• Energy Research
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This study introduces novel phenothiazine-based organic dyes, 2-LBH-100, 2-LBH-44, and 2-Ryu-4, specifically designed for quasi-solid-state dye-sensitized solar cells (QsDSSCs). Employing a donor-π-acceptor architecture, these dyes incorporate varying electron-donating moieties, including bis(3-(hexyloxy)phenyl)amine and diphenylamino, coupled with a cyanoacrylic acid acceptor. Alkoxy substitutions in 2-LBH-100 and 2-LBH-44 enhanced solubility and dye loading on TiO2, leading to improved performance in QsDSSCs. 2-LBH-100 exhibited a power conversion efficiency (PCE) exceeding 5% with excellent stability, while 2-LBH-44 demonstrated a PCE of over 3%, increasing to 4% over time. 2-Ryu-4, with its diphenylamino donor, achieved an initial PCE of over 6%. This research highlights the crucial role of donor–acceptor interactions in optimizing organic dye design for high-performance QsDSSCs, paving the way for efficient and stable next-generation solar energy technologies.

This deliverable includes the methodology in EnergyPROSPECTS for an in-depth study of energy citizenship. It features the criteria used for selecting the cases for indepth study, the list of cases selected for in-depth study as well as key research foci and empirical research questions.

The disposal area of a deep geological repository (DGR) for the disposal of spent nuclear fuels (SNFs) is estimated considering the spacing between deposition holes and between disposal tunnels, as determined by a thermal analysis using the decay heat of a reference SNF. Given the relatively large amount of decay heat of the reference SNF, the disposal area of the DGR is found to be overestimated. Therefore, we develop a computer program using MATLAB, termed ACom (Assembly Combination), to combine SNFs when stored in canisters such that the decay heat per canister is evenly distributed. The stability of ACom was checked and the overall distribution of the decay heat per canister was analyzed. Finally, ACom was applied to disposal scenarios suggested in the conceptual design of a DGR for SNFs, and it was confirmed that the decay heat per canister could be evenly distributed and that the maximum decay heat of the canister could be much lower than that of a canister estimated using a reference SNF. ACom can be used to improve the disposal efficiency by reducing the disposal area of a DGR for SNFs by ensuringg a relatively even distribution of decay heat per canister.

Research on digital twins (DTs) in the power system field has mainly focused on implementing DTs for specific resources, while few studies on electric vehicle (EV)-based DT implementation have considered integration and interoperability between systems. This study introduces a DT-based EV system operation framework to address the aforementioned research gap. The framework implements individual EVs, charging stations, and charging station operators (CPOs) as DTs, enabling integrated operation with the power grid. The DT-based EV agent supports independent decision-making on power service participation by considering location information, distance, charging amount, spare time, and incentives. In addition, the CPO can establish an optimal incentive strategy to induce EV users to participate in grid power services. The proposed DT systems map information between EVs, charging stations, and the grid, enabling analysis and verification of the impact of participants on charging station operation, grid stability, and economic efficiency in an independent environment. The effectiveness and usability of the proposed framework were verified through a case study on an incentive-based demand response program.

Lithium-ion batteries exhibit a dynamic voltage behaviour depending nonlinearly on current and state of charge. The modelling of lithium-ion batteries is therefore complicated and model parametrisation is often time demanding. Grey-box models combine physical and data-driven modelling to benefit from their respective advantages. Neural ordinary differential equations (NODEs) offer new possibilities for grey-box modelling. Differential equations given by physical laws and NODEs can be combined in a single modelling framework. Here we demonstrate the use of NODEs for grey-box modelling of lithium-ion batteries. A simple equivalent circuit model serves as a basis and represents the physical part of the model. The voltage drop over the resistor–capacitor circuit, including its dependency on current and state of charge, is implemented as a NODE. After training, the grey-box model shows good agreement with experimental full-cycle data and pulse tests on a lithium iron phosphate cell. We test the model against two dynamic load profiles: one consisting of half cycles and one dynamic load profile representing a home-storage system. The dynamic response of the battery is well captured by the model.

Abstract Electricity markets in Europe become increasingly interconnected due to new grid connections and market coupling regulations. This paper examines the interdependencies between the Swiss electricity market and those of neighbouring countries. The Swiss market serves as a good example for a smaller electricity market which is increasingly affected by developments in the large neighbouring countries. To study these cross-border effects, especially those on Swiss electricity prices, we apply two different methodologies, an econometric and a Nash-Cournot equilibrium model. The analyses show that the Swiss electricity price correlates strongly with the German electricity price in the summer, but tends to follow the French electricity price in the winter. Another finding is that gas prices and the electricity load of neighbouring countries have a significant influence on prices. In particular, the load of France and Italy is driving up Swiss prices in the winter, while the German electricity demand and renewable energy generation have a larger influence on Swiss prices in the summer.

Installations of an Energy Storage System (ESS) with various functions such as power stabilization of renewable energy, demand management, and frequency adjustment are increasing. In particular, ESS for demand management is being established for high-voltage customers (300 KVA–1000 KVA) who have placed an Auto Section Switch (ASS) at the connection point within the distribution system. However, a power outage may occur in the Power Receiving System (PRS) when a short-circuit fault due to insulation breakdown occurs at the ESS DC side. The reason for this breakdown is that the fault current is reduced by transformer impedance, and the ASS is opened before the DC power fuse. Therefore, using the Graphic Solution Method (GSM), this paper presents an operation algorithm for protection coordination that isolates the fault section by first operating the DC power fuse with a small fault current. Furthermore, fault analysis modeling for a PRS composed of a switchgear section, a main distribution panel, a Power Conditioning System (PCS), a power fuse, and a battery is performed through PSCAD/EMTDC. From the simulation results, it is confirmed that the fault section is quickly isolated, and power outages for high-voltage customers are prevented because the DC power fuse selected by the proposed operation algorithm of protection coordination is opened before the ASS.

This article makes the central argument that basic democratic values such as justice, autonomy and participation run the risk of being neglected when designing ‘nudges’ (i.e., indirect suggestions to influence individual behaviour) for sustainable behaviour change in the context of food governance, potentially complicating a democratisation of the food system. ‘Nudges’ uphold freedom of choice while simultaneously advocating a non-coercive soft force of paternalism to help people realise their preferences, maximise societal well-being and meet macro-sustainability goals. While the promises of the ‘nudge’ approach are widely echoed, nudging is also being contested because of its possible anti-democratic effects, such as individualisation, depoliticization and the emphasis of the status of citizens as ‘consumer-citizens.’ From a food democracy perspective, these dangers may undermine efforts to organise collective political action and impede alternative visions of a future food system. Empirically, the article examines specifically how behavioural-economic approaches imagine transitions to a more sustainable food system. By using the “COOP Supermarket of the Future” as a case study, the following analysis will illustrate how private actors are increasingly involved in steering consumer choice towards socially desirable actions. The analysis suggests that the design of choice environments may under specific circumstances increase the susceptibility of individuals to the influence of corporate preferences and simultaneously decrease the prospects for democratic legitimation and decision-making. The article therefore critically assesses whether reforming the food system by altering consumers’ choice-sets and the attribution of personal responsibility, may in fact point towards implicit anti-democratic tenets underlying the ‘will to nudge’ citizens.