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This perspective covers the use of molybdenum disulfide and related compounds, generally termed MoSx, as electro- or photoelectrocatalysts for the hydrogen evolution reaction (HER). State of the art solutions as well as the most illustrative results from the extensive electro- and photoelectrocatalytic literature are given. The research strategies currently employed in the field are outlined and future challenges pointed out. We suggest that the key to optimising the HER activity of MoS2 is divided into (1) increasing the catalytic activity of the active site, (2) increasing the number of active sites of the catalyst, and (3) improving the electrical contact to these sites. These postulations are substantiated by examples from the existing literature and some new results. To demonstrate the electrocatalytic properties of a highly conductive MoS2 hybrid material, we present the HER activity data for multi-wall MoS2 nanotubes on multi-wall carbon nanotubes (MWMoS2@MWCNTs). This exemplifies the typical data collected for the electrochemical HER. In addition, it demonstrates that the origin of the activity is closely related to the amount of edges in the layered MoS2. The photoelectrocatalytic HER is also discussed, based on examples from literature, with an emphasis on the use of MoSx as either (1) the co-catalyst providing the HER activity for a semiconductor, e.g. Mo3S+4on Si or (2) MoS2 as the semiconductor with an intrinsic HER activity. Finally, suggestions for future catalyst designs are given.

The luminescent solar concentrator has the potential of widespread use as a generator of electricity from sunlight well-suited for use in the urban environment owing to its adaptability in shape and coloration. The device performance is heavily dependent on the ability to transport light long distances to the edges. A common organic luminophore used in the device is based on a perylene core. In this work, we describe an overlooked effect of UV illumination on the appearance and efficiency of these devices. An additional absorption peak appears upon polymerization under intense UV in nitrogen atmosphere which significantly reduces the edge emissions from the device. The additional absorbance peak disappears after exposure to air, indicating the presence of a radical anion being formed during the UV light exposure. This suggests newly-produced LSC devices should be allowed to stand a period of time under ambient conditions before their performance characteristics are determined, which could have implications in potential future commercialization of the technology.

Self-organizing nanopatterns can enable economically competitive, industrially applicable light-harvesting platforms for thin-film solar cells. In this work, we present transparent solar cell substrates having quasiperiodic uniaxial nanowrinkle patterns with high optical haze values. The self-organized nanowrinkle template is created by controlled heat-shrinking of metal-deposited pre-stretched polystyrene sheets. A scalable UV nanoimprinting method is used to transfer the nanopatterns to glass substrates on which single-junction hydrogenated amorphous silicon p-i-n solar cells are subsequently fabricated. The structural and optical analyses of the solar cell show that the nanowrinkle pattern is replicated throughout the solar cell structure leading to enhanced absorption of light. The efficient broadband light-trapping in the nanowrinkle solar cells results in very high 18.2 mA/cm2 short-circuit current density and 9.5% energy-conversion efficiency, which respectively are 35.8% and 39.7% higher than the values obtained in flat-substrate solar cells. The cost- and time-efficient technique introduces a promising new approach to customizable light-management strategies in thin-film solar cells.

This study provides the first comprehensive overview of the sustainability performance of the hotel sector in the Himalayan region: Sagarmatha National Park and Buffer Zone, using both environmental, economic, and technical criteria. In particular, the performance of 45 buildings in this region were measured and quantified in terms of life cycle based carbon footprint, life cycle costs, heat loss rate, number of guests, energy consumption, and area. Buildings were classified into three types: traditional, semi-modern and modern. The statistical analysis included testing for significant differences between such categories by means of ANOVA, and determination of the correlation between the same parameters. Results show a significant difference between the buildings’ total carbon footprint and operation stage carbon footprint while, there is no significant difference between the buildings’ life cycle costs. Traditional buildings have on average the largest carbon footprint and life-cycle cost over the typical building lifespan of 50 years of building lifespan. The ANOVA tests highlight how heat loss rate, size of the building and number of tourists in the hotels are significantly different across the building types. A strong positive correlation is observed between environmental impact, economic impact and energy consumption for the household activities, and a negative correlation with the number of guests and building size. By considering several buildings, this study allows to draw new and more general conclusions about effective sustainability strategies in the whole hotel sector in the Himalayan region. In particular, it shows that reducing impacts in the operation stage should be highly prioritized, focusing on reducing energy consumption and heat loss and shifting to the use of renewable energy sources.

Electrical energy production from renewable energy sources and electrification of consumer energy demand are developments in the ongoing energy transition. These developments urge the demand for flexibility in low voltage distribution networks, on the one hand caused by the intermittency of renewable energy sources, and on the other hand by the high power demand of battery electric vehicles and heat pumps. One of the foremost ways to create flexibility is by using energy storage systems. This paper proposes a method to first optimize the siting, power and capacity rating, technology, and operation of energy storage systems based on the technical and economic value. Secondly the method can be used to make cost- and time-based network planning decisions between network upgrades and network upgrade deferral by energy storage systems. To demonstrate the proposed method, study cases are analyzed of five low voltage distribution networks with different penetrations of photovoltaics, heat pumps and battery electric vehicles. The optimal energy storage systems in the study cases are: flow batteries sited at over 50% of the cable length with a high capacity rating per euro. With the current state of energy storage system development, network upgrade deferral is up to 61% cheaper than network upgrades in the study cases. The energy storage systems can offer additional value by reducing the peak loading of the medium voltage grid which is not taken into account in this research.

Abstract The configuration of a latent heat thermal energy storage (LHTES) is an important factor considered by manufacturers of heat storage systems. In this study, an applicable and low-cost way of improving melting behavior in a rectangular cavity was remarked. There was a preconceived idea that with a single conductive baffle, embedded on the upper wall of the cavity, the melting rate and the amount of heat storage could improve. Therefore, for different locations as well as lengths of a baffle, the heat transfer and melting characteristic of gallium as a phase change material (PCM) in a rectangular cavity were investigated numerically. The cavity has the insulated upper and bottom walls. The sidewalls are regarded to have constant temperatures one higher and another lower than the melting point of gallium. The phase change process is modeled with the fixed grid-based enthalpy-porosity method coupled with the semi-implicit method for pressure-linked equations (SIMPLE) algorithm. The isotherm lines and streamlines, as well as the liquid fraction and Nusselt number on the hot wall, are considered to present the results at a constant Rayleigh number equal to 106. The results show the baffle imposes noticeable improvement on the melting process of gallium in a rectangular cavity by influencing the feature of convective heat transfer. Investigating the different baffle’s locations (LX/L = 0.2 to 0.9) revealed that when the baffle located at the right half of the cavity, melting initiates from the left side, the more amount of PCM melts in comparison with the other cases. Ultimately, the dimensionless location of LX/L = 0.8 demonstrates the best melting characteristic and the most final liquid fraction. The more liquid-fraction, the more energy storing concluded. It also observed a dimensionless height of LY/L = 0.4 represents the most liquid-fraction compared to the heights of LY/L = 0.2, 0.3, and 0.4.