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In old age, the complex relation of food consumption with energy and nutrient requirements finds expression in both single and multiple nutritional problems. Addressing conditions affecting intake -- either from foods or from supplements -- endogenous production, bioefficacy and/or requirements can benefit nutritional health in old age through balancing requirements and supply.

In old age, the complex relation of food consumption with energy and nutrient requirements finds expression in both single and multiple nutritional problems. Addressing conditions affecting intake -- either from foods or from supplements -- endogenous production, bioefficacy and/or requirements can benefit nutritional health in old age through balancing requirements and supply.

In our continued efforts in the synthesis of ruthenium(II) polypyridine complexes as potential dyes for use in varied applications, such as the dye-sensitized solar cells (DSSCs), this work particularly describes the synthesis, absorption spectrum, redox behavior and luminescence properties of a new homoleptic ruthenium(II) complex bearing a simple trans-2-methyl-2-butenoic acid functionality as the anchoring ligand on terpyridine moiety. The functionalized terpyridine ligand: 4’-(trans-2-methyl-2-butenoic acid)-terpyridyl (L1) was synthesized by aryl bromide substitution on terpyridine in a basic reaction condition under palladium carbide catalysis. In particular, the photophysical and redox properties of the complex formulated as: bis-4’-(trans-2-methyl-2-butenoic acid)-terpyridyl ruthenium(II) bis-hexafluorophosphate [Ru(L1)2(PF6)2] are significantly better compared to those of [Ru(tpy)2]2+ and compare well with those of the best emitters of Ru(II) polypyridine family containing tridentate ligands. Reasons for the improved photophysical and redox properties of the complex may be attributed partly to the presence of a substituted α,β-unsaturated carboxylic acid moiety leading to increase in the length of π-conjugation bond thereby enhancing the MLCT-MC (Metal-to-ligand-charge transfer-metal centred) energy gap, and to the reduced difference between the minima of the excited and ground states potential energy surfaces.

In our continued efforts in the synthesis of ruthenium(II) polypyridine complexes as potential dyes for use in varied applications, such as the dye-sensitized solar cells (DSSCs), this work particularly describes the synthesis, absorption spectrum, redox behavior and luminescence properties of a new homoleptic ruthenium(II) complex bearing a simple trans-2-methyl-2-butenoic acid functionality as the anchoring ligand on terpyridine moiety. The functionalized terpyridine ligand: 4’-(trans-2-methyl-2-butenoic acid)-terpyridyl (L1) was synthesized by aryl bromide substitution on terpyridine in a basic reaction condition under palladium carbide catalysis. In particular, the photophysical and redox properties of the complex formulated as: bis-4’-(trans-2-methyl-2-butenoic acid)-terpyridyl ruthenium(II) bis-hexafluorophosphate [Ru(L1)2(PF6)2] are significantly better compared to those of [Ru(tpy)2]2+ and compare well with those of the best emitters of Ru(II) polypyridine family containing tridentate ligands. Reasons for the improved photophysical and redox properties of the complex may be attributed partly to the presence of a substituted α,β-unsaturated carboxylic acid moiety leading to increase in the length of π-conjugation bond thereby enhancing the MLCT-MC (Metal-to-ligand-charge transfer-metal centred) energy gap, and to the reduced difference between the minima of the excited and ground states potential energy surfaces.

The flow field in a subsonic vaned radial diffuser of a single-stage centrifugal compressor is numerically investigated using a three-dimensional Navier–Stokes solver (TASCflow) and a two-dimensional analysis and inverse-design software package (MISES). The vane geometry is modified in the leading edge area (two-dimensional blade shaping) using MISES, without changing the diffuser throughflow characteristics. An analysis of the two-dimensional and three-dimensional effects of two redesigns on the flow in each of the diffuser subcomponents is performed in terms of static pressure recovery, total pressure loss production, and secondary flow reduction. The computed characteristic lines are compared with measurements, which confirm the improvement obtained by the leading edge redesign in terms of increased pressure rise and operating range.

The flow field in a subsonic vaned radial diffuser of a single-stage centrifugal compressor is numerically investigated using a three-dimensional Navier–Stokes solver (TASCflow) and a two-dimensional analysis and inverse-design software package (MISES). The vane geometry is modified in the leading edge area (two-dimensional blade shaping) using MISES, without changing the diffuser throughflow characteristics. An analysis of the two-dimensional and three-dimensional effects of two redesigns on the flow in each of the diffuser subcomponents is performed in terms of static pressure recovery, total pressure loss production, and secondary flow reduction. The computed characteristic lines are compared with measurements, which confirm the improvement obtained by the leading edge redesign in terms of increased pressure rise and operating range.

AbstractIn this work, the drying step for cathodes based on carbon‐coated LiFePO4 prepared in the temperature range of 60–120 °C has been investigated in detail. The microstructure of the cathode shows a homogeneous distribution of the active material and conductive additive particles independent of the drying temperature. However, the results of impedance spectroscopy and cycling voltammetry are affected by the drying temperature. The solvent evaporation temperature, therefore, affects the polymer binder distribution and its characteristics, which include the polar phase content of the polymer and its affinity with the other components of the cathode. The discharge capacity value after 50 cycles is 120 and 81 mAh g−1 for the samples dried at 80 and 60 °C, respectively, which show the best and worst battery performance, respectively. It was concluded that carbon‐coated LiFePO4 cathodes should be prepared at drying temperatures between 80 and 100 °C for optimized performance.