• Energy Research
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The increasing number of consumers possessing a global mindset has led to the emergence of environmentally friendly materialist consumers who find pleasure in owning environmentally friendly brands and products. We examine why and how such consumers emerge by studying consumers of luxury apparel products, which actively promote environmentally conscious values on a global scale. Structural equation modeling and mediation analysis were conducted on consumers in China and Japan—two countries with high consumption of this product category and a contrasting awareness of environmental consciousness. Our findings revealed that the higher the global mindset of consumers, environmentally friendly materialism is enhanced by internal motives in countries with high environmental consciousness and by external motives in countries with low environmental consciousness. Our results have implications for mechanisms on how the conditions for the emergence of environmentally friendly materialism differ from country to country and marketing measures that respond to these differences.

Abstract This paper reviews the current status of biodiesel production mainly under supercritical conditions. Various methods such as homogeneous acid- and alkali-catalyzed transesterification, heterogeneous acid and alkali-catalyzed transesterification, enzyme-catalyzed transesterification, and supercritical reactions have been employed so far to synthesize biodiesel. Herein, we review the reaction mechanisms and experimental results for these approaches. Recently, supercritical biodiesel production has undergone a vigorous development as the technology offers several advantages over other methods, including the fact that it does not require a catalyst, short residence time, high reaction rate, no pretreatment requirement, and applicability to a wide variety of feedstock. This technology was first designed for biodiesel production using methanol and ethanol. Biodiesel production without glycerol as a byproduct is attractive and has been achieved using supercritical methyl acetate and dimethyl carbonate (DMC). Most recently, biodiesel production in supercritical tert-butyl methyl ether (MTBE) has been developed also. In this review, supercritical biodiesel production will be discussed in detail. Empirical rate expressions are derived for biodiesel production in supercritical methanol, ethanol, methyl acetate, DMC, and MTBE in this study for the first time. These rate equations are critical to predicting biodiesel yields and to comparing the reaction behaviors in different solvents. Lastly challenges for improving energy recovery in supercritical biodiesel production and recommendations for future work are provided.

Controlling the morphological structure of titanium dioxide (TiO2) is crucial for obtaining superior power conversion efficiency for dye‐sensitized solar cells. Although the sol–gel‐based process has been developed for this purpose, there has been limited success in resisting the aggregation of nanostructured TiO2, which could act as an obstacle for mass production. Herein, we report a simple approach to improve the efficiency of dye‐sensitized solar cells (DSSC) by controlling the degree of aggregation and particle surface charge through zeta potential analysis. We found that different aqueous colloidal conditions, i.e., potential of hydrogen (pH), water/titanium alkoxide (titanium isopropoxide) ratio, and surface charge, obviously led to different particle sizes in the range of 10–500 nm. We have also shown that particles prepared under acidic conditions are more effective for DSSC application regarding the modification of surface charges to improve dye loading and electron injection rate properties. Power conversion efficiency of 6.54%, open‐circuit voltage of 0.73 V, short‐circuit current density of 15.32 mA/cm2, and fill factor of 0.73 were obtained using anatase TiO2 optimized to 10–20 nm in size, as well as by the use of a compact TiO2 blocking layer.

The purpose of this study is to examine a dynamic interdependence between national and interregional growth, money, monetary policy, residential structures, spatial amenity, price of goods, land rent, housing rent in a comprehensive analytical framework. The economy consists of multiple regions and each region has industrial and housing sectors. The model is a synthesis of the four models in the growth theory, urban economics and monetary economics in a multi-regional context. Industrial production and capital accumulation follow the Solow model. Regional population distributes over the urban area according to the Alonso model and regional housing production follows the Muth model. The microeconomic foundation for determining time distribution, savings, spatial location and consumption follows the approach proposed by Zhang. We simulate the model and examine effects of changes in some parameters.

AbstractCOURSE 50 aims at developing technologies to reduce CO2 emissions by approximately 30% through suppression of CO2 emissions from blast furnaces as well as capture - separation and recovery - of CO2 from blast furnace gas (BFG), and establishing the technologies by ca. 2030 with the final goal of industrializing and transferring the developed technologies by 2050.(CO2 Ultimate Reduction in Steelmaking process by Innovative technology for cool Earth 50)

Land degradation poses a major threat to agricultural production and food security in Ethiopia, and sustainable land management (SLM) is key in dealing with its adverse impacts. This paper examines the covariates that shape rural livelihood diversification and examines their effects on the intensity of adoption of SLM practices. Household-level data were collected in 2017 from 270 households in three drought-prone watersheds located in northwestern Ethiopia. We used the Herfindahl–Simpson diversity index to explore the extent of livelihood diversification. A stochastic dominance ordering was also employed to identify remunerative livelihood activities. A multivariate probit model was employed to estimate the probability of choosing simultaneous livelihood strategies, and an ordered probit model was estimated to examine the effect of livelihood diversification on the adoption intensity of SLM practices. In addition to mixed cropping and livestock production, the production of emerging cash crops (e.g., Acacia decurrens for charcoal, and khat) dominated the overall income generation of the majority of farmers. Stress/shock experience, extent of agricultural intensification, and agro-ecology significantly affected the probability of choosing certain livelihood strategies. Livelihood diversification at the household level was significantly associated with the dependency ratio, market distance, credit access, extension services, membership in community organizations, level of income, and livestock ownership. A greater extent of livelihood diversification had a significant negative effect on adopting a greater number of SLM practices, whereas it had a positive effect on lower SLM adoption intensity. Overall, we found evidence that having greater livelihood diversification could prompt households not to adopt more SLM practices. Livelihood initiatives that focus on increasing shock resilience, access to financial support mechanisms, improving livestock production, and providing quality extension services, while also considering agro-ecological differences, are needed. In addition, development planners should take into account the livelihood portfolios of rural households when trying to implement SLM policies and programs.

Abstract In core disruptive accident (CDA) of sodium-cooled fast reactors (SFRs), fuel and steel can melt to form a molten pool. The objective of the present work is to investigate design measures for core of SFR to prevent recriticality. This paper studied core geometry of convex cross-section shape to increase neutron leakage from core surface in case of core compaction. In order to evaluate effective neutron multiplication factor, 70-group neutron diffusion calculations were performed by changing parameters related to the convex core geometry (i.e. ratio of inner height to inner diameter). Neutron diffusion code and nuclear data library employed in those calculations are CITATION and JENDL-3.3, respectively. By optimizing core configuration, the compaction reactivity of the convex shaped core showed drastic reduction from 2.07 % of reference cylindrical core (Japan Sodium-cooled Fast Reactor) to -3.28 %.

AbstractWater is the only available fossil-free source of hydrogen. Splitting water electrochemically is among the most used techniques, however, it accounts for only 4% of global hydrogen production. One of the reasons is the high cost and low performance of catalysts promoting the oxygen evolution reaction (OER). Here, we report a highly efficient catalyst in acid, that is, solid-solution Ru‒Ir nanosized-coral (RuIr-NC) consisting of 3 nm-thick sheets with only 6 at.% Ir. Among OER catalysts, RuIr-NC shows the highest intrinsic activity and stability. A home-made overall water splitting cell using RuIr-NC as both electrodes can reach 10 mA cm−2geo at 1.485 V for 120 h without noticeable degradation, which outperforms known cells. Operando spectroscopy and atomic-resolution electron microscopy indicate that the high-performance results from the ability of the preferentially exposed {0001} facets to resist the formation of dissolvable metal oxides and to transform ephemeral Ru into a long-lived catalyst.