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  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Authors: Silvio Marta; Roberto Sergio Azzoni; Davide Fugazza; Levan Tielidze; +41 Authors

    Most of the world’s mountain glaciers have been retreating for more than a century in response to climate change. Glacier retreat is evident on all continents, and the rate of retreat has accelerated during recent decades. Accurate, spatially explicit information on the position of glacier margins over time is useful for analyzing patterns of glacier retreat and measuring reductions in glacier surface area. This information is also essential for evaluating how mountain ecosystems are evolving due to climate warming and the attendant glacier retreat. Here, we present a non-comprehensive spatially explicit dataset showing multiple positions of glacier fronts since the Little Ice Age (LIA) maxima, including many data from the pre-satellite era. The dataset is based on multiple historical archival records including topographical maps; repeated photographs, paintings, and aerial or satellite images with a supplement of geochronology; and own field data. We provide ESRI shapefiles showing 728 past positions of 94 glacier fronts from all continents, except Antarctica, covering the period between the Little Ice Age maxima and the present. On average, the time series span the past 190 years. From 2 to 46 past positions per glacier are depicted (on average: 7.8).

    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Archivio Istituziona...arrow_drop_down
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      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Archivio Istituziona...arrow_drop_down
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      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
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  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Authors: Silvio Marta; Roberto Sergio Azzoni; Davide Fugazza; Levan Tielidze; +41 Authors

    Most of the world’s mountain glaciers have been retreating for more than a century in response to climate change. Glacier retreat is evident on all continents, and the rate of retreat has accelerated during recent decades. Accurate, spatially explicit information on the position of glacier margins over time is useful for analyzing patterns of glacier retreat and measuring reductions in glacier surface area. This information is also essential for evaluating how mountain ecosystems are evolving due to climate warming and the attendant glacier retreat. Here, we present a non-comprehensive spatially explicit dataset showing multiple positions of glacier fronts since the Little Ice Age (LIA) maxima, including many data from the pre-satellite era. The dataset is based on multiple historical archival records including topographical maps; repeated photographs, paintings, and aerial or satellite images with a supplement of geochronology; and own field data. We provide ESRI shapefiles showing 728 past positions of 94 glacier fronts from all continents, except Antarctica, covering the period between the Little Ice Age maxima and the present. On average, the time series span the past 190 years. From 2 to 46 past positions per glacier are depicted (on average: 7.8).

    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Archivio Istituziona...arrow_drop_down
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      Article . 2021 . Peer-reviewed
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    Authors: A. V. Zhuikov; D. A. Loginov; G. R. Mongush; S. V. Chicherin; +1 Authors

    The process of combusting Tuva coals before and after their carbonization was studied using the methods of thermogravimetric analysis and electron microscopy. Coal samples were subjected to thermomechanical and elemental analysis, which revealed a higher content of volatile substances in Kaa-Khem coal (47.5 %) compared to Chadan coal (10 %). Following carbonization, a decrease in volatile substances to 11.5 % and 9.3 %, respectively, was observed. The conducted thermogravimetric analysis showed the ignition temperature of the coke residue of the Kaa-Khem and Chadan coal samples to increase by 76 °C and 90 °C, respectively, after carbonization. The burnup temperature of the coke residue after carbonizing (723 °C) Kaa-Khem coal samples remained effectively the same, while the Chadan coal showed an increase from 704 °C to 727 °C. The carbonization of coals was established to decrease the maximum reaction rate from 19 % per min to 10% per min for Kaa-Khem coal and from 26 % per min to 11 % per min for Chadan coal. The process of combusting the coke residue after coal carbonization was found to shift into the region of higher temperatures: from 448–723°C to 524–724°C for Kaa-Khem coal and from 436–704 °C to 526–727 °C for Chadan coal. A morphological analysis of the surface of coal particles after carbonization showed the appearance of larger-size pores and cracks on the surface of carbonates compared to coal before carbonization. The conclusion is made that the content of volatile substances, rather than the developed pore structure, comprises the main factor in improving the combustion characteristics of Tuva coals under the conditions of non-isothermal heating before and after their carbonization.

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    Authors: A. V. Zhuikov; D. A. Loginov; G. R. Mongush; S. V. Chicherin; +1 Authors

    The process of combusting Tuva coals before and after their carbonization was studied using the methods of thermogravimetric analysis and electron microscopy. Coal samples were subjected to thermomechanical and elemental analysis, which revealed a higher content of volatile substances in Kaa-Khem coal (47.5 %) compared to Chadan coal (10 %). Following carbonization, a decrease in volatile substances to 11.5 % and 9.3 %, respectively, was observed. The conducted thermogravimetric analysis showed the ignition temperature of the coke residue of the Kaa-Khem and Chadan coal samples to increase by 76 °C and 90 °C, respectively, after carbonization. The burnup temperature of the coke residue after carbonizing (723 °C) Kaa-Khem coal samples remained effectively the same, while the Chadan coal showed an increase from 704 °C to 727 °C. The carbonization of coals was established to decrease the maximum reaction rate from 19 % per min to 10% per min for Kaa-Khem coal and from 26 % per min to 11 % per min for Chadan coal. The process of combusting the coke residue after coal carbonization was found to shift into the region of higher temperatures: from 448–723°C to 524–724°C for Kaa-Khem coal and from 436–704 °C to 526–727 °C for Chadan coal. A morphological analysis of the surface of coal particles after carbonization showed the appearance of larger-size pores and cracks on the surface of carbonates compared to coal before carbonization. The conclusion is made that the content of volatile substances, rather than the developed pore structure, comprises the main factor in improving the combustion characteristics of Tuva coals under the conditions of non-isothermal heating before and after their carbonization.

