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AbstractBACKGROUNDFermentation of vegetables and fruits is a traditional preservation technique, e.g. in Eastern Europe. Although usually spontaneous fermentation processes are applied, the addition of lactic acid bacteria (LAB) starter cultures could accelerate processing and improve the consistency and quality of the end‐products.RESULTSThe application of Lactobacillus plantarum IMDO 788 as a starter culture strain for cauliflower and mixed vegetable fermentations resulted in accelerated acidification as compared with the spontaneous fermentations. The strain dominated the background microbiota throughout the process, whereas the spontaneous fermentations were characterised by widely variable species diversity. During the spontaneous fermentations, almost all carbohydrates were converted into lactic acid, ethanol, mannitol and acetic acid, indicating the participation of both heterofermentative and homofermentative LAB species. During the starter culture‐added fermentations, residual carbohydrates were found and lactic acid and ethanol were the main end‐metabolites. Vegetable‐associated aromas, ethyl acetate and isoamyl acetate were produced during all fermentations. The high concentration of ethanol and the production of ethyl acetate and isoamyl acetate suggested the involvement of yeasts during all fermentations.CONCLUSIONLactobacillus plantarum IMDO 788 was an adequate starter culture strain for vegetable fermentations, prevailing over endogenous LAB communities. Further optimisation of the starter culture formulation is necessary to avoid yeast growth. © 2013 Society of Chemical Industry

In this paper, we propose innovative solutions for reusing an inactive offshore gas platform and its associated infrastructures as a scientific research hub, where an integrated energy system and innovative environmental monitoring methods are envisaged. To this end, the Azalea A platform, located in the northern Adriatic Sea, is considered a good pilot site. This study analyzes the engineering solutions on Azalea A for the combined production of solar and wind energy coupled with hydrogen production from seawater electrolysis. It analyzes the potential for storage and transport on land of the produced hydrogen using the sealines connected to the platform. However, this study does not deal with the current structural conditions of the platform (corrosion, stability etc.), which should be evaluated before these solutions are put into practice. The main outcomes of this work consist in a feasibility study for the reuse of existing infrastructures as a self-sufficient research hub using green energy systems, which include considerations about the measures needed to ensure the protection of the marine environment. Data show a positive feedback about the technical feasibility of the proposal in safety conditions. Furthermore, encouraging outcomes derive also by the economic evaluation that estimates sustainable costs comparing to those implicated with the decommissioning of the infrastructures in the order of tens millions euro. In addition, the proposed reuse seems to be a good opportunity to promote both energy transition toward renewable energy systems and environmental protection, avoiding decommissioning impacts and promoting an innovative monitoring program for the Adriatic Sea.

Abstract Supercritical Water Oxidation (SCWO) is the process of complete destruction of toxic and hazardous organic wastes in a compact, totally enclosed system through oxidation in water brought to temperatures and pressures above its critical point: 374 °C and 218 atm. At these conditions, organic materials, gases and water form a new phase, completely mixed, that provides the environment for a rapid and complete oxidation. Typical products from a SCWO process include carbon dioxide, water, and inorganic salts or acids. SCWO advantages include very high destruction efficiencies, low NO x and SO x occurrence, no dioxins or furans, totally contained process, no smokestack, relatively low temperature operation, and compact size. The chemical reactors energy integration (CREI) concept focuses on, simultaneously, the entropy generation reduction of both chemical reactor network (CRN) and heat exchanger networks (HEN) and the search for possibly new operating conditions for some of the reactors (if not all) to accomplish this goal. The basic idea of CREI is to replace each of the reactors of the CRN with a corresponding virtual heat exchanger, having the chemical reaction enthalpy as thermal load, thus creating a virtual HEN. Then, combine this VHEN and the existing HEN into an extended system, which will be the object of the pinch analysis. Care should be taken that the virtual heat exchanger system produces the same amount of entropy as the replaced chemical reactor. Pinch and CREI analysis were applied to SCWO process and the suitable network configuration and operating conditions were found to achieve the minimum entropy generation.

