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Research data keyboard_double_arrow_right Dataset 2022Publisher:Zenodo Funded by:UKRI | Fashion Fictions: imagini...UKRI| Fashion Fictions: imagining sustainable fashion worldsAuthors: Twigger Holroyd, Amy;This dataset was generated via a focused piece of research conducted by Dr Matilda Aspinall and Dr Amy Twigger Holroyd which investigated the experiences of students and staff involved in Fashion Fictions projects in 2022 at two institutions: LASALLE College of the Arts in Singapore and Nottingham Trent University. This focused research was situated within the broader Fashion Fictions project. Fashion Fictions, founded by Amy Twigger Holroyd in 2020, brings people together to generate, experience and reflect on engaging fictional visions of alternative fashion cultures and systems. Through these activities, we gain new perspectives on challenges, possibilities and pathways for change in the real world. The project is structured in three stages. Stage 1 prompts contributors to create brief written outlines of fictional fashion cultures and systems, known as Worlds; at Stage 2, participants put flesh on these outlines and create visual or material prototypes to represent their cultures, known as Explorations; at Stage 3, they performatively enact practices or events from the fictional worlds. To find out more about Fashion Fictions, visit the project website. To see other data linked to the project, visit the Fashion Fictions Zenodo community. -------------------------------- In both institutions, Fashion Fictions was initially introduced to the curriculum in the 2020/21 academic year; the activities discussed here took place in the following year, with a second cohort of students. At NTU, first-year undergraduate students from BA (Hons) courses in Fashion Design, Textile Design and Fashion Knitwear Design & Knitted Textiles undertook a short Stage 2 Fashion Fictions project. Spanning three two-hour workshops, the project was part of a Future Thinking toolkit within a module that aims to develop students’ intellectual curiosity and appreciation of the future as something that can be shaped and questioned. Working in small cross-course groups, students were given a specified Stage 1 fiction and asked to create a visual or material prototype to represent everyday life in that world, presented via a selection of images and a short explanatory text. At LASALLE, Fashion Fictions was set up as a major project extending across a 14-week semester for second-year students on two BA (Hons) programmes: Fashion Media and Industries and Fashion Design and Textiles. Also working in cross-course collaborative groups, the students first created their own Stage 1 world and then progressed to create a collection of Stage 2 prototypes in the form of garments and related media such as photographs and films, accompanied by an extensive body of supporting work. -------------------------------- in April and May 2022 we conducted semi-structured interviews with tutors involved in the projects – Lorraine Warde (Principal Lecturer in Fashion Design) at NTU and Martin Bonney and Kathryn Shannon Sim Yen Ping (Lecturers in Fashion, interviewed together) at LASALLE – and with three student groups, selected by the tutors, from each institution. The interview schedules for students and tutors each comprised four reflective questions, designed to gain an insight into the students’ experiences and the tutors’ observations. Each recorded interview lasted between twenty and sixty minutes. -------------------------------- The dataset is organised in nine folders: 1 Project context Project website About page from February 2022 (explaining the wider project at the time of this research). Project website Education projects page from January 2022 (giving context to the education projects taking place at the time of this research). 2 Activity guidance Project website Stage 1 (World) online guide from January 2022 (as available for use by LASALLE students). NTU virtual workspace Stage 2 (Exploration) guidance (as used by NTU students and providing an indication of the type of guidance that would have been offered to LASALLE students for their Stage 2 work - although their project was much longer in duration). 3 Interview documentation Information sheet and consent form given to research participants. Interview questions for staff and students, shared with all participants in advance. 4 LASALLE staff interview Transcript of interview with Martin Bonney and Kathryn Shannon Sim Yen Ping (Lecturers in Fashion). 5 LASALLE student interviews Transcripts of interviews with three student groups, each identified by the number/letter of the Stage 1 World and Stage 2 Exploration they created (as listed on the project website Worlds and Explorations pages). 6 LASALLE student work Project work (Stage 1 Worlds and Stage 2 Explorations) created by the three student groups interviewed, as displayed on the project website. One group (World 154) did not submit their Exploration for the website. 7 NTU staff interview Transcript of interview with Lorraine Warde (Principal Lecturer in Fashion Design). 8 NTU student interviews Transcripts of interviews with three student groups, each identified by the number/letter of the Stage 2 Exploration they created (as listed on the project website Explorations page). 9 NTU student work Project work (Stage 2 Explorations) created by the three student groups interviewed. Two groups' work is as displayed on the project website. One group (World 95, Exploration X) did not submit their Exploration for the website and so their internal presentation has been included instead.
