reliable and feasible than the aggressive depressurization. On the other hand, the dual-vertical-well system significantly exceeded the single-vertical-well system due to the synergistic effect of the two wellbores, and could raise the average gas production rate (9.5 × 103 m3/day) by one order of magnitude (to 7.9 × 104 m3/day). Moreover, if this new system was combined with the aggressive depressurization, the average gas production rate could be further raised by one order of magnitude (to 3.4 × 105 m3/day).

AbstractA bioreactor system composed of a stirred tank and three tubular bioreactors in series was established, and continuous ethanol fermentation was carried out using a general Saccharomyces cerevisiae strain and a very high gravity medium containing 280 g L−1 glucose, supplemented with 5 g L−1 yeast extract and 3 g L−1 peptone. Sustainable oscillations of glucose, ethanol, and biomass were observed when the tank was operated at the dilution rate of 0.027 h−1, which significantly affected ethanol fermentation performance of the system. After the tubular bioreactors were packed with 1/2″ Intalox ceramic saddles, the oscillations were attenuated and quasi‐steady states were achieved. Residence time distributions were studied for the packed bioreactors by the step input response technique using xylose as a tracer, which was added into the medium at a concentration of 20 g L−1, indicating that the backmixing alleviation assumed for the packed tubular bioreactors could not be established, and its contribution to the oscillation attenuation could not be verified. Furthermore, the role of the packing's yeast cell immobilization in the oscillation attenuation was investigated by packing the tubular bioreactors with packings with significant difference in yeast cell immobilization effects, and the experimental results revealed that only the Intalox ceramic saddles and wood chips with moderate yeast cell immobilization effects could attenuate the oscillations, and correspondingly, improved the ethanol fermentation performance of the system, while the porous polyurethane particles with good yeast cell immobilization effect could not. And the viability analysis for the immobilized yeast cells illustrated that the extremely lower yeast cell viability within the tubular bioreactors packed with the porous polyurethane particles could be the reason for their inefficiency, while the yeast cells loosely immobilized onto the surfaces of the Intalox ceramic saddles and wood chips could be renewed during the fermentation, guaranteeing their viability and making them more efficient in attenuating the oscillations. The packing Raschig rings without yeast cell immobilization effect did not affect the oscillatory behavior of the tubular bioreactors, further supporting the role of the yeast cell immobilization in the oscillation attenuation. Biotechnol. Bioeng. 2009;102: 113–121. © 2008 Wiley Periodicals, Inc.

This study highlights how Chinese economic development detrimentally impacted water quality in recent decades and how this has been improved by enormous investment in environmental remediation funded by the Chinese government. To our knowledge, this study is the first to describe the variability of surface water quality in inland waters in China, the affecting drivers behind the changes, and how the government-financed conservation actions have impacted water quality. Water quality was found to be poorest in the North and the Northeast China Plain where there is greater coverage of developed land (cities + cropland), a higher gross domestic product (GDP), and higher population density. There are significant positive relationships between the concentration of the annual mean chemical oxygen demand (COD) and the percentage of developed land use (cities + cropland), GDP, and population density in the individual watersheds (p < 0.001). During the past decade, following Chinese government-financed investments in environmental restoration and reforestation, the water quality of Chinese inland waters has improved markedly, which is particularly evident from the significant and exponentially decreasing GDP-normalized COD and ammonium (NH4+-N) concentrations. It is evident that the increasing GDP in China over the past decade did not occur at the continued expense of its inland water ecosystems. This offers hope for the future, also for other industrializing countries, that with appropriate environmental investments a high GDP can be reached and maintained, while simultaneously preserving inland aquatic ecosystems, particularly through management of sewage discharge.

Abstract Synthetic hyperaccumulator biomass (SHB) impregnated with Ni, Zn, Cu, Co or Cr was used to conduct 11 experiments in a lab-scale fluidized bed reactor. Two runs with blank corn stover, with no metal added, were also conducted. The reactor was operated in an entrained mode in a oxygen-free (N2) environment at 873 K and 1 atm . The apparent gas residence time through the lab-scale reactor was 0.6 s at 873 K . The material balance for the lab-scale experiments on N2-free basis varied between 81% and 98%. The presence of a heavy metal in the SHB decreased the char yield and increased the tar yield, compared to the blank. The char and gas yields appeared to depend on the form of the metal salt used to prepare the SHB. However, the metal distribution in the product streams did not seem to be influenced by the chemical form of the metal salt used to prepare the SHB. Greater than 98.5% of the metal in the product stream was concentrated in the char formed by pyrolyzing and gasifying the SHB in the reactor. The metal concentration in the char varied between 0.7 and 15.3% depending on the type of metal in the SHB. However, the metal concentration was increased 4 to 6 times in the char compared to the feed.

Microbial fuel cell (MFC) is an emerging biotechnology to convert the organic substrates in wastewater to electricity by anaerobic electrogenic bacteria. The main challenge for MFC research is to elucidate the fundamental mechanisms of electron generation and transfer and to apply these mechanisms to improve the power production in the engineering operation. This study extensively investigated the effects of three inocula (Geobacter sulfurreducens, soil, and wastewater) on the power production and electrochemical characteristics (i.e., internal resistances, Coulombic Efficiency) of MFCs. The results showed that the extents of bacterial adhesion varied between mixed cultures (soil) and pure cultures (G. sulfurreducens). The voltage output increased 30% when bacterial adhesion was well-developed in the soil inocula. Meanwhile, the inoculum types clearly affected the internal resistance (R(in)) and power production of MFCs. Pure culture inoculum (G. sulfurreducens) had the lowest R(in) (165 Omega) and the highest Coulombic Efficiency (CE, 25.8%) and Energy Conversion Efficiency (ECE, 7.2%), while the mixed culture inocula (soil) with the high concentration of nonelectrogenic bacteria, exhibited the highest R(in) (620 Omega), lowest CE (9.2%) and lowest ECE (2.4%). Additionally, a second-order correlation was established between the anode potential (P(A)) and power output while an exponential correlation was established between the difference between anode and cathode potentials (DeltaP(C-A)) and power output.