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The specific problems of determining and simulating the surface energy balance (SEB) and the mixing height (MH) over urban areas are examined. The SEB and MH are critical components of algorithms and numerical models for the urban boundary layer, though the constituent parts of the SEB and the MH are not routinely measured by national weather services. Parameterisations are thus needed in applications. In this investigation, several recently developed algorithms and models for estimating the SEB and MH were applied to new datasets and assessed. Results are discussed in terms of the need for spatial resolution and the parameters needed to describe the urban atmosphere. Limitations of models are identified and recommendations for further development and observations are given. Having identified gaps in knowledge, key findings from new urban experiments and numerical modelling for the SEB and MH are given. The diurnal cycle for the SEB is significantly different from rural conditions—urban heat storage is needed in urban parameterisations. The urban MH is increased over the rural MH, as shown by several numerical schemes and careful sodar analyses. This work has been carried out within the COST-715 Action “Meteorology applied to urban air pollution problems (1998–2004). COST 715 reached a consensus proposing representatively sited measurements of meteorological parameters and turbulent fluxes above roof-tops, and recognised that such data are needed to improve numerical models of the urban surface processes.

The specific problems of determining and simulating the surface energy balance (SEB) and the mixing height (MH) over urban areas are examined. The SEB and MH are critical components of algorithms and numerical models for the urban boundary layer, though the constituent parts of the SEB and the MH are not routinely measured by national weather services. Parameterisations are thus needed in applications. In this investigation, several recently developed algorithms and models for estimating the SEB and MH were applied to new datasets and assessed. Results are discussed in terms of the need for spatial resolution and the parameters needed to describe the urban atmosphere. Limitations of models are identified and recommendations for further development and observations are given. Having identified gaps in knowledge, key findings from new urban experiments and numerical modelling for the SEB and MH are given. The diurnal cycle for the SEB is significantly different from rural conditions—urban heat storage is needed in urban parameterisations. The urban MH is increased over the rural MH, as shown by several numerical schemes and careful sodar analyses. This work has been carried out within the COST-715 Action “Meteorology applied to urban air pollution problems (1998–2004). COST 715 reached a consensus proposing representatively sited measurements of meteorological parameters and turbulent fluxes above roof-tops, and recognised that such data are needed to improve numerical models of the urban surface processes.

AbstractIn this paper, we report on the outcome of a German network project conducted with 12 partners from universities and research institutes on the material development of dye solar cells (DSC). We give an overview in the field and evaluate the concept of monolithic DSC further with respect to upscaling and producibility on glass substrates. We have developed a manufacturing process for monolithic DSC modules which is entirely based on screen printing. Similar to our previous experience gained in the sealing of standard DSC, the encapsulation of the modules is achieved in a fusing step by soldering of glass frit layers. For use in monolithic DSC, a platinum free, conductive counter electrode layer, showing a charge transfer resistance of RCT < 1·5 Ω cm2, has been realized by firing a graphite/carbon black composite under an inert atmosphere. Glass frit sealed monolithic test cells have been prepared using this platinum‐free material. A solar efficiency of 6% on a 2·0 cm2 active cell area has been achieved in this case. Various types of non‐volatile imidazolium‐based binary ionic liquid electrolytes have been synthesized and optimized with respect to diffusion‐limited currents and charge transfer resistances in DSC. In addition, quasi‐solid‐state electrolytes have been successfully tested by applying inorganic (SiO2) physical gelators. For the use in semi‐transparent DSC modules, a polyol process has been developed which resulted in the preparation of screen printed, transparent catalytic platinum layers showing an extremely low charge transfer resistance (0·25 Ω cm2). Copyright © 2008 John Wiley & Sons, Ltd.

AbstractIn this paper, we report on the outcome of a German network project conducted with 12 partners from universities and research institutes on the material development of dye solar cells (DSC). We give an overview in the field and evaluate the concept of monolithic DSC further with respect to upscaling and producibility on glass substrates. We have developed a manufacturing process for monolithic DSC modules which is entirely based on screen printing. Similar to our previous experience gained in the sealing of standard DSC, the encapsulation of the modules is achieved in a fusing step by soldering of glass frit layers. For use in monolithic DSC, a platinum free, conductive counter electrode layer, showing a charge transfer resistance of RCT < 1·5 Ω cm2, has been realized by firing a graphite/carbon black composite under an inert atmosphere. Glass frit sealed monolithic test cells have been prepared using this platinum‐free material. A solar efficiency of 6% on a 2·0 cm2 active cell area has been achieved in this case. Various types of non‐volatile imidazolium‐based binary ionic liquid electrolytes have been synthesized and optimized with respect to diffusion‐limited currents and charge transfer resistances in DSC. In addition, quasi‐solid‐state electrolytes have been successfully tested by applying inorganic (SiO2) physical gelators. For the use in semi‐transparent DSC modules, a polyol process has been developed which resulted in the preparation of screen printed, transparent catalytic platinum layers showing an extremely low charge transfer resistance (0·25 Ω cm2). Copyright © 2008 John Wiley & Sons, Ltd.

