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Abstract CBM reservoirs are extremely vulnerable to damage due to their complex pore structure. So, changing pore structures in CBM reservoirs is of vital importance for reducing reservoirs damage. Organic solvents have been considered as additives into fracturing fluids to enhance production because they can enhance the pore connectivity and loosening macromolecular network structure. It is thus of great interests to investigate how organic solvents (ethanol and ethylene glycol ether) change micropore structures and fluid distribution. In this study, samples were selected from different wells completed in No. 3 coal seam, Zhaozhuang minefield. Low-pressure nitrogen adsorption (LP-N2GA) experiments were conducted on coal samples to evaluate the changes in pore-structure parameters including specific surface area (SSA), pore diameter, and pore volume. NMR experiments were conducted on coal samples to evaluate the changes in fluid distribution. Analyzing the LP-N2GA results suggests ethylene glycol ether and ethanol can effectively increase SSA, pore diameter, and opening degree of pores in coal samples. Comparative analysis of NMR results indicates that ethylene glycol ether consistently reduces the irreducible water saturation (Swir) in samples. The average value of Swir of raw samples is 0.8670 and the average value of Swir of samples treated with ethylene glycol ether value is 0.7644. Considering the pore-structure alterations, this study demonstrates that ethylene glycol ether is more preferable for enhancing recovery from CBM reservoirs compared with ethanol.

Daily rainfall is measured as the total (mm) over the 24-hour period 0900 to 0900 GMT. It includes all precipitation - snow, rain, mist and fog. Rainfall was first recorded at Rothamsted in March 1853, using a copper funnel rain gauge (5 inch / 12.7 cm diameter) and measured using a graduated cylinder. Since 2004 it has been measured using an electronic tipping bucket rain gauge (10 inch / 25.4cm diameter), ARG100, calibrated to tip at 0.2mm (which has since become the minimum amount of rain that can be recorded). The rain gauge is placed within a 30cm deep 1.5m radius turf wall, retained by brick, to reduce wind eddies that may potentially blow rain out of the gauges. Data were collected daily manually until 2004 and since then by Automatic Weather Station using a standard protocol. There are differences in the capture rate between the two gauges, see Rainfall for further information. The monthly summary data contained in this spreadsheet are derived from daily data measured at Rothamsted Meteorological Station, Harpenden. Total monthly data is determined from daily data using Genstat 19th Edition. Verification includes checks for instrument errors, for missing data and outliers. The original raw daily data is available, after registering, from the e-RA database. Please contact the e-RA Curators for an access password and further details. This dataset represents the mean monthly rainfall recorded at Rothamsted from October 1985 - September 2017 and is derived from continuous daily records measured at the site. Location: Rothamsted Meteorological Station, Harpenden, Hertfordshire, England 51.82 N 0.37 W 128 m asl.

Comparison of the water budget for the typical cropland and pear orchard ecosystems in the North China Plain Comparison of the water budget for the typical cropland and pear orchard ecosystems in the North China Plain

Virtual water flows have a profound impact on the natural water system of a country or region, and they may help conserve local water resources or exacerbate water scarcity in some areas. However, current research has only focused on the measurement of virtual water flows, without analysis of the causes of virtual water flow patterns. This study first obtained virtual water flow patterns across provinces by constructing a multi-regional input–-output (MRIO) model of the Yellow River basin in 2012 and 2017, and then analyzed its driving factors by applying the extended STIRPAT model to provide directions for using virtual water trade to alleviate water shortages in water-scarce areas of the basin. We found the following: (1) The Yellow River basin as a whole had a net virtual water inflow in 2012 and 2017, and the net inflow has increased from 2.14 billion m3 to 33.67 billion m3. (2) Different provinces or regions assume different roles in the virtual water trade within the basin. (3) There is an obvious regional heterogeneity in the virtual water flows in different subsectors. (4) Per capita GDP, tertiary industry contribution rate, consumer price index, and water scarcity are the main positive drivers of virtual water inflow in the Yellow River Basin provinces, while primary industry contribution rate, per capita water resources, and water use per unit arable area promote virtual water outflow. The results of this paper present useful information for understanding the driving factors of virtual water flow, which could promote the optimal allocation of water resources in the Yellow River basin and achieve ecological protection and high-quality development in this area.

As a porous medium with rich pore structure, activated carbon (AC) was once considered the best carrier for hydrate storage and transportation. However, the harsh conditions of the hydrate reaction in the wet carbon environment have always limited the sufficient and rapid formation of hydrate. Therefore, the influences of particle size (4–8, 8–16, 20–40 and 100 mesh) and liquid phase saturation (fully/partially saturated) in the sodium dodecyl sulfate system on hydrate reaction were investigated. The results showed that small particle in the fully saturated liquid phase system led to the increase in hydrate generation rate, with the highest hydrate reaction rate of 3.16 mmol/min in the 100 mesh AC layer, which was 1.7–2.9 times higher than other AC layers. The gas storage capability of the 4–8 mesh AC layer with a water saturation of 70% was the highest among all systems, reaching 0.198 mol/mol. The saturation of the liquid phase induced the nucleation and growth of hydrates. Adherently growing hydrates of fully saturated liquid phase systems and mushroom-like hydrates of partially saturated liquid phase systems were found in turn. This research facilitates the commercialization of AC-based hydrate technology.