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You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
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For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Article 2024 United KingdomPublisher:Elsevier BV Authors: David P, Edwards; Gianluca R, Cerullo;pmid: 38714168
The global restoration agenda can help solve the biodiversity extinction crisis by regenerating biodiversity-rich ecosystems, maximising conservation benefits using natural regeneration. Yet, conservation is rarely the core objective of restoration, and biodiversity is often neglected in restoration projects targeted towards carbon sequestration or enhancing ecosystem services for improved local livelihoods. Here, we synthesise evidence to show that promoting biodiversity in restoration planning and delivery is integral to delivering other long-term restoration aims, such as carbon sequestration, timber production, enhanced local farm yields, reduced soil erosion, recovered hydrological services and improved human health. For each of these restoration goals, biodiversity must be a keystone objective to the entire process. Biodiversity integration requires improved evidence and action, delivered via a socio-ecological process operating at landscape scales and backed by supportive regulations and finance. Conceiving restoration and biodiversity conservation as synergistic, mutually reinforcing partners is critical for humanity's bids to tackle the global crises of climate change, land degradation and biodiversity extinction.
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You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1016/j.cub.2024.02.032&type=result"></script>'); --> </script>
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You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1016/j.cub.2024.02.032&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Article 2024Publisher:Oxford University Press (OUP) Authors: Cody P Cretini; Katherine A Galloway;doi: 10.1093/icb/icae013
pmid: 38702853
Synopsis Climate change can directly and indirectly affect species distribution. Warming may allow for invasive species, such as apple snails, to migrate to higher latitudes where temperatures are more conducive to their survival and invasion success. Higher temperatures and lower pH ranges have been previously documented to affect the form and function of calcium carbonate shells, which serve many functions, including protection from predators and thermoregulation. This study aimed to quantify differences in the morphology and mechanical properties of invasive apple snail, Pomacea maculata, shells after altering temperature and pH. We mechanically tested shells among three five-week treatments: control, higher temperature, and lower pH. Ultimate Strength increased in shells that were exposed to higher temperatures, but Young’s Modulus and Peak Load did not differ among control, temperature, and pH treatments. Apple snails in higher temperature tanks increased their shell length over the five-week trials. Although snail morphometrics did not differ between sexes, male shells exhibited a higher Peak Load, Young’s Modulus, and Ultimate Strength compared to female shells. Our findings are consistent with previous gastropod studies, in that a lower pH is associated with a decrease in shell size, and higher temperatures yield larger snail shells with a higher ultimate strength. Peak Load did not significantly differ among treatments, which suggests that the cross-sectional area is relatively important when considering this species mechanical performance today and in future climates. Due to the intense nutritional and calcium demands of egg production, female snails may be more susceptible to weakened shells due to low pH environments caused by climate change.
