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An innovative approach was developed by incorporating high-pressure CO2 into the separate hydrolysis-fermentation of aspen leftover branches, aiming to enhance the bioethanol production efficiency. The high-pressure CO2 significantly increased the 72-h enzymatic hydrolysis yield of converting aspen into glucose from 53.8% to 82.9%. The hydrolysis process was performed with low enzyme loading (10 FPU g-1 glucan) with the aim of reducing the cost of fuel bioethanol production. The ethanol yield from fermentation of the hydrolyzed glucose using yeast (Saccharomyces cerevisiae) was 8.7 g L-1, showing increment of 10% compared with the glucose control. Techno-economic analysis indicated that the energy consumption of fuel bioethanol production from aspen branch chips was reduced by 35% and the production cost was cut 44% to 0.615 USD L-1, when 68 atm CO2 was introduced into the process. These results furtherly emphasized the low carbon footprint of this sustainable energy production approach.

In this research, efforts were put to demonstrate synergistic interactions between bioenergy generation and wastewater treatment. The extent of such synergistic effect was assessed against wastewater effluents released from the beverage industry through the operation of a membrane-less truncated conical (TC) microbial fuel cell (MFC). A graphite-based reactor was operated for five cycles in batch mode using beverage industry wastewater as an organic substrate. Maximum bioelectricity produced on the fifth operating cycle corresponded to a voltage of 338 mV and a power of 1.14 mW at 100 Ω. The MFC recorded a higher substrate degradation rate (0.84 kg of chemical oxygen demand [COD]/m3-day) accompanied by the development of an electroactive biofilm and polarization behavior (e.g., a reduction in internal resistance from 323 Ω to 197 Ω over five operation cycles). Cyclic voltammetry showed a maximum performance of the biofilm during the fifth cycle (through its enrichment) as interpreted by oxidation and reduction currents of 2.48 and -2.21 mA, respectively. The performance of the proposed MFC was superior to other designs reported previously in both effluent treatment and bioenergy generation. A maximum treatment efficiency of 84.4% (in 385 h) was seen at an organic load (COD) of 3500 mg/L with the specific power yield (0.504 W/Kg of substrate (COD) removal) and volumetric power yield (15.03 W/m3). Our experimental studies support that the proposed system could be upscaled to realize the commercial operation.

ABSTRACTNepal, a country rich in biomass, still does not have any commercial pellet production plants and is wasting large amounts of agricultural crop residue. The current study showed that about 5.61 million tonnes (Mt) of biomass in the form of pellets are potentially available from agricultural crop residues. The brick and cement industries could use these agro-pellets. Co-firing of pellets in such industries could play an important role in reducing the import volume of coal and minimize the related environmental loadings.

The separation of biogas leads to not only recovery and sequestration of CO2, but also to much greater purification and recovery of value-added CH4 able to be used, for example, to directly feed pipelines for domestic or small plants. In this work, an alternative approach for a preliminary design of separation process based on the use of polymeric membranes is proposed. Two different types of polymeric membranes were taken into account, Hyflon AD60 and Matrimid 5218, the first showing a higher permeability with respect to other membranes but a quite low selectivity (12.9), the second exhibiting a higher selectivity with respect to other membranes (41 and 100) even though a lower permeability. Four possible operation schemes using two different types of membranes in multistage configuration system are analysed as functions of the main design parameters, i.e., pressure ratio and permeation number. The achieved results are compared with certain targets and are also discussed in terms of process metrics, according to the Process Intensification strategy. This latter analysis, coupled with a conventional one, provides an alternative point of view over the evaluation of the plant performance taking into account not only the final characteristics of the streams but also process efficiency, exploitation of raw material and energy, and the footprint occupied by the installation.

Abstract This paper recognizes the synergetic relationship and inextricable linkage between conservation and sustainability. Heritage preservation maximizes the use of existing materials and infrastructure, reduces waste, and preserves the historic character of older towns and cities. This paper also presents technical advances in BPS/BES (Building Performance Simulation/Building Energy Simulation), and in co-simulation for energy efficiency optimization, RES integrated historic building's greening and historic neighborhoods, settlements, as well as whole cities urban re-planning. Further, the paper presents initial results of the Aviation Museum in Belgrade preliminary energy refurbishment study focusing results obtained via BPS and co-simulation. Foreseen is the deep energy refurbishment aimed to reach the “total building performance optimization” encompassing multifunctional optimization of building's skin – glazing replacement with the semi-transparent PV glazing and day-lighting control with reference to the artifact preservation, as well as the IEQ (Indoor Environment Quality) control analysis. This study shows that the RES integrated refurbishment can result in the Museum's Zero CO2 emission and even in the sustainable Energy + status (producing more than using electricity). Finally, needs for most current ICT knowledge use and refurbishment technologies development, as well as integrated design, including particularly relevant benchmarking and rating system development are outlined.