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    Authors: P. N. Petrova; E.S. Kolesova; F.F. Protopopov; O. V. Gogoleva;
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    Petroleum Engineering
    Article . 2021 . Peer-reviewed
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      Petroleum Engineering
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    Authors: P. N. Petrova; E.S. Kolesova; F.F. Protopopov; O. V. Gogoleva;
    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Petroleum Engineerin...arrow_drop_down
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    Petroleum Engineering
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      Petroleum Engineering
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    Authors: Kennedy Masamba; Wisdom Changadeya; Pheneas Ntawuruhunga; Pilirani Pankomera; +2 Authors

    Cassava utilisation in Malawi is negatively affected by rapid deterioration of fresh roots, primarily caused by postharvest physiological deterioration (PPD). A study was conducted to assess farmers’ knowledge and approaches used to minimize losses from PPD. Multi-stage sampling was used to identify districts, Extension Planning Areas (EPA’s) and farmers. Data were collected from 519 farmers using a structured questionnaire. Results revealed that PPD (74.0%) was the major post-harvest constraint followed by pests and diseases (62.1%). Farmers had varying knowledge levels on signs and causes of PPD. They were knowledgeable on PPD signs with 91.5% ably identifying PPD through change of pulp colour. The farmers also had moderate knowledge on causes of PPD, citing high temperature (57.6%) and over-staying of roots (56.2%) as main causes of PPD. Key methods for preventing PPD are: storage (43.0%) and piece-meal harvesting (40.4%). Only 2.6% of the farmers exploited varietal difference in dealing with PPD as some varieties (Sauti, Mpuma, Ching’amba, and Kalasa) take three to five days before showing PPD signs. Farmers’ knowledge levels and PPD preventive methods could be strengthened through: provision of training on post-harvest handling, improvement in storage and processing technologies; and application of advanced breeding techniques to exploit genetic variation in cassava germplasm.

    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Sustainabilityarrow_drop_down
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    Authors: Kennedy Masamba; Wisdom Changadeya; Pheneas Ntawuruhunga; Pilirani Pankomera; +2 Authors

    Cassava utilisation in Malawi is negatively affected by rapid deterioration of fresh roots, primarily caused by postharvest physiological deterioration (PPD). A study was conducted to assess farmers’ knowledge and approaches used to minimize losses from PPD. Multi-stage sampling was used to identify districts, Extension Planning Areas (EPA’s) and farmers. Data were collected from 519 farmers using a structured questionnaire. Results revealed that PPD (74.0%) was the major post-harvest constraint followed by pests and diseases (62.1%). Farmers had varying knowledge levels on signs and causes of PPD. They were knowledgeable on PPD signs with 91.5% ably identifying PPD through change of pulp colour. The farmers also had moderate knowledge on causes of PPD, citing high temperature (57.6%) and over-staying of roots (56.2%) as main causes of PPD. Key methods for preventing PPD are: storage (43.0%) and piece-meal harvesting (40.4%). Only 2.6% of the farmers exploited varietal difference in dealing with PPD as some varieties (Sauti, Mpuma, Ching’amba, and Kalasa) take three to five days before showing PPD signs. Farmers’ knowledge levels and PPD preventive methods could be strengthened through: provision of training on post-harvest handling, improvement in storage and processing technologies; and application of advanced breeding techniques to exploit genetic variation in cassava germplasm.

    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Sustainabilityarrow_drop_down
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    This paper is devoted to study the electrochemical behavior of Pt catalyst in a polymer electrolyte fuel cell at various operating conditions and at different electric potential difference (also known as voltage) cycling applied in accelerated stress tests. The degradation of platinum is considered with respect to the Pt ion dissolution and the Pt oxide coverage of catalyst described by a one-dimensional model. In the model, degradation rate increases with temperature and decreasing particle diameter of Pt nano-particles. The theoretical study of the underlying diffusion system with the nonlinear reactions is presented by analytical methods and gives explicit solutions through a first integral of the ODE system. Numerical tests are obtained using a second order implicit-explicit scheme. The computer simulation shows that the lifetime of the catalyst depends on the voltage profile and the upper potential level. By this Pt mass loss is more significant at the membrane surface than at the gas diffusion layer.

    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Journal of Power Sou...arrow_drop_down
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    https://dx.doi.org/10.48550/ar...
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    image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
    Journal of Power Sources
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      https://dx.doi.org/10.48550/ar...
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      Journal of Power Sources
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    This paper is devoted to study the electrochemical behavior of Pt catalyst in a polymer electrolyte fuel cell at various operating conditions and at different electric potential difference (also known as voltage) cycling applied in accelerated stress tests. The degradation of platinum is considered with respect to the Pt ion dissolution and the Pt oxide coverage of catalyst described by a one-dimensional model. In the model, degradation rate increases with temperature and decreasing particle diameter of Pt nano-particles. The theoretical study of the underlying diffusion system with the nonlinear reactions is presented by analytical methods and gives explicit solutions through a first integral of the ODE system. Numerical tests are obtained using a second order implicit-explicit scheme. The computer simulation shows that the lifetime of the catalyst depends on the voltage profile and the upper potential level. By this Pt mass loss is more significant at the membrane surface than at the gas diffusion layer.