In this paper, the performances of two iron-based syngas-fueled chemical looping (SCL) systems for hydrogen (H2) and electricity production, with carbon dioxide (CO2) capture, using different reactor configurations were evaluated and compared. The first investigated system was based on a moving bed reactor configuration (SCL-MB) while the second used a fluidized bed reactor configuration (SCL-FB). Two modes of operation of the SCL systems were considered, namely, the H2 production mode, when H2 was the desired product from the system, and the combustion mode, when only electricity was produced. The SCL systems were modeled and simulated using Aspen Plus software. The results showed that the SCL system based on a moving bed reactor configuration is more efficient than the looping system with a fluidized bed reactor configuration. The H2 production efficiency of the SCL-MB system was 11 % points higher than that achieved in the SCL-FB system (55.1 % compared to 44.0 %). When configured to produce only electricity, the net electrical efficiency of the SCL-MB system was 1.4 % points higher than that of the SCL-FB system (39.9 % compared to 38.5 %). Further, the results showed that the two chemical looping systems could achieve >99 % carbon capture efficiency and emit ~2 kg CO2/MWh, which is significantly lower than the emission rate of conventional coal gasification-based plants for H2 and/or electricity generation with CO2 capture.

Alpine grasslands on the Qinghai-Tibetan Plateau are sensitive and vulnerable to climate change and human activities. Climate warming and overgrazing have already caused degradation in a large fraction of alpine grasslands on this plateau. However, it remains unclear how human activities (mainly livestock grazing) regulates vegetation dynamics under climate change. Here, alpine grassland productivity (substituted with the normalized difference vegetation index, NDVI) is hypothesized to vary in a nonlinear trajectory to follow climate fluctuations and human disturbances. With generalized additive mixed modelling (GAMM) and residual-trend (RESTREND) analysis together, both magnitude and direction of climatic (in terms of temperature, precipitation, and radiation) and anthropogenic impacts on NDVI variation were examined across alpine meadows, steppes, and desert-steppes on the Qinghai-Tibetan Plateau. The results revealed that accelerating warming and greening, respectively, took place in 76.2% and 78.8% of alpine grasslands on the Qinghai-Tibetan Plateau. The relative importance of temperature, precipitation, and radiation impacts was comparable, between 20.4% and 24.8%, and combined to explain 66.2% of NDVI variance at the pixel scale. The human influence was strengthening and weakening, respectively, in 15.5% and 14.3% of grassland pixels, being slightly larger than any sole climatic variable across the entire plateau. Anthropogenic and climatic factors can be in opposite ways to affect alpine grasslands, even within the same grassland type, likely regulated by plant community assembly and species functional traits. Therefore, the underlying mechanisms of how plant functional diversity regulates nonlinear ecosystem response to climatic and anthropogenic stresses should be carefully explored in the future.

Molinate (S-ethyl-azepane-1-carbothioate) is a thiocarbamate herbicide used in rice cultivation for the control of grass weeds. Environmental contamination with molinate is of major concern due to the adverse effects described both for humans and animals. Molinate hydrolase, a novel amidohydrolase previously characterized, is responsible for the initial breakdown of molinate, cleaving the thioester bond of molinate, releasing ethanethiol and azepane-1-carboxylate (ACA). Biotechnology is the key for sustainable farming. With advances in biotechnology, bioremediation has become one of the most rapidly developing fields of environmental restoration. Through the microencapsulation of molinate hydrolase, we are aiming to develop a bioremediation process for the effective molinate degradation in rice paddies. The purpose of this work was to develop and validate an UV method to effectively quantify the substrate (molinate) in further assays with free and microencapsulated molinate hydrolase. The analytical method was validated and the main parameters, as limit of detection, linearity range, precision and accuracy were determined, and compared to those obtained by HPLC (regarding free enzyme kinetics). Both methods show to be linear (r > 0.999) over the concentration range of 0.005-0.150 mM molinate. The global uncertainty, estimated accordingly to the bottom-up approach used by Eurachem, was estimated for both methods. The UV analytical method is effective and seems that it can be applied in future for the quantification of molinate breakdown by free and encapsulated molinate hydrolase.