The phenomena of global warming have increased the frequency of natural disasters. These disasters generate thousands of tons of waste and cause loss of human lives, environmental damages, and economic losses every year. Currently, disaster response policies are reactive in nature to bring the community back to normal routine. However, increased resilience against future disasters can be achieved by working on long-term planning and setting goals for ecological, economic, and social sustainability in disaster response policies. Keeping in view the importance of the considered issue, this study proposes a large-scale disaster waste management supply chain model, considering economic aspect via total waste processing, environmental aspect by greenhouse gas emissions from disaster waste processing, and social aspect by job opportunities generated during waste processing. To demonstrate the applicability of the proposed supply chain model, numerical experiments are performed on a large-scale case problem. Results show that there is a strong trade-off among the dimensions of sustainability. If decision makers want to achieve higher satisfaction levels against environmental and social objectives, the operational cost of waste management will increase accordingly. Numerical studies obtain the results in accordance with the values of the confidence level of decision makers and coefficient of compensation decided by the managers which also provides the flexibility for the decision makers of developing countries to obtain preferred compromised solution in accordance with their own preferences for the dimensions of sustainability during disaster waste management operation.

The Amazon rainforest has sustained human existence for more than 10,000 years. Part of this has been the way that the forest controls regional climate including precipitation important for the ecosystem as well as agroforestry and farming. In addition, the Amazon also affects the global weather systems, so cutting down the rainforest significantly increases the effects of climate change, threatening the world's biodiversity and causing local desertification and soil erosion. The current fire activities and deforestation in the Amazon rainforest therefore have consequences for global sustainability. In the light of this, the current decisions made in Brazil regarding an increase in Amazon deforestation require policy changes if the global ecosystems and biodiversity are not to be set to collapse. There is only one way to move forward and that is to increase efforts in sustainable development of the region including limitation in deforestation and to continuously measure and monitor the development. The G7 countries have offered Brazil financial support for at least 20 million euros for fighting the forest fires but the president denies receiving such financial support and says that it is more relevant to raise new forests in Europe. In fact, this is exactly what is happening in Denmark and China in order to reduce climate change. Such activities should be global and include South America, Europe, Africa and Asia where deforestation is important issue. Forest restoration reduces climate change, desertification, and preserves both the regional tropical and global environment if the wood is not burned at a later stage but instead used in e.g. roads as filling material. Changes are therefore needed through improved international understanding and agreements to better avoid the global climate changes, from cutting down the precious rainforest before it is too late as rainforest cannot be re-planted.

Although desalination market is today dominated by Seawater Reverse Osmosis (SWRO), important technological issues remain unaddressed, specifically: relatively low water recovery factor (around 50%) and consequent huge amount of brine discharged, and energy consumption (3-5 kWh/m3) still far from the minimum thermodynamic value (~1 kWh/m3). Herein, the energy performance of an innovative systems combining SWRO, Membrane Distillation (MD) and Reverse Electrodialysis (RED) for simultaneous production of water and energy is investigated. The valorization of hypersaline waste brine by Salinity Gradient Power production via RED and the achievement of high recovery factors (since MD is not limited by osmotic phenomena) represent a step forward to the practical implementation of Zero Liquid Discharge and low-energy desalination. The analysis is supported by lab-scale experimental tests carried out on MD and RED over a broad set of operational conditions. Among the different case studies investigated, exergetic efficiency reached 49% for the best scenario, i.e. MD feed temperature of 60°C, MD brine concentration of 5M NaCl, RED power density of 2.2 W/m2MP (MP: membrane pair). Compared to the benchmark flowsheet (only SWRO), up to 23% reduction in electrical energy consumption and 16.6% decrease in specific energy consumption were achieved when including a RED unit. The analysis also indicates that optimization of thermal energy input at the MD stage is critical, although it can potentially be fulfilled by lowgrade waste heat or solar-thermal renewable sources. Overall, the proposed integrated system is coherent with the emergent paradigm of Circular Economy and the logic of Process Intensification.