Integrative and Comp... arrow_drop_down Integrative and Comparative BiologyArticle . 2024 . Peer-reviewedLicense: OUP Standard Publication ReuseData sources: Crossrefadd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
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You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1093/icb/icae013&type=result"></script>'); --> </script>
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more_vert Integrative and Comp... arrow_drop_down Integrative and Comparative BiologyArticle . 2024 . Peer-reviewedLicense: OUP Standard Publication ReuseData sources: Crossrefadd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
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For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Thesis 2024 United KingdomPublisher:Apollo - University of Cambridge Repository Authors: Silseth, Tobias;doi: 10.17863/cam.109687
From the British debate on the depletion of coal in 1865 to the First World Power Conference held in London in 1924, scientists, engineers, industrialists, and politicians produced new interpretations of the past, present, and future in terms of the mobilisation of energy resources. This thesis identifies an emerging ‘energy developmentalism’, which called for maximising energy use to maintain or improve a nation’s place in international competition. Energy developmentalism was not a marginal worldview confined to ‘energeticists’, but a coherent set of claims, measurements, and arguments that informed energy governance on an international scale. Rather than focusing on a single resource, energy developmentalism applied a unified schema to all energy sources, including those like solar and tidal energy that were still mostly theoretical. Drawing on sources from across Europe, while staying grounded in political changes in Britain and France, makes it possible to understand how a general formula for transforming raw materials with maximum efficiency was applied differently depending on specific political contexts. This period saw the articulation of problems like the depletion of resources, the difference between renewable and nonrenewable energy, the intermittency of renewables, the overreliance on a single source of energy, and the centrality of energy to modern economies – problems that are often associated with later periods. Scientific measurements of efficiency, horsepower, and kilowatts became operators in political debates centred on questions of national standing and progress. Even as oil became increasingly important in the world economy, the delegates at the First World Power Conference transformed a vision of a renewable energy future into one of a general expansion of energy consumption as the basis of progress. In so doing, they downplayed the continued importance of fossil fuels and equated ‘conservation’ with the fullest possible use of all energy sources, renewable or not.
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You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
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more_vert add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.17863/cam.109687&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Other literature type , Project deliverable 2021Publisher:Zenodo Masera, Kemal; Tannous, Hadi; Tassou, Savvas; Stojceska, Valentina; Kew, Peter; Reay, David;This report aims to provide concept designs to integrate the SunDial/TES system with the MANDREKAS and ArcelorMittal end-users. These concept designs are important to understand how the ASTEP system will be integrated with the end-users including the tailored designs for the specific needs of each end-user. The end-user specific ASTEP system is introduced and existing heating/cooling systems are explained in schematic diagrams. A small number of integration options are presented in detailed schematics. Possible integration components such as steam generator for MANDREKAS and pipe heater for ArcelorMittal are investigated at the component level. In addition, key fluid properties at the critical locations such as inlet and outlet of the components are summarised.
add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
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visibility 49visibility views 49 download downloads 2 Powered bymore_vert add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.5281/zenodo.5772202&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Article 2023 Czech RepublicPublisher:Elsevier BV Jiří Laurin; David Uličný; Dave Waltham; Petr Toman; Michael Warsitzka; Bradley B. Sageman;Climate-controlled changes in eustatic sea level (ESL) are linked to transfers of water between ocean and land, thus offering a rare insight into the past hydrological cycle. In this study, we examine the timing and phase of Milankovitch-scale ESL cycles in the peak Cretaceous greenhouse, the early Turonian (-93-94 million years, Myr, ago). A high-resolution astronomical framework established for the Bohemian Cretaceous Basin (central Europe) suggests a -400-kyr pace and a distinct asymmetry of interpreted ESL cycles. The rising limbs of ESL change constitute only 20-30 % of the cycle, and are encased entirely within the falling phase of the 405-kyr eccentricity. The intervening ESL falls (<= 6 m in magnitude) are more protracted, starting within 70 kyr prior to the eccentricity minima and culminating -60 kyr after the 405-kyr eccentricity maxima. Despite similarities to the sawtooth shape of -100-kyr glacioeustatic oscillations of the Late Pleistocene, the time scales and phasing are unparalleled in the Pleistocene icehouse. A similar, 405-kyr pace is found in ice-volume variations of the early Miocene, but the timing of glacioeustatic change relative to eccentricity forcing is incompatible with the phase of greenhouse sea-level oscillations. The phasing points to major differences in the geographic location and insolation sensitivity of the key hydrological reservoirs under icehouse and greenhouse regimes. The inferred structure of greenhouse eustasy points to low- or middle-latitude water storage, likely aquifers, that charge (expand) with rising seasonality variations and discharge (contract) with declining seasonality amplitudes on the 405-kyr scale. The net volume of water transferred on these time scales is within 2.2 x 106 km3, equivalent to <= 10 % of the present-day storage in the uppermost 2 km of continental crust. Potential additive interference with steric eustasy, proportionally relevant during greenhouse regimes, could reduce the volumes required for continental storage.