    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Journal of Power Sou...arrow_drop_down
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    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    https://dx.doi.org/10.48550/ar...
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    Journal of Power Sources
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      https://dx.doi.org/10.48550/ar...
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    Authors: Sean C. Lema; J. Adam Luckenbach; Yoji Yamamoto; Madeline J. Housh;

    Reproduction in fishes is sensitive to temperature. Elevated temperatures and anomalous ‘heat waves’ associated with climate change have the potential to impact fish reproductive performance and, in some cases, even induce sex reversals. Here we examine how thermal sensitivity in the hormone pathways regulating reproduction provides a framework for understanding impacts of warmer conditions on fish reproduction. Such effects will differ depending on evolved variation in temperature sensitivity of endocrine pathways regulating reproductive processes of sex determination/differentiation, gametogenesis and spawning, as well as how developmental timing of those processes varies with reproductive ecology. For fish populations unable to shift geographical range, persistence under future climates may require changes in temperature responsiveness of the hormone pathways regulating reproductive processes. How thermal sensitivity in those hormone pathways varies among populations and species, how those pathways generate temperature maxima for reproduction, and how rapidly reproductive thermal tolerances can change via adaptation or transgenerational plasticity will shape which fishes are most at risk for impaired reproduction under rising temperatures. This article is part of the theme issue ‘Endocrine responses to environmental variation: conceptual approaches and recent developments’.

    image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Philosophical Transa...arrow_drop_down
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    Authors: Sean C. Lema; J. Adam Luckenbach; Yoji Yamamoto; Madeline J. Housh;

    Reproduction in fishes is sensitive to temperature. Elevated temperatures and anomalous ‘heat waves’ associated with climate change have the potential to impact fish reproductive performance and, in some cases, even induce sex reversals. Here we examine how thermal sensitivity in the hormone pathways regulating reproduction provides a framework for understanding impacts of warmer conditions on fish reproduction. Such effects will differ depending on evolved variation in temperature sensitivity of endocrine pathways regulating reproductive processes of sex determination/differentiation, gametogenesis and spawning, as well as how developmental timing of those processes varies with reproductive ecology. For fish populations unable to shift geographical range, persistence under future climates may require changes in temperature responsiveness of the hormone pathways regulating reproductive processes. How thermal sensitivity in those hormone pathways varies among populations and species, how those pathways generate temperature maxima for reproduction, and how rapidly reproductive thermal tolerances can change via adaptation or transgenerational plasticity will shape which fishes are most at risk for impaired reproduction under rising temperatures. This article is part of the theme issue ‘Endocrine responses to environmental variation: conceptual approaches and recent developments’.

    image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Philosophical Transa...arrow_drop_down
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    Authors: Pavel Pashkovskiy; Vladimir D. Kreslavski; Yury Ivanov; Alexandra Ivanova; +5 Authors

    Varying the spectral composition of light is one of the ways to accelerate the growth of conifers under artificial conditions for the development of technologies and to obtain sustainable seedlings required to preserve the existing areas of forests. We studied the influence of light of different quality on the growth, gas exchange, fluorescence indices of Chl a, and expression of key light-dependent genes of Pinus sylvestris L. seedlings. It was shown that in plants growing under red light (RL), the biomass of needles and root system increased by more than two and three times, respectively, compared with those of the white fluorescent light (WFL) control. At the same time, the rates of photosynthesis and respiration in RL and blue light (BL) plants were lower than those of blue red light (BRL) plants, and the difference between the rates of photosynthesis and respiration, which characterizes the carbon balance, was maximum under RL. RL influenced the number of xylem cells, activated the expression of genes involved in the transduction of cytokinin (Histidine-containing phosphotransfer 1, HPT1, Type-A Response Regulators, RR-A) and auxin (Auxin-induced protein 1, Aux/IAA) signals, and reduced the expression of the gene encoding the transcription factor phytochrome-interacting factor 3 (PIF3). It was suggested that RL-induced activation of key genes of cytokinin and auxin signaling might indicate a phytochrome-dependent change in cytokinins and auxins activity.

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    Authors: Pavel Pashkovskiy; Vladimir D. Kreslavski; Yury Ivanov; Alexandra Ivanova; +5 Authors

    Varying the spectral composition of light is one of the ways to accelerate the growth of conifers under artificial conditions for the development of technologies and to obtain sustainable seedlings required to preserve the existing areas of forests. We studied the influence of light of different quality on the growth, gas exchange, fluorescence indices of Chl a, and expression of key light-dependent genes of Pinus sylvestris L. seedlings. It was shown that in plants growing under red light (RL), the biomass of needles and root system increased by more than two and three times, respectively, compared with those of the white fluorescent light (WFL) control. At the same time, the rates of photosynthesis and respiration in RL and blue light (BL) plants were lower than those of blue red light (BRL) plants, and the difference between the rates of photosynthesis and respiration, which characterizes the carbon balance, was maximum under RL. RL influenced the number of xylem cells, activated the expression of genes involved in the transduction of cytokinin (Histidine-containing phosphotransfer 1, HPT1, Type-A Response Regulators, RR-A) and auxin (Auxin-induced protein 1, Aux/IAA) signals, and reduced the expression of the gene encoding the transcription factor phytochrome-interacting factor 3 (PIF3). It was suggested that RL-induced activation of key genes of cytokinin and auxin signaling might indicate a phytochrome-dependent change in cytokinins and auxins activity.

    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Cellsarrow_drop_down
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    Authors: Lilia Abunaeva; Natalia Kartashova; Kirill Karpenko; Dmitry Chikin; +6 Authors

    The proposed anthraquinone-bromate cell combines the advantages of anthraquinone-bromine redox flow batteries and novel hybrid hydrogen-bromate flow batteries. The anthraquinone-2,7-disulfonic acid is of interest as a promising organic negolyte due its high solubility, rapid kinetics of electrode reactions and suitable redox potentials combined with a high chemical stability during redox reactions. Lithium or sodium bromates as posolytes provide an anomalously high discharge current density of order ~A cm−2 due to a novel autocatalytic mechanism. Combining these two systems, we developed a single cell of novel anthraquinone-bromate flow battery, which showed a power density of 1.08 W cm−2, energy density of 16.1 W h L−1 and energy efficiency of 72% after 10 charge–discharge cycles.

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    Authors: Lilia Abunaeva; Natalia Kartashova; Kirill Karpenko; Dmitry Chikin; +6 Authors

    The proposed anthraquinone-bromate cell combines the advantages of anthraquinone-bromine redox flow batteries and novel hybrid hydrogen-bromate flow batteries. The anthraquinone-2,7-disulfonic acid is of interest as a promising organic negolyte due its high solubility, rapid kinetics of electrode reactions and suitable redox potentials combined with a high chemical stability during redox reactions. Lithium or sodium bromates as posolytes provide an anomalously high discharge current density of order ~A cm−2 due to a novel autocatalytic mechanism. Combining these two systems, we developed a single cell of novel anthraquinone-bromate flow battery, which showed a power density of 1.08 W cm−2, energy density of 16.1 W h L−1 and energy efficiency of 72% after 10 charge–discharge cycles.

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    Energies
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    Authors: Larisa V. Arapkina; Kirill V. Chizh; Dmitry B. Stavrovskii; Vladimir P. Dubkov; +2 Authors

    In this article, the results of investigation of processes occurring during the molecular-beam deposition of germanium layers on Si$_3$N$_4$ dielectric substrates within a wide range of the Ge film growth temperatures (30 to 600��C) are presented. The intensity of the IR absorption bands related to the vibrations of the N$-$H and Si$-$N bonds are established to decrease with the increase of the Ge deposition temperature. It appears that this phenomenon cannot be explained only as a thermally activated process. Simultaneously, the peak corresponding to the Ge$-$N vibration bonds emerges in the X-ray photoelectron spectra. We suppose that the deposition of germanium layers on Si3N4 dielectric substrates containing hydrogen atoms causes the diffusion of hydrogen atoms from the dielectric layer into the growing film. The experimental results may be interpreted in terms of a model, according to which the migration of hydrogen atoms from the Si$_3$N$_4$ layer into the growing germanium film is due to the difference in chemical potentials of hydrogen atoms in the dielectric layer and the germanium film. This process initiates the diffusion of germanium atoms in the opposite direction, into the Si$_3$N$_4$ layer, where they connect to free bonds of nitrogen atoms arising due to the escape of hydrogen atoms. The analogous processes occur during the deposition of silicon layers on Si$_3$N$_4$ substrates. 38 pages, 9 figures

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    Solar Energy Materials and Solar Cells
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    Authors: Larisa V. Arapkina; Kirill V. Chizh; Dmitry B. Stavrovskii; Vladimir P. Dubkov; +2 Authors

    In this article, the results of investigation of processes occurring during the molecular-beam deposition of germanium layers on Si$_3$N$_4$ dielectric substrates within a wide range of the Ge film growth temperatures (30 to 600��C) are presented. The intensity of the IR absorption bands related to the vibrations of the N$-$H and Si$-$N bonds are established to decrease with the increase of the Ge deposition temperature. It appears that this phenomenon cannot be explained only as a thermally activated process. Simultaneously, the peak corresponding to the Ge$-$N vibration bonds emerges in the X-ray photoelectron spectra. We suppose that the deposition of germanium layers on Si3N4 dielectric substrates containing hydrogen atoms causes the diffusion of hydrogen atoms from the dielectric layer into the growing film. The experimental results may be interpreted in terms of a model, according to which the migration of hydrogen atoms from the Si$_3$N$_4$ layer into the growing germanium film is due to the difference in chemical potentials of hydrogen atoms in the dielectric layer and the germanium film. This process initiates the diffusion of germanium atoms in the opposite direction, into the Si$_3$N$_4$ layer, where they connect to free bonds of nitrogen atoms arising due to the escape of hydrogen atoms. The analogous processes occur during the deposition of silicon layers on Si$_3$N$_4$ substrates. 38 pages, 9 figures

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    Solar Energy Materials and Solar Cells
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    Authors: Alexey V. Shishkin; Vladimir Yu. Shishkin; Anna A. Maslennikova; Aleksander B. Salyulev; +2 Authors

    The electrochemical reduction of pelleted heterophase powder Pd-Nd2O3-CeO2 mixtures was studied in molten LiCl-Li2O (1–1.5 wt%) at 650 °C. The influence of the composition of the mixture, as well as electrochemical factors—i.e., the amount of electricity passed and the cathode potential during electrolysis—were considered. It was found that in the presence of metallic palladium, neodymium and cerium oxides are reduced by lithium released at the cathode and form intermetallic compounds of different compositions. At potentials more positive than the formation of a phase based on liquid lithium at 0.5–0.8 V, CePd3 and NdPd3 intermetallic compounds are present in the reduced product. At potentials close to the formation of liquid lithium, a whole spectrum of intermetallic compounds is synthesized: CePd, NdPd, Ce3Pd4, and Nd3Pd4. The mechanisms of formation of palladium alloys with neodymium and cerium are proposed and considered. The degree of the reduction of lanthanide oxides was calculated from the data on the concentration of residual oxygen in the reduced product.

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    Authors: Alexey V. Shishkin; Vladimir Yu. Shishkin; Anna A. Maslennikova; Aleksander B. Salyulev; +2 Authors

    The electrochemical reduction of pelleted heterophase powder Pd-Nd2O3-CeO2 mixtures was studied in molten LiCl-Li2O (1–1.5 wt%) at 650 °C. The influence of the composition of the mixture, as well as electrochemical factors—i.e., the amount of electricity passed and the cathode potential during electrolysis—were considered. It was found that in the presence of metallic palladium, neodymium and cerium oxides are reduced by lithium released at the cathode and form intermetallic compounds of different compositions. At potentials more positive than the formation of a phase based on liquid lithium at 0.5–0.8 V, CePd3 and NdPd3 intermetallic compounds are present in the reduced product. At potentials close to the formation of liquid lithium, a whole spectrum of intermetallic compounds is synthesized: CePd, NdPd, Ce3Pd4, and Nd3Pd4. The mechanisms of formation of palladium alloys with neodymium and cerium are proposed and considered. The degree of the reduction of lanthanide oxides was calculated from the data on the concentration of residual oxygen in the reduced product.

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    Authors: Silvio Marta; Roberto Sergio Azzoni; Davide Fugazza; Levan Tielidze; +41 Authors

    Most of the world’s mountain glaciers have been retreating for more than a century in response to climate change. Glacier retreat is evident on all continents, and the rate of retreat has accelerated during recent decades. Accurate, spatially explicit information on the position of glacier margins over time is useful for analyzing patterns of glacier retreat and measuring reductions in glacier surface area. This information is also essential for evaluating how mountain ecosystems are evolving due to climate warming and the attendant glacier retreat. Here, we present a non-comprehensive spatially explicit dataset showing multiple positions of glacier fronts since the Little Ice Age (LIA) maxima, including many data from the pre-satellite era. The dataset is based on multiple historical archival records including topographical maps; repeated photographs, paintings, and aerial or satellite images with a supplement of geochronology; and own field data. We provide ESRI shapefiles showing 728 past positions of 94 glacier fronts from all continents, except Antarctica, covering the period between the Little Ice Age maxima and the present. On average, the time series span the past 190 years. From 2 to 46 past positions per glacier are depicted (on average: 7.8).

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    Authors: Silvio Marta; Roberto Sergio Azzoni; Davide Fugazza; Levan Tielidze; +41 Authors

    Most of the world’s mountain glaciers have been retreating for more than a century in response to climate change. Glacier retreat is evident on all continents, and the rate of retreat has accelerated during recent decades. Accurate, spatially explicit information on the position of glacier margins over time is useful for analyzing patterns of glacier retreat and measuring reductions in glacier surface area. This information is also essential for evaluating how mountain ecosystems are evolving due to climate warming and the attendant glacier retreat. Here, we present a non-comprehensive spatially explicit dataset showing multiple positions of glacier fronts since the Little Ice Age (LIA) maxima, including many data from the pre-satellite era. The dataset is based on multiple historical archival records including topographical maps; repeated photographs, paintings, and aerial or satellite images with a supplement of geochronology; and own field data. We provide ESRI shapefiles showing 728 past positions of 94 glacier fronts from all continents, except Antarctica, covering the period between the Little Ice Age maxima and the present. On average, the time series span the past 190 years. From 2 to 46 past positions per glacier are depicted (on average: 7.8).

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      Article . 2021 . Peer-reviewed
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    Authors: A. V. Zhuikov; D. A. Loginov; G. R. Mongush; S. V. Chicherin; +1 Authors

    The process of combusting Tuva coals before and after their carbonization was studied using the methods of thermogravimetric analysis and electron microscopy. Coal samples were subjected to thermomechanical and elemental analysis, which revealed a higher content of volatile substances in Kaa-Khem coal (47.5 %) compared to Chadan coal (10 %). Following carbonization, a decrease in volatile substances to 11.5 % and 9.3 %, respectively, was observed. The conducted thermogravimetric analysis showed the ignition temperature of the coke residue of the Kaa-Khem and Chadan coal samples to increase by 76 °C and 90 °C, respectively, after carbonization. The burnup temperature of the coke residue after carbonizing (723 °C) Kaa-Khem coal samples remained effectively the same, while the Chadan coal showed an increase from 704 °C to 727 °C. The carbonization of coals was established to decrease the maximum reaction rate from 19 % per min to 10% per min for Kaa-Khem coal and from 26 % per min to 11 % per min for Chadan coal. The process of combusting the coke residue after coal carbonization was found to shift into the region of higher temperatures: from 448–723°C to 524–724°C for Kaa-Khem coal and from 436–704 °C to 526–727 °C for Chadan coal. A morphological analysis of the surface of coal particles after carbonization showed the appearance of larger-size pores and cracks on the surface of carbonates compared to coal before carbonization. The conclusion is made that the content of volatile substances, rather than the developed pore structure, comprises the main factor in improving the combustion characteristics of Tuva coals under the conditions of non-isothermal heating before and after their carbonization.

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    Authors: A. V. Zhuikov; D. A. Loginov; G. R. Mongush; S. V. Chicherin; +1 Authors

    The process of combusting Tuva coals before and after their carbonization was studied using the methods of thermogravimetric analysis and electron microscopy. Coal samples were subjected to thermomechanical and elemental analysis, which revealed a higher content of volatile substances in Kaa-Khem coal (47.5 %) compared to Chadan coal (10 %). Following carbonization, a decrease in volatile substances to 11.5 % and 9.3 %, respectively, was observed. The conducted thermogravimetric analysis showed the ignition temperature of the coke residue of the Kaa-Khem and Chadan coal samples to increase by 76 °C and 90 °C, respectively, after carbonization. The burnup temperature of the coke residue after carbonizing (723 °C) Kaa-Khem coal samples remained effectively the same, while the Chadan coal showed an increase from 704 °C to 727 °C. The carbonization of coals was established to decrease the maximum reaction rate from 19 % per min to 10% per min for Kaa-Khem coal and from 26 % per min to 11 % per min for Chadan coal. The process of combusting the coke residue after coal carbonization was found to shift into the region of higher temperatures: from 448–723°C to 524–724°C for Kaa-Khem coal and from 436–704 °C to 526–727 °C for Chadan coal. A morphological analysis of the surface of coal particles after carbonization showed the appearance of larger-size pores and cracks on the surface of carbonates compared to coal before carbonization. The conclusion is made that the content of volatile substances, rather than the developed pore structure, comprises the main factor in improving the combustion characteristics of Tuva coals under the conditions of non-isothermal heating before and after their carbonization.