Abstract To understand how extratropical cyclones (ETCs) may change in a warmer climate, we conduct idealized baroclinic life cycle simulations using the Icosahedral Nonhydrostatic (ICON)–NWP model with varied initial conditions. With respect to a present-day climate, two experiments are highlighted: a 4-K uniform warming and a more realistic late twenty-first-century warming pattern projected by a Coupled Model Intercomparison Project, version 6 (CMIP6), model. Different ETC deepening mechanisms, especially by diabatic processes, are quantified via the pressure tendency equation analysis, and the horizontal model resolution dependency is examined by contrasting coarse-grid (80 km) and convection-permitting (2.5 km) simulations. While our simulated ETCs are primarily baroclinically driven, dominated by the horizontal warm-air advection in the air column above the surface low, such an effect only strengthens by 10% in both warming experiments. However, the direct contribution of diabatic heating to surface pressure drop almost doubles, which likely feeds back positively to horizontal warm-air advection. Although their combined response to warming is pronounced, it is largely offset by the strengthened adiabatic cooling (17%) due to enhanced upward motions in warmer and moister ETCs, leading to a marginal ETC deepening at maturity (lowers by ∼1.5–4 hPa). Nevertheless, the near-surface impacts strongly increase, particularly the local extreme precipitation (up to 56%). The convection-permitting and the coarse-grid simulations show qualitatively consistent ETC responses to global warming. We suggest that the systematically weaker ETCs (with higher central pressure) in 2.5-km compared to 80-km simulations might be primarily caused by model uncertainty in representing the convective-diabatic heating over the warm front near the cyclone core.

Abstract To understand how extratropical cyclones (ETCs) may change in a warmer climate, we conduct idealized baroclinic life cycle simulations using the Icosahedral Nonhydrostatic (ICON)–NWP model with varied initial conditions. With respect to a present-day climate, two experiments are highlighted: a 4-K uniform warming and a more realistic late twenty-first-century warming pattern projected by a Coupled Model Intercomparison Project, version 6 (CMIP6), model. Different ETC deepening mechanisms, especially by diabatic processes, are quantified via the pressure tendency equation analysis, and the horizontal model resolution dependency is examined by contrasting coarse-grid (80 km) and convection-permitting (2.5 km) simulations. While our simulated ETCs are primarily baroclinically driven, dominated by the horizontal warm-air advection in the air column above the surface low, such an effect only strengthens by 10% in both warming experiments. However, the direct contribution of diabatic heating to surface pressure drop almost doubles, which likely feeds back positively to horizontal warm-air advection. Although their combined response to warming is pronounced, it is largely offset by the strengthened adiabatic cooling (17%) due to enhanced upward motions in warmer and moister ETCs, leading to a marginal ETC deepening at maturity (lowers by ∼1.5–4 hPa). Nevertheless, the near-surface impacts strongly increase, particularly the local extreme precipitation (up to 56%). The convection-permitting and the coarse-grid simulations show qualitatively consistent ETC responses to global warming. We suggest that the systematically weaker ETCs (with higher central pressure) in 2.5-km compared to 80-km simulations might be primarily caused by model uncertainty in representing the convective-diabatic heating over the warm front near the cyclone core.

Abstract Decarbonising the heating sector is crucial for reducing CO2 emissions. This is in particular true for Central European cities such as Vienna, where 28% of the total CO2 emissions are caused by the energy supply for buildings. One promising option for environmental friendly heat supply is the use of shallow geothermal energy. To determine whether shallow geothermal systems are a feasible option to meet the urban heating demand, the Python tool GeoEnPy is developed and applied to a case study in Vienna. It allows the evaluation of the anthropogenic heat input into the subsurface, the theoretical sustainable potential, the technical geothermal potential, and the heat supply rate. The overall heat flow in Vienna is 17.6 PJ/a, which represents 38% of the current heating demand or indeed 99% once all buildings are thermally refurbished. The technical geothermal potential can satisfy the current heating demand for 63% (BHE system) or rather 8% (GWHP system) of the city area. GeoEnPy reveals that BHE systems are most feasible in the eastern and southern districts of Vienna. Our findings can guide integration of shallow geothermal use in spatial energy management focused on key locations to supply buildings with decentralised and sustainable heat from the subsurface.

Abstract Decarbonising the heating sector is crucial for reducing CO2 emissions. This is in particular true for Central European cities such as Vienna, where 28% of the total CO2 emissions are caused by the energy supply for buildings. One promising option for environmental friendly heat supply is the use of shallow geothermal energy. To determine whether shallow geothermal systems are a feasible option to meet the urban heating demand, the Python tool GeoEnPy is developed and applied to a case study in Vienna. It allows the evaluation of the anthropogenic heat input into the subsurface, the theoretical sustainable potential, the technical geothermal potential, and the heat supply rate. The overall heat flow in Vienna is 17.6 PJ/a, which represents 38% of the current heating demand or indeed 99% once all buildings are thermally refurbished. The technical geothermal potential can satisfy the current heating demand for 63% (BHE system) or rather 8% (GWHP system) of the city area. GeoEnPy reveals that BHE systems are most feasible in the eastern and southern districts of Vienna. Our findings can guide integration of shallow geothermal use in spatial energy management focused on key locations to supply buildings with decentralised and sustainable heat from the subsurface.