Nitrogen reduction reaction (NRR) and nitrate reduction reaction (NO3−RR) provide a potential sustainable route by which to produce ammonia, a next-generation energy carrier. Many studies have been conducted over the years, mainly emphasizing material design and strategies to improve catalytic performance. Despite significant achievements in material design and corresponding fundamental knowledge, the produced ammonia is still very limited, which makes it prone to bias. The presence of interferants (e.g., cations and sacrificial reagents), the pH of the solution, and improper analytical procedure can lead to the over or underestimation of ammonia quantification. Therefore, the selection of the appropriate ammonia quantification method, which meets the sample solution condition, along with the proper analytical procedures, is of great importance. In this review, the state-of-the-art ammonia quantification method is summarized, emphasizing the advantages, limitations, and practicality for NRR and NO3−RR studies. Fundamental knowledge of the quantification method is introduced. Perspective on the considerations for selecting the suitable quantification method and for performing the quantification process is also provided. Although non exhaustive, this focused review can be useful as a guide to design the experimental setup and procedure for more reliable ammonia quantification results.

Energy Climate dataset consistent with ENTSO-E Pan-European Climatic Database (PECD 2021.3) in CSV and netCDF format TL;DR: this is a nationally aggregated hourly dataset for the capacity factors per unit installed capacity for storage hydropower plants and run-of-river hydropower plants in the European region. All the data is provided for 30 climatic years (1981-2010). Method Description The hydro inflow data is based on historical river runoff reanalysis data simulated by the E-HYPE model. E-HYPE is a pan-European model developed by The Swedish Meteorological and Hydrological Institute (SMHI), which describes hydrological processes including flow paths at the subbasin level. E-hype only provides the time series of daily river runoff entering the inlet of each European subbasin over 1981-2010. To match the operational resolution of the dispatch model, we linearly downscale these time series to hourly. By summing up runoff associated with the inlet subbasins of each country, we also obtain the country-level river runoff. The hydro inflow time series per country is defined as the normalized energy inflows (per unit installed capacity of hydropower) embodied in the country-level river runoff. A dispatch model can be used to decides whether the energy inflows are actually used for electricity generation, stored, or spilled (in case the storage reservoir is already full). Data coverage This dataset considers two types of hydropower plants, namely storage hydropower plant (STO) and run-of-river hydropower plant (ROR). Not all countries have both types of hydropower plants installed (see table). The countries and their acronyms for both technologies included in this dataset are: Country Run-of-River Storage Austria AT_ROR AT_STO Belgium BE_ROR BE_STO Bulgaria BG_ROR BG_STO Switzerland CH_ROR CH_STO Cyprus CZ_ROR CZ_STO Germany DE_ROR DE_STO Denmark DK_ROR Estonia EE_ROR Greece EL_ROR EL_STO Spain ES_ROR ES_STO Finland FI_ROR FI_STO France FR_ROR FR_STO Great Britain GB_ROR GB_STO Croatia HR_ROR HR_STO Hungary HU_ROR HU_STO Ireland IE_ROR IE_STO Italy IT_ROR IT_STO Luxembourg LU_ROR Latvia LV_ROR the Netherlands NL_ROR Norway NO_ROR NO_STO Poland PL_ROR PL_STO Portugal PT_ROR PT_STO Romania RO_ROR RO_STO Sweden SE_ROR SE_STO Slovenia SI_ROR SI_STO Slovakia SK_ROR SK_STO Data structure description The files is provided in CSV (.csv) format with a comma (,) as separator and double-quote mark (") as text indicator. The first row stores the column labels. The columns contain the following: first column (or A) contains the row number Label: unlabeled Contents: interger range [1,262968] second column (or B) contains the valid-time Label: T1h Contents represent time with text as [DD/MM/YYYY HH:MM]) column 3-52 (or C-AY) each contain the capacity factor for each valid combination of a country and hydropower plant type Label: XX_YYY the two letter country code (XX) and the hydropower plant type (YYY) acronym for storage hydropower plant (STO) and run-of-river hydropower plant (ROR) Contents represent the capacity factor as a floating value in the range [0,1], the decimal separator is a point (.). DISCLAIMER: the content of this dataset has been created with the greatest possible care. However, we invite to use the original data for critical applications and studies. The raw hydro data was generated as part of 'Evaluating sediment Delivery Impacts on Reservoirs in changing climaTe and society across scales and sectors (DIRT-X)', this project and therefor, Jing hu, received funding from the European Research Area Network (ERA-NET) under grant number 438.19.902. Laurens P. Stoop received funding from the Netherlands Organization for Scientific Research (NWO) under Grant No. 647.003.005.

AbstractThe integration of power plants and desalination systems has attracted increasing attention over the past few years as an effective solution to tackle sustainable development and climate change issues. In this light, this paper introduces a novel modelling and optimization approach for a combined-cycle power plant (CCPP) integrated with reverse osmosis (RO) and multi-effect distillation (MED) desalination systems. The integrated CCPP and RO–MED desalination system is thermodynamically modelled utilizing MATLAB and EES software environments, and the results are validated via Thermoflex software simulations. Comprehensive energy, exergic, exergoeconomic, and exergoenvironmental (4E) analyses are performed to assess the performance of the integrated system. Furthermore, a new multi-objective water cycle algorithm (MOWCA) is implemented to optimize the main performance parameters of the integrated system. Finally, a real-world case study is performed based on Iran's Shahid Salimi Neka power plant. The results reveal that the system exergy efficiency is increased from 8.4 to 51.1% through the proposed MOWCA approach, and the energy and freshwater costs are reduced by 8.4% and 29.4%, respectively. The latter results correspond to an environmental impact reduction of 14.2% and 33.5%. Hence, the objective functions are improved from all exergic, exergoeconomic, and exergoenvironmental perspectives, proving the approach to be a valuable tool towards implementing more sustainable combined power plants and desalination systems.

Spatio-temporal variations in extreme drought in China during 1961–2015 Spatio-temporal variations in extreme drought in China during 1961–2015