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    Authors: P. N. Petrova; E.S. Kolesova; F.F. Protopopov; O. V. Gogoleva;
    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Petroleum Engineerin...arrow_drop_down
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    Petroleum Engineering
    Article . 2021 . Peer-reviewed
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      Petroleum Engineering
      Article . 2021 . Peer-reviewed
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    Authors: P. N. Petrova; E.S. Kolesova; F.F. Protopopov; O. V. Gogoleva;
    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Petroleum Engineerin...arrow_drop_down
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    Petroleum Engineering
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      Petroleum Engineering
      Article . 2021 . Peer-reviewed
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    Authors: Kennedy Masamba; Wisdom Changadeya; Pheneas Ntawuruhunga; Pilirani Pankomera; +2 Authors

    Cassava utilisation in Malawi is negatively affected by rapid deterioration of fresh roots, primarily caused by postharvest physiological deterioration (PPD). A study was conducted to assess farmers’ knowledge and approaches used to minimize losses from PPD. Multi-stage sampling was used to identify districts, Extension Planning Areas (EPA’s) and farmers. Data were collected from 519 farmers using a structured questionnaire. Results revealed that PPD (74.0%) was the major post-harvest constraint followed by pests and diseases (62.1%). Farmers had varying knowledge levels on signs and causes of PPD. They were knowledgeable on PPD signs with 91.5% ably identifying PPD through change of pulp colour. The farmers also had moderate knowledge on causes of PPD, citing high temperature (57.6%) and over-staying of roots (56.2%) as main causes of PPD. Key methods for preventing PPD are: storage (43.0%) and piece-meal harvesting (40.4%). Only 2.6% of the farmers exploited varietal difference in dealing with PPD as some varieties (Sauti, Mpuma, Ching’amba, and Kalasa) take three to five days before showing PPD signs. Farmers’ knowledge levels and PPD preventive methods could be strengthened through: provision of training on post-harvest handling, improvement in storage and processing technologies; and application of advanced breeding techniques to exploit genetic variation in cassava germplasm.

    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Sustainabilityarrow_drop_down
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    Authors: Kennedy Masamba; Wisdom Changadeya; Pheneas Ntawuruhunga; Pilirani Pankomera; +2 Authors

    Cassava utilisation in Malawi is negatively affected by rapid deterioration of fresh roots, primarily caused by postharvest physiological deterioration (PPD). A study was conducted to assess farmers’ knowledge and approaches used to minimize losses from PPD. Multi-stage sampling was used to identify districts, Extension Planning Areas (EPA’s) and farmers. Data were collected from 519 farmers using a structured questionnaire. Results revealed that PPD (74.0%) was the major post-harvest constraint followed by pests and diseases (62.1%). Farmers had varying knowledge levels on signs and causes of PPD. They were knowledgeable on PPD signs with 91.5% ably identifying PPD through change of pulp colour. The farmers also had moderate knowledge on causes of PPD, citing high temperature (57.6%) and over-staying of roots (56.2%) as main causes of PPD. Key methods for preventing PPD are: storage (43.0%) and piece-meal harvesting (40.4%). Only 2.6% of the farmers exploited varietal difference in dealing with PPD as some varieties (Sauti, Mpuma, Ching’amba, and Kalasa) take three to five days before showing PPD signs. Farmers’ knowledge levels and PPD preventive methods could be strengthened through: provision of training on post-harvest handling, improvement in storage and processing technologies; and application of advanced breeding techniques to exploit genetic variation in cassava germplasm.

    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Sustainabilityarrow_drop_down
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    This paper is devoted to study the electrochemical behavior of Pt catalyst in a polymer electrolyte fuel cell at various operating conditions and at different electric potential difference (also known as voltage) cycling applied in accelerated stress tests. The degradation of platinum is considered with respect to the Pt ion dissolution and the Pt oxide coverage of catalyst described by a one-dimensional model. In the model, degradation rate increases with temperature and decreasing particle diameter of Pt nano-particles. The theoretical study of the underlying diffusion system with the nonlinear reactions is presented by analytical methods and gives explicit solutions through a first integral of the ODE system. Numerical tests are obtained using a second order implicit-explicit scheme. The computer simulation shows that the lifetime of the catalyst depends on the voltage profile and the upper potential level. By this Pt mass loss is more significant at the membrane surface than at the gas diffusion layer.

    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Journal of Power Sou...arrow_drop_down
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    https://dx.doi.org/10.48550/ar...
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    image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
    Journal of Power Sources
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      https://dx.doi.org/10.48550/ar...
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      Journal of Power Sources
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    This paper is devoted to study the electrochemical behavior of Pt catalyst in a polymer electrolyte fuel cell at various operating conditions and at different electric potential difference (also known as voltage) cycling applied in accelerated stress tests. The degradation of platinum is considered with respect to the Pt ion dissolution and the Pt oxide coverage of catalyst described by a one-dimensional model. In the model, degradation rate increases with temperature and decreasing particle diameter of Pt nano-particles. The theoretical study of the underlying diffusion system with the nonlinear reactions is presented by analytical methods and gives explicit solutions through a first integral of the ODE system. Numerical tests are obtained using a second order implicit-explicit scheme. The computer simulation shows that the lifetime of the catalyst depends on the voltage profile and the upper potential level. By this Pt mass loss is more significant at the membrane surface than at the gas diffusion layer.

    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Journal of Power Sou...arrow_drop_down
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    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    https://dx.doi.org/10.48550/ar...
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    Journal of Power Sources
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      https://dx.doi.org/10.48550/ar...
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    Authors: Sean C. Lema; J. Adam Luckenbach; Yoji Yamamoto; Madeline J. Housh;

    Reproduction in fishes is sensitive to temperature. Elevated temperatures and anomalous ‘heat waves’ associated with climate change have the potential to impact fish reproductive performance and, in some cases, even induce sex reversals. Here we examine how thermal sensitivity in the hormone pathways regulating reproduction provides a framework for understanding impacts of warmer conditions on fish reproduction. Such effects will differ depending on evolved variation in temperature sensitivity of endocrine pathways regulating reproductive processes of sex determination/differentiation, gametogenesis and spawning, as well as how developmental timing of those processes varies with reproductive ecology. For fish populations unable to shift geographical range, persistence under future climates may require changes in temperature responsiveness of the hormone pathways regulating reproductive processes. How thermal sensitivity in those hormone pathways varies among populations and species, how those pathways generate temperature maxima for reproduction, and how rapidly reproductive thermal tolerances can change via adaptation or transgenerational plasticity will shape which fishes are most at risk for impaired reproduction under rising temperatures. This article is part of the theme issue ‘Endocrine responses to environmental variation: conceptual approaches and recent developments’.

    image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Philosophical Transa...arrow_drop_down
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    Authors: Sean C. Lema; J. Adam Luckenbach; Yoji Yamamoto; Madeline J. Housh;

    Reproduction in fishes is sensitive to temperature. Elevated temperatures and anomalous ‘heat waves’ associated with climate change have the potential to impact fish reproductive performance and, in some cases, even induce sex reversals. Here we examine how thermal sensitivity in the hormone pathways regulating reproduction provides a framework for understanding impacts of warmer conditions on fish reproduction. Such effects will differ depending on evolved variation in temperature sensitivity of endocrine pathways regulating reproductive processes of sex determination/differentiation, gametogenesis and spawning, as well as how developmental timing of those processes varies with reproductive ecology. For fish populations unable to shift geographical range, persistence under future climates may require changes in temperature responsiveness of the hormone pathways regulating reproductive processes. How thermal sensitivity in those hormone pathways varies among populations and species, how those pathways generate temperature maxima for reproduction, and how rapidly reproductive thermal tolerances can change via adaptation or transgenerational plasticity will shape which fishes are most at risk for impaired reproduction under rising temperatures. This article is part of the theme issue ‘Endocrine responses to environmental variation: conceptual approaches and recent developments’.

    image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Philosophical Transa...arrow_drop_down
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    Authors: Pavel Pashkovskiy; Vladimir D. Kreslavski; Yury Ivanov; Alexandra Ivanova; +5 Authors

    Varying the spectral composition of light is one of the ways to accelerate the growth of conifers under artificial conditions for the development of technologies and to obtain sustainable seedlings required to preserve the existing areas of forests. We studied the influence of light of different quality on the growth, gas exchange, fluorescence indices of Chl a, and expression of key light-dependent genes of Pinus sylvestris L. seedlings. It was shown that in plants growing under red light (RL), the biomass of needles and root system increased by more than two and three times, respectively, compared with those of the white fluorescent light (WFL) control. At the same time, the rates of photosynthesis and respiration in RL and blue light (BL) plants were lower than those of blue red light (BRL) plants, and the difference between the rates of photosynthesis and respiration, which characterizes the carbon balance, was maximum under RL. RL influenced the number of xylem cells, activated the expression of genes involved in the transduction of cytokinin (Histidine-containing phosphotransfer 1, HPT1, Type-A Response Regulators, RR-A) and auxin (Auxin-induced protein 1, Aux/IAA) signals, and reduced the expression of the gene encoding the transcription factor phytochrome-interacting factor 3 (PIF3). It was suggested that RL-induced activation of key genes of cytokinin and auxin signaling might indicate a phytochrome-dependent change in cytokinins and auxins activity.

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    Authors: Pavel Pashkovskiy; Vladimir D. Kreslavski; Yury Ivanov; Alexandra Ivanova; +5 Authors

    Varying the spectral composition of light is one of the ways to accelerate the growth of conifers under artificial conditions for the development of technologies and to obtain sustainable seedlings required to preserve the existing areas of forests. We studied the influence of light of different quality on the growth, gas exchange, fluorescence indices of Chl a, and expression of key light-dependent genes of Pinus sylvestris L. seedlings. It was shown that in plants growing under red light (RL), the biomass of needles and root system increased by more than two and three times, respectively, compared with those of the white fluorescent light (WFL) control. At the same time, the rates of photosynthesis and respiration in RL and blue light (BL) plants were lower than those of blue red light (BRL) plants, and the difference between the rates of photosynthesis and respiration, which characterizes the carbon balance, was maximum under RL. RL influenced the number of xylem cells, activated the expression of genes involved in the transduction of cytokinin (Histidine-containing phosphotransfer 1, HPT1, Type-A Response Regulators, RR-A) and auxin (Auxin-induced protein 1, Aux/IAA) signals, and reduced the expression of the gene encoding the transcription factor phytochrome-interacting factor 3 (PIF3). It was suggested that RL-induced activation of key genes of cytokinin and auxin signaling might indicate a phytochrome-dependent change in cytokinins and auxins activity.

    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Cellsarrow_drop_down
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    Authors: Lilia Abunaeva; Natalia Kartashova; Kirill Karpenko; Dmitry Chikin; +6 Authors

    The proposed anthraquinone-bromate cell combines the advantages of anthraquinone-bromine redox flow batteries and novel hybrid hydrogen-bromate flow batteries. The anthraquinone-2,7-disulfonic acid is of interest as a promising organic negolyte due its high solubility, rapid kinetics of electrode reactions and suitable redox potentials combined with a high chemical stability during redox reactions. Lithium or sodium bromates as posolytes provide an anomalously high discharge current density of order ~A cm−2 due to a novel autocatalytic mechanism. Combining these two systems, we developed a single cell of novel anthraquinone-bromate flow battery, which showed a power density of 1.08 W cm−2, energy density of 16.1 W h L−1 and energy efficiency of 72% after 10 charge–discharge cycles.

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    Authors: Lilia Abunaeva; Natalia Kartashova; Kirill Karpenko; Dmitry Chikin; +6 Authors

    The proposed anthraquinone-bromate cell combines the advantages of anthraquinone-bromine redox flow batteries and novel hybrid hydrogen-bromate flow batteries. The anthraquinone-2,7-disulfonic acid is of interest as a promising organic negolyte due its high solubility, rapid kinetics of electrode reactions and suitable redox potentials combined with a high chemical stability during redox reactions. Lithium or sodium bromates as posolytes provide an anomalously high discharge current density of order ~A cm−2 due to a novel autocatalytic mechanism. Combining these two systems, we developed a single cell of novel anthraquinone-bromate flow battery, which showed a power density of 1.08 W cm−2, energy density of 16.1 W h L−1 and energy efficiency of 72% after 10 charge–discharge cycles.

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    Authors: Larisa V. Arapkina; Kirill V. Chizh; Dmitry B. Stavrovskii; Vladimir P. Dubkov; +2 Authors

    In this article, the results of investigation of processes occurring during the molecular-beam deposition of germanium layers on Si$_3$N$_4$ dielectric substrates within a wide range of the Ge film growth temperatures (30 to 600��C) are presented. The intensity of the IR absorption bands related to the vibrations of the N$-$H and Si$-$N bonds are established to decrease with the increase of the Ge deposition temperature. It appears that this phenomenon cannot be explained only as a thermally activated process. Simultaneously, the peak corresponding to the Ge$-$N vibration bonds emerges in the X-ray photoelectron spectra. We suppose that the deposition of germanium layers on Si3N4 dielectric substrates containing hydrogen atoms causes the diffusion of hydrogen atoms from the dielectric layer into the growing film. The experimental results may be interpreted in terms of a model, according to which the migration of hydrogen atoms from the Si$_3$N$_4$ layer into the growing germanium film is due to the difference in chemical potentials of hydrogen atoms in the dielectric layer and the germanium film. This process initiates the diffusion of germanium atoms in the opposite direction, into the Si$_3$N$_4$ layer, where they connect to free bonds of nitrogen atoms arising due to the escape of hydrogen atoms. The analogous processes occur during the deposition of silicon layers on Si$_3$N$_4$ substrates. 38 pages, 9 figures

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    Solar Energy Materials and Solar Cells
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    Authors: Larisa V. Arapkina; Kirill V. Chizh; Dmitry B. Stavrovskii; Vladimir P. Dubkov; +2 Authors

    In this article, the results of investigation of processes occurring during the molecular-beam deposition of germanium layers on Si$_3$N$_4$ dielectric substrates within a wide range of the Ge film growth temperatures (30 to 600��C) are presented. The intensity of the IR absorption bands related to the vibrations of the N$-$H and Si$-$N bonds are established to decrease with the increase of the Ge deposition temperature. It appears that this phenomenon cannot be explained only as a thermally activated process. Simultaneously, the peak corresponding to the Ge$-$N vibration bonds emerges in the X-ray photoelectron spectra. We suppose that the deposition of germanium layers on Si3N4 dielectric substrates containing hydrogen atoms causes the diffusion of hydrogen atoms from the dielectric layer into the growing film. The experimental results may be interpreted in terms of a model, according to which the migration of hydrogen atoms from the Si$_3$N$_4$ layer into the growing germanium film is due to the difference in chemical potentials of hydrogen atoms in the dielectric layer and the germanium film. This process initiates the diffusion of germanium atoms in the opposite direction, into the Si$_3$N$_4$ layer, where they connect to free bonds of nitrogen atoms arising due to the escape of hydrogen atoms. The analogous processes occur during the deposition of silicon layers on Si$_3$N$_4$ substrates. 38 pages, 9 figures

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    Authors: Alexey V. Shishkin; Vladimir Yu. Shishkin; Anna A. Maslennikova; Aleksander B. Salyulev; +2 Authors

    The electrochemical reduction of pelleted heterophase powder Pd-Nd2O3-CeO2 mixtures was studied in molten LiCl-Li2O (1–1.5 wt%) at 650 °C. The influence of the composition of the mixture, as well as electrochemical factors—i.e., the amount of electricity passed and the cathode potential during electrolysis—were considered. It was found that in the presence of metallic palladium, neodymium and cerium oxides are reduced by lithium released at the cathode and form intermetallic compounds of different compositions. At potentials more positive than the formation of a phase based on liquid lithium at 0.5–0.8 V, CePd3 and NdPd3 intermetallic compounds are present in the reduced product. At potentials close to the formation of liquid lithium, a whole spectrum of intermetallic compounds is synthesized: CePd, NdPd, Ce3Pd4, and Nd3Pd4. The mechanisms of formation of palladium alloys with neodymium and cerium are proposed and considered. The degree of the reduction of lanthanide oxides was calculated from the data on the concentration of residual oxygen in the reduced product.

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    Authors: Alexey V. Shishkin; Vladimir Yu. Shishkin; Anna A. Maslennikova; Aleksander B. Salyulev; +2 Authors

    The electrochemical reduction of pelleted heterophase powder Pd-Nd2O3-CeO2 mixtures was studied in molten LiCl-Li2O (1–1.5 wt%) at 650 °C. The influence of the composition of the mixture, as well as electrochemical factors—i.e., the amount of electricity passed and the cathode potential during electrolysis—were considered. It was found that in the presence of metallic palladium, neodymium and cerium oxides are reduced by lithium released at the cathode and form intermetallic compounds of different compositions. At potentials more positive than the formation of a phase based on liquid lithium at 0.5–0.8 V, CePd3 and NdPd3 intermetallic compounds are present in the reduced product. At potentials close to the formation of liquid lithium, a whole spectrum of intermetallic compounds is synthesized: CePd, NdPd, Ce3Pd4, and Nd3Pd4. The mechanisms of formation of palladium alloys with neodymium and cerium are proposed and considered. The degree of the reduction of lanthanide oxides was calculated from the data on the concentration of residual oxygen in the reduced product.

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