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Abstract Currently, the first generation of silicon solar cells is dominating the photovoltaic market. Silicon cells are produced by various methods, which employ either crystalline or multi-crystalline substrates. However, both these manufacturing processes are expensive and potentially harmful to the environment and health. One example of this is that the surface is given its texture in a highly corrosive water solution of nitric and hydrofluoric acid. Additionally, both the diffusion and manufacturing of p-n junction and of metal contacts are associated with very high temperatures. This prompted us in our search for cheaper and more environmental friendly technologies. In this work, we discuss the possibility of producing components of photovoltaic cells by employing atomic layer deposition and hydrothermal technologies. This does not require the use of hazardous chemicals and high temperatures. The maximum efficiency of zinc oxide/silicon solar cells is 14% and 10% for textured and planar structures, respectively. A environmentally-friendly and simple procedure is thus being proposed, which, together with its relative efficiency, makes it an attractive alternative to the present procedure.

Abstract The present work aimed to find the answer how does the isomerization of the Ru based dyes affect the overall photon-to-current efficiency of the DSSCs and to explain the charge transfer phenomenon occurring on the dye/nanosemiconductor interface. Therefore, electronic and optical properties of three bipyridine derivatives anchored on the TiO2 electrode were investigated by computational simulations based on quantum chemistry codes performed on a cluster model and the predictions compared with experimental responses. The quantum chemical calculations carried out for the para-, meta- and ortho-isomers has given the possibility to explain the role of an anchor group position in the DSSC devices design. An in-depth analysis of the obtained data shows that the nature of the bonding between the anchor groups and the semiconducting nanoparticles affects the charge transfer at the interfaces. The electronic properties obtained for the hybrid systems and their components indicate that solar cells with the para-derivatives of the Ru based dyes as sensitizers exhibit the highest photo conversion efficiency. The observed phenomenon was explained based on the photogenerated excitons in the organic groups and their dissociation at the dye/semiconductor interfaces to ensure the free charge carriers.

Information about decadal to millennial variability of El Nino Southern Oscillation (ENSO) is fundamental for the assessment of ENSO responses to natural and anthropogenic forcings. Despite a growing number of ENSO reconstructions, the overall picture of Holocene ENSO variability is inconsistent. Here, we revisit the iconic Holocene ENSO sediment record of Lake Pallcacocha, Ecuador (Rodbell et al., 1999). We asked: (i) How coherent are the records of clastic layers (flood layers) in the sediments of Lake Pallcacocha and adjacent Lake Fondococha? (ii) What are the synoptic-scale atmospheric conditions that lead to intense precipitation and, potentially, to alluvial activity promoting the deposition of clastic layers in these lakes? (iii) Is intense precipitation in this area associated with El Nino, or not? We analyzed clastic layers in Late-Holocene sediments from multiple cores in Lakes Pallcacocha and Fondococha from Cajas National Park, southern Ecuadorian Andes. Additionally, we investigated precipitation data from 13 nearby meteorological stations to test if intense precipitation (percentiles P0.95, P0.99, P0.995) is predominantly related to El Nino conditions or not (based on 15 different ENSO indices). Our results show that the absolute flood frequencies (clastic layers per 100 years) differ substantially from lake to lake. This indicates that the frequency of clastic layers reflects different sensitivities (thresholds of precipitation) of the catchments to alluvial activity. 210Pb ages suggest that neither the 1982/83 nor the 1997/98 very strong El Ninos produced clastic layers comparable to those found in the late Holocene. Daily precipitation records from meteorological stations close to Lake Pallcacocha including a high-altitude station from the western slope of the Andes did not show unusually high precipitation during the super El Nino 2015/16. We further find that intense precipitation in this area occurs at roughly equal probability under El Nino, La Nina and neutral conditions. Although the spectral properties of the late Holocene clastic layers in Lake Pallcacocha fall into the typical ENSO frequency band, we do not find evidence in the recent sediments and the meteorological data that would support a diagnostic link between alluvial activity in Lake Pallcacocha and strong El Nino events. Our data do not support the idea that the (late) Holocene flood record of Lake Pallcacocha is a conclusive paleo-El Nino record

The research has been aimed at answering two questions: (1) What factors impact perception and acceptance of technological and environmental hazards? (2) Why are rich societies involved more in protecting their environment and health than poor societies? Data has been collected from representative samples of two countries—Poland and Sweden. The results indicate that (1) contrary to earlier findings, the inverse relations between perceived benefits and dangers of hazards has not been observed, (2) acceptance of a risk has been mostly influenced by perceived benefits, (3) rejection of a risk has been mostly influenced by its perceived harmful consequences. Concerning the second question, it has been found that: (1) perceived hazard's danger and benefit is not the only factor that impacts its acceptance, and (2) a broader economic context can impact acceptance (tolerance) of hazards. It has been found that being aware of high dangers and not very high benefits of hazardous activities, Poles still have accepted them. Thus, Poles seem to follow an old proverb: “When one does not have what one likes, one has to like what one has.”

Controlling the shuttling of lithium polysulphides (LiPS) to enhance the utilization of elemental sulfur has been considered as an important issue to improve the energy density and coulombic efficiency of lithium–sulfur batteries.

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