Decision-makers need tailored information regarding future climate, land use, forest management and societal scenarios for sustainable watershed management. Such information can be attained by integrating the water-energy-land nexus approach with climate services. To support decision-makers from Brașov metropolitan area (Romania), we co-developed land use, forest management and societal scenarios and analysed their impact on the water-energy-land nexus under climate change. We applied the Soil and Water Assessment Tool (SWAT) to the Săcele reservoir from the Tărlung river basin in order to spot the interrelations between nexus components under different climate and societal scenarios. In particular, we applied four bias-corrected GCM & RCM model combinations for two climate scenarios RCP4.5 and RCP8.5, nine land use and forest management scenarios, and twelve societal scenarios. Modelling results were analysed between 2020 and 2099. The results for the study area indicate that the projected average annual precipitation is close to historical averages in most climate scenarios explored, while the projected average annual temperature is increasing. Furthermore, the analysed data suggest an increase in severe dry intervals from approximately 6% (for the period 1961–2013) to 12% by the end of the 21st century, indicating that precipitation variability may change considerably. The SWAT model results show no significant changes in the water flow under different forest management scenarios. In contrast, model results for scenarios that imply forests' clearcutting and their replacement with pastures or meadows indicate that water quality is affected by increased sediment flow. Regarding the number of months with water scarcity in the Săcele reservoir (i.e. water demand exceeds water supply), we found an increase from 0.4 months in 2020 to 1.5 months in 2099. The model results also revealed that climate change significantly influences the water supply in the reservoir. To conclude, the regional stakeholders highly value the model results for the co-developed scenarios, which have been already used to promote sustainable resource management.

Abstract The early diagenetic characteristics of pyrite formation processes in a Miocene freshwater sequence of mixed sediments (coal fragments in clays, sandstones or shales) alternating with continuous brown coal layers was investigated. Based on abundant minerals, the following main sedimentary environments were distinguished: the illite-montmorillonitic (I-M), calcitic (Ct) and coal-forming environment (CL). For these hydrogeochemically differing environments the effects of limiting factors on the pyrite formation process (availability of sulphate and Fe, amount of organic matter and participation of organic sulphur) were assessed by correlation analysis. Significant differences in the effects of these limiting factors in the particular environments were observed. These differences were explained taking in account the different oxidative activity, Fe-complex and surface complex forming properties of humic substances in dependence of pH of environment and the abundance of sorptionally active clay minerals. In environments having a relatively low pH and containing clay minerals (I-M-and CL-environments) the oxidative activity of humic substances (Hs) on pyrite precursors was greatly prevented however pyrite formation depended on reactive Fe availability as the consequence of complex formation. On the contrary, in environments with a relatively high pH, as it was the calcitic, the oxidative activity of Hs was greatly enhanced, thus oxidizing the sulfur precursors of pyrite. The oxidation degree of organic matter was probably also a consequence of the differing activity of the humic electron-acceptors.

Based on the approach of 'arena of development' controversies over bioenergy in the shaping of a Danish climate strategy are analyzed as a contribution to a sustainable transition perspective on bioenergy in industrialized societies with substantial agricultural production. Bioenergy plays a prominent role in several Danish climate and energy plans, alongside with wind and solar energy, and energy savings. There are major controversies about targets for bioenergy with respect to acceptable types, sources and amounts of biomass. Strong path dependency is identified. Energy companies in Denmark convert coal fired power plants to biomass in order to sustain the role of these power plants. Their increasing use of imported wood pellets is criticized for increasing greenhouse gas emissions because of fast logging of years of forest growth. A Danish biotech company is developing enzymes for processing of biomass for biofuels. The alignment with the private car regime is strong, because biofuel enables continuation of fuel-driven vehicles as dominating transportation mode. Danish farmers see manure as important source for biogas while arguing for reduction of climate impact and nuisances from digested manure. Such biogas is questioned by some NGOs who fear manure-based biogas is used as argument for increased animal husbandry. The bioenergy controversies concern also methodologies for environmental assessments, including for indirect land use changes (ILUC), and reliability of certification schemes. The mapping of controversies identifies issues that probably need to be taken into account in shaping of Danish bioenergy strategies if these strategies should gain substantial legitimacy among environmental NGOs.

Forests have been undergoing through immense pressure due to the factors like human activities; procurement of forest products and climate change which is a major factor influencing this pressure buildup on forests. Climate change and temperature increase caused by anthropogenic activities have notably affected forests and wildlife on a global scale. High temperature increases the soil-water evaporation, resulting in drier soils, and water loss in forest flora. The incidence of forest fires has doubled since 1984 and these are linked to global warming. Drought influences fuel moisture by bringing about physiological changes in forest vegetation leading to forest fires. Forest resilience is hampered because of temperature and drought stress at the developing stage of plant's life cycle leading to the shift in plant species in those areas. Forest fire incidences can be managed with proper management strategies such as sustainable, community and urban forest management. A careful monitoring of stress precursors, subsistence uses of forests, ecological education and planting of near native and new indigenous plant species are the tools that can aid in efficient forest management.