Repository of the Cz... arrow_drop_down Repository of the Czech Academy of SciencesArticle . 2023Data sources: Repository of the Czech Academy of SciencesEarth and Planetary Science LettersArticle . 2023 . Peer-reviewedLicense: Elsevier TDMData sources: Crossrefadd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1016/j.epsl.2023.118421&type=result"></script>'); --> </script>
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more_vert Repository of the Cz... arrow_drop_down Repository of the Czech Academy of SciencesArticle . 2023Data sources: Repository of the Czech Academy of SciencesEarth and Planetary Science LettersArticle . 2023 . Peer-reviewedLicense: Elsevier TDMData sources: Crossrefadd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1016/j.epsl.2023.118421&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Doctoral thesis 2024 SwitzerlandPublisher:Lausanne, EPFL Authors: Cattry, Alexandre Dominique M.;Photo-electrochemical (PEC) devices allow for converting solar energy into chemical energy and for the production of energetically dense solar fuels. Light absorption, charge separation and transport, electrochemical reactions, and ionic transport are required in such devices, all processes happening simultaneously. PEC devices - compared to competing, conventional PV-electrolysis systems - offer the promise of less complexity in design and implementation and more flexibility in their use. Nevertheless, PEC devices' economic and performance competitiveness is not well understood, given their low technology readiness level. No study has considered accurate multi-physical, multi-scale, and multi-dimensional performance models, degradation aspects, and uncertainty in the performance and cost metrics. Addressing some of these unknowns and focusing on the conversion of solar energy into two different solar fuels (H2 from water and CO from CO2), the objective of this thesis is threefold: (i) conduct a system-level techno-economic analysis based on a systematic and physical performance model (including degradation), and address uncertainty via a probabilistic approach (Monte Carlo (MC) method); (ii) based on the insight gained from the techno-economic analysis, identify most promising design and operational principles, substantiated by experimental investigation of an example case to assess practical feasibility; and (iii) develop two intricate multi-dimensional, multi-physical models: one for an innovative PEC device designed to operate with water vapor, and the other for a PEC device utilizing concentrated solar light engaged in the conversion of CO2 to CO. Overall, this thesis provides a combination of experimental demonstration and simulation tools to conduct feasibility studies, predict costs, and provide design guidelines and operational conditions for PEC devices in diverse electrochemical processes. This scope extends the use of PEC devices beyond the traditional liquid water splitting reaction, encompassing applications such as water vapor splitting, energy storage, and CO2 reduction.
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You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
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more_vert add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.5075/epfl-thesis-10076&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Conference object , Other literature type 2021 Russian FederationPublisher:IEEE Authors: Ziuzev, A.; Nakataev, A.; Shelyug, S.; Ippolitov, V.;The paper presents a computer simulation of the operation of three independent electric drives with a periodic load, connected to a common power supply network. Two cases are considered - operation of electric drives in one phase and in different phases. An analysis of their impact on the electrical supply network is carried out, the results are compared with the permissible Russian standards. An analytical optimization method based on the analysis of power graphs of electric drives with periodic load was considered. The article contains an overview of possible methods for regulating the working phase of the mechanism.
Institutional reposi... arrow_drop_down Institutional repository of Russian State Vocational Pedagogical UniversityConference object . 2021https://doi.org/10.1109/iwed52...Conference object . 2021 . Peer-reviewedLicense: IEEE CopyrightData sources: Crossrefadd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1109/iwed52055.2021.9376368&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eu2 citations 2 popularity Top 10% influence Average impulse Average Powered by BIP!
more_vert Institutional reposi... arrow_drop_down Institutional repository of Russian State Vocational Pedagogical UniversityConference object . 2021https://doi.org/10.1109/iwed52...Conference object . 2021 . Peer-reviewedLicense: IEEE CopyrightData sources: Crossrefadd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
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For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Thesis 2021Embargo end date: 15 Jan 2021 United KingdomPublisher:Apollo - University of Cambridge Repository Authors: Rebecca Haboucha;doi: 10.17863/cam.63327
Climate change has been widely recognised as one of the most urgent and growing threats to natural and cultural heritage in the twenty-first century, and the indelible impact of humanity has led to the definition of a new geological epoch, the Anthropocene. Indigenous peoples are disproportionately affected by natural and human-induced changes to the environment. Their vulnerability is exacerbated by centuries of cultural and territorial disenfranchisement within settler-colonial nations. This dissertation aims at understanding Indigenous perceptions of heritage in the face of climate change and its intersection with the impacts of settler- colonialism. It analyses how these on-the-ground perceptions can, in turn, inform heritage organisations and contribute to safeguarding the many facets of tangible and intangible Indigenous heritage for future generations in the Anthropocene. This is accomplished through a comparative, transnational case study of two communities each from the Dehcho First Nations in the Northwest Territories, Canada, and the Aymara and Quechua peoples in northern Chile. I use a multi-method approach consisting of semi-structured interviews, oral histories and participant observation. The data is complemented by environmental and heritage legislation and grey literature at multiple organisational scales for both case studies. Three lines of enquiry are explored through an applied comparative thematic analysis: i) the perceptions of climate change and associated land loss/change among Indigenous groups and how this impacts each group’s notions of challenges to its cultural identity; ii) the intersection of the effects of post- colonialism, ongoing industrial activities and climate change on the intergenerational transmission of ancestral knowledge and notions of place attachment; and iii) how international, national and regional political and sociocultural rhetoric on environmental and heritage conservation affect local, grassroots considerations for safeguarding heritage. The similarities and contrasts of the Dehcho First Nations, Aymara and Quechua experiences of climate change across the North-South divide are related from the grassroots to arrive at redefining heritage practices in the Anthropocene. The results demonstrate that decolonising heritage is not only necessary, but that this decolonisation depends on building and actively engaging in intercultural empathy through the global threat of climate change. In order to understand how Indigenous practices, places, and items are valorised—attributed value—as heritage in the face of climate change, one must empathise with the cultural loss that exists in the temporal and cognitive spaces between Indigenous individuals’ moments of nostalgic reference and today.
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You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
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For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Doctoral thesis 2021 SwitzerlandPublisher:Lausanne, EPFL Authors: Alanazi, Anwar Qasem M;The semiconducting hybrid-organic inorganic halide perovskites have excellent optical and electronic properties that attract the interest of scientists and researchers. Perovskite solar cells have seen the most rising-rate in the chart of solar cell efficiency from 3 to over 25% in less than ten years. In the last three years, most researchers have been focusing on the α-FAPbI3-based perovskite solar cells due to having a lower bandgap (1.45 eV) which is closer to the Shockley-Queisser optimum (1.1- 1.4eV) to gain high efficiency. A distinctive feature of FAPbI3 is that it is more thermally stable compared to MAPbI3. However, the α-FAPbI3 perovskite is not stable at room temperature as it converts to the undesirable Ύ-phase. The 2D- Ruddlesden-Popper-phase-doped 3D FAPbI3 enhancing the stability of the structure, albeit the bandgap is increased rendering a less optimal bandgap. The main achievement of this thesis is discovering that the doping of FAPbI3 with large alkyl ammonium moieties enhances efficiency and stability while maintaining the bandgap of pure α-FAPbI3 perovskite phase. I describe the resulting composition by the formula (A)xFAPbI3, where A represents the large alkyl ammonium iodide species. I study the stabilization of α-FAPbI3 via doping with 5-amino valeric acid hydroiodide (AVAI). By using solid-state NMR, we demonstrate the atomic-level interaction between this molecular modulator and the perovskite lattice and propose a structural model of the stabilized three-dimensional structure, further aided by density functional theory (DFT) calculations. We find the presence of AVAI produces highly crystalline films with large, micrometer-sized grains and enhanced charge-carrier lifetimes, as probed by transient absorption spectroscopy. Optical measurements confirm that there is no effect on the bandgap of FAPbI3 after doping. The devices based on (AVAI)0.25FAPbI3 exhibit superior operational stability in comparison with neat FAPbI3 while achieving power conversion efficiency of 19%. A similar approach based on benzylammonium iodide (BzI) has been used. The structural and optical characterization of films based on (BzI)xFAPbI3 composition demonstrate that there is no 2D phase forming under these conditions. Moreover, solid-state NMR results show BzI interacting on the atomic level with α-FAPbI3 by binding to the 3D perovskite through hydrogen bonding interaction and stabilizing it against the detrimental α-to-Ύ phase transition. Perovskite solar cells based on the (BzI)0.25FAPbI3composition achieve power conversion efficiencies exceeding 20%, which is accompanied by enhanced shelf-life and operational stability, maintaining 80% of the performance after one year at ambient conditions. Finally, films based on (BzI)0.25FAPbI3 compositions are further investigated upon aging under the ambient conditions, as they show an unexpected transition from black to red color without transition to expected yellow Ύ phase, unlike the reference FAPbI3. I perform different measurements to investigate the nature of this red phase as a function of annealing temperature compare these properties to the corresponding Ruddlesden-Popper phase (Bz2FAn-1PbnI3n+1). The red phase was found to be a mixture of a 2D phase (n = 2) Bz2FAPb2I7 and Ύ-FAPbI3, which acts as a barrier to the α-to-Ύ phase transition.
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You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.5075/epfl-thesis-8807&type=result"></script>'); --> </script>
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You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
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Research data keyboard_double_arrow_right Dataset 2022Publisher:Zenodo Funded by:UKRI | Fashion Fictions: imagini...UKRI| Fashion Fictions: imagining sustainable fashion worldsAuthors: Twigger Holroyd, Amy;This dataset was generated via a focused piece of research conducted by Dr Matilda Aspinall and Dr Amy Twigger Holroyd which investigated the experiences of students and staff involved in Fashion Fictions projects in 2022 at two institutions: LASALLE College of the Arts in Singapore and Nottingham Trent University. This focused research was situated within the broader Fashion Fictions project. Fashion Fictions, founded by Amy Twigger Holroyd in 2020, brings people together to generate, experience and reflect on engaging fictional visions of alternative fashion cultures and systems. Through these activities, we gain new perspectives on challenges, possibilities and pathways for change in the real world. The project is structured in three stages. Stage 1 prompts contributors to create brief written outlines of fictional fashion cultures and systems, known as Worlds; at Stage 2, participants put flesh on these outlines and create visual or material prototypes to represent their cultures, known as Explorations; at Stage 3, they performatively enact practices or events from the fictional worlds. To find out more about Fashion Fictions, visit the project website. To see other data linked to the project, visit the Fashion Fictions Zenodo community. -------------------------------- In both institutions, Fashion Fictions was initially introduced to the curriculum in the 2020/21 academic year; the activities discussed here took place in the following year, with a second cohort of students. At NTU, first-year undergraduate students from BA (Hons) courses in Fashion Design, Textile Design and Fashion Knitwear Design & Knitted Textiles undertook a short Stage 2 Fashion Fictions project. Spanning three two-hour workshops, the project was part of a Future Thinking toolkit within a module that aims to develop students’ intellectual curiosity and appreciation of the future as something that can be shaped and questioned. Working in small cross-course groups, students were given a specified Stage 1 fiction and asked to create a visual or material prototype to represent everyday life in that world, presented via a selection of images and a short explanatory text. At LASALLE, Fashion Fictions was set up as a major project extending across a 14-week semester for second-year students on two BA (Hons) programmes: Fashion Media and Industries and Fashion Design and Textiles. Also working in cross-course collaborative groups, the students first created their own Stage 1 world and then progressed to create a collection of Stage 2 prototypes in the form of garments and related media such as photographs and films, accompanied by an extensive body of supporting work. -------------------------------- in April and May 2022 we conducted semi-structured interviews with tutors involved in the projects – Lorraine Warde (Principal Lecturer in Fashion Design) at NTU and Martin Bonney and Kathryn Shannon Sim Yen Ping (Lecturers in Fashion, interviewed together) at LASALLE – and with three student groups, selected by the tutors, from each institution. The interview schedules for students and tutors each comprised four reflective questions, designed to gain an insight into the students’ experiences and the tutors’ observations. Each recorded interview lasted between twenty and sixty minutes. -------------------------------- The dataset is organised in nine folders: 1 Project context Project website About page from February 2022 (explaining the wider project at the time of this research). Project website Education projects page from January 2022 (giving context to the education projects taking place at the time of this research). 2 Activity guidance Project website Stage 1 (World) online guide from January 2022 (as available for use by LASALLE students). NTU virtual workspace Stage 2 (Exploration) guidance (as used by NTU students and providing an indication of the type of guidance that would have been offered to LASALLE students for their Stage 2 work - although their project was much longer in duration). 3 Interview documentation Information sheet and consent form given to research participants. Interview questions for staff and students, shared with all participants in advance. 4 LASALLE staff interview Transcript of interview with Martin Bonney and Kathryn Shannon Sim Yen Ping (Lecturers in Fashion). 5 LASALLE student interviews Transcripts of interviews with three student groups, each identified by the number/letter of the Stage 1 World and Stage 2 Exploration they created (as listed on the project website Worlds and Explorations pages). 6 LASALLE student work Project work (Stage 1 Worlds and Stage 2 Explorations) created by the three student groups interviewed, as displayed on the project website. One group (World 154) did not submit their Exploration for the website. 7 NTU staff interview Transcript of interview with Lorraine Warde (Principal Lecturer in Fashion Design). 8 NTU student interviews Transcripts of interviews with three student groups, each identified by the number/letter of the Stage 2 Exploration they created (as listed on the project website Explorations page). 9 NTU student work Project work (Stage 2 Explorations) created by the three student groups interviewed. Two groups' work is as displayed on the project website. One group (World 95, Exploration X) did not submit their Exploration for the website and so their internal presentation has been included instead.
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You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
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For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Article 2024 United KingdomPublisher:Elsevier BV Authors: David P, Edwards; Gianluca R, Cerullo;pmid: 38714168
The global restoration agenda can help solve the biodiversity extinction crisis by regenerating biodiversity-rich ecosystems, maximising conservation benefits using natural regeneration. Yet, conservation is rarely the core objective of restoration, and biodiversity is often neglected in restoration projects targeted towards carbon sequestration or enhancing ecosystem services for improved local livelihoods. Here, we synthesise evidence to show that promoting biodiversity in restoration planning and delivery is integral to delivering other long-term restoration aims, such as carbon sequestration, timber production, enhanced local farm yields, reduced soil erosion, recovered hydrological services and improved human health. For each of these restoration goals, biodiversity must be a keystone objective to the entire process. Biodiversity integration requires improved evidence and action, delivered via a socio-ecological process operating at landscape scales and backed by supportive regulations and finance. Conceiving restoration and biodiversity conservation as synergistic, mutually reinforcing partners is critical for humanity's bids to tackle the global crises of climate change, land degradation and biodiversity extinction.
add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
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For further information contact us at helpdesk@openaire.euAccess RoutesGreen 0 citations 0 popularity Average influence Average impulse Average Powered by BIP!
more_vert add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1016/j.cub.2024.02.032&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Article 2024Publisher:Oxford University Press (OUP) Authors: Cody P Cretini; Katherine A Galloway;doi: 10.1093/icb/icae013
pmid: 38702853
Synopsis Climate change can directly and indirectly affect species distribution. Warming may allow for invasive species, such as apple snails, to migrate to higher latitudes where temperatures are more conducive to their survival and invasion success. Higher temperatures and lower pH ranges have been previously documented to affect the form and function of calcium carbonate shells, which serve many functions, including protection from predators and thermoregulation. This study aimed to quantify differences in the morphology and mechanical properties of invasive apple snail, Pomacea maculata, shells after altering temperature and pH. We mechanically tested shells among three five-week treatments: control, higher temperature, and lower pH. