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In the present paper design, realization and testing of a novel small scale adsorption refrigerator prototype based on activated carbon/ethanol working pair is described. Firstly, experimental activity has been carried out for identification of the best performing activated carbon available on the market, through the evaluation of the achievable thermodynamic performance both under air conditioning and refrigeration conditions. Once identified the best performing activated carbon, the design of the adsorber was developed by experimental dynamic performance analysis, carried out by means of the Gravimetric-Large Temperature Jump (G-LTJ) apparatus available at CNR ITAE lab. Finally, the whole 0.5 kW refrigerator prototype was designed and built. First experimental results both under reference air conditioning and refrigeration cycles have been reported, to check the achievable performance. High Specific Cooling Powers (SCPs), 95 W/kg and 50 W/kg, for air conditioning and refrigeration respectively, were obtained, while the COP ranged between 0.09 and 0.11, thus showing an improvement of the current state of the art.

Latent thermal energy storage systems represent a promising alternative to traditional sensible storages, but their exploitation requires a careful design of the system. The present paper reports a mathematical model for the simulation of thermal energy storage systems with phase change materials (PCMs). The model is suitable for the description of a latent heat storage using a fin-and-tube heat exchanger. Accuracy and computational effort are both taken into consideration, by coupling a 1D model for the tubes of the heat exchanger and a reduced 3D model for the material and fin domains. The developed model has been validated for two systems, realised at ITAE and ISE, differing for the PCM employed and the constructive characteristics of the heat exchanger. Results show that the model has a good accuracy and could predict the behaviour of the storages within 40 W error in case of powers and 1 K in case of heat transfer fluid temperatures. When a stable PCM was used, the average deviation between the PCM temperature in experiments and simulation was lower than 0.6 K.

This paper presents a multidisciplinary methodology to estimate the underground heat-exchange potential for Borehole Heat Exchangers (BHEs) coupled with Ground Source Heat Pumps (GSHPs) over wide areas. The proposed methodology was tested in four sites in western Sicily (southern Italy) where the shortage of subsurface geological data, in addition to the undefined authorization processes for this kind of system, is probably the main barrier to planning and exploiting geothermal heat for heating and cooling purposes. Reliable high-resolution 3D geological and petrophysical models were built based on the integration of airborne electromagnetic data and laboratory measurements of the thermal properties of rock samples. A GIS-based procedure was applied to assess the geothermal heat-exchange potential using 3D models of thermal conductivity as the main input. The results of the analyses are represented by thematic maps of the underground heat exchange potential for BHEs coupled with GSHPs. The study areas show a generally high suitability for the use of this technology and several municipalities in the area could take advantage of the resulting maps for energy planning.

AbstractThe rotational spectra of two isotopologues of the 1:1 complex formed between acetone and ethanol have been recorded and analyzed by using Fourier‐transform microwave spectroscopy. One rotamer was detected, in which ethanol adopts the gauche form. The two subunits are linked by a conventional O−H⋅⋅⋅O and a weak C−H⋅⋅⋅O hydrogen bond, forming a six‐membered ring. Each rotational transition is split into five component lines due to the internal rotations of two nonequivalent acetone methyl groups. The V3 barriers to internal rotation of the two CH3 tops of acetone were determined to be 252(4) and 220(1) cm−1, which are noticeably lower than the value for the monomer (266 cm−1).

Thin film technology has reached a maturity to achieve conversion efficiencies of the order of 22%. Among thin films, CdTe-based photovoltaic modules represent 80% of the total production. Nonetheless, some issues concerning back-contact are still open. In industrial process a chemical etching is required in order to make the CdTe film surface rich in Te. The Te-excess is fundamental in order to form a stable telluride compound with copper and to obtain an ohmic, low-resistance back-contact. Moreover, the Te-excess hinders the fast diffusion of copper in CdTe and its achievement of the junction region, preventing the destruction of the device. In this paper we study a ZnTe:Cu buffer layer deposited onto a CdTe film, characterized by a naturally Te-rich surface obtained with a particular chlorine heat treatment without any chemical etching. Copper diffusion and the CdTe/ZnTe:Cu interface were studied by x-ray photoemission spectroscopy (SIPS) and time-of-flight secondary ion mass spectrometry (ToF- SIMS) to deeply analyze the intermixing phenomena and copper behavior inside polycrystalline CdTe film.

Research and development of cost-effective, high-performance thermal insulation materials for the construction sector has to be focused on their final application. In particular, solutions for refurbishing historic buildings, which represent 40% of the European building stock, have to offer a good compromise between environmental quality, energy efficiency and conservation aspects. In this paper, the experimental assessment of an insulation material based on aerogel technology, recently developed in the European project EFFESUS, is presented with regard to the material's thermal performance, compatibility with historic fabric and reversibility. The overall results obtained in laboratory testing on a real-size mock-up and in a real-world case application indicate that the new material is a promising solution for retrofitting historic buildings, thanks to its thermal properties, easy application, reversibility and material compatibility.

While the effects of climate change unfold and become more visible, infrastructures - especially those related to the distribution of water and energy - are the most exposed to the deep changes expected in the next years. Water is fundamental for people, and for infrastructures like energy, waste, and food production. Water sustainability is therefore a fundamental aspect to be addressed by an efficient use of the resources and by mainteining high quality standards. Hence, water industry and water infrastructure need a deep transformation; in this paper we present a framework based on complex systems and management science as a possible pathway to reshape and optimize the performance of the water infrastructure to cope with the complexity of todays' challenges. To this aim, we propose the framework Acque 2.0 (Water 2.0), where we point out how the increase of the infrastructural resilience and of the overall quality of service can be attained by integrating models, algorithms and numerical methods like network simulations and big data analytics for the predictive maintenance of water networks. We discuss how Complexity Science is the natural glue allowing technical, management and social issues to be integrated in the holistic vision of the "water system" needed play to provide measures for an integrated sustainability reporting that involves utilities, regulators, policy makers, and citizens.

In this contribution, we discuss the implementation of a novel microelectromechanical-systems (MEMS)-based energy harvester (EH) concept within the technology platform available at the ISAS Institute (TU Vienna, Austria). The device, already presented by the authors, exploits the piezoelectric effect to convert environmental vibrations energy into electricity, and presents multiple resonant modes in the frequency range of interest (i.e. below 10 kHz). The experimental characterisation of a sputter deposited aluminium nitride piezoelectric thin-film layer is reported, leading to the extraction of material properties parameters. Such values are then incorporated in the finite element method model of the EH, implemented in Ansys Workbench (TM), in order to get reasonable estimates of the converted power levels achievable by the proposed device solution. Multiphysics simulations indicate that extracted power values in the range of several mu W can be addressed by the EH-MEMS concept when subjected to mechanical vibrations up to 10 kHz, operating in closed-loop conditions (i.e. piezoelectric generator connected to a 100 k Omega resistive load). This represents an encouraging result, opening up the floor to exploitations of the proposed EH-MEMS device in the field of wireless sensor networks and zero-power sensing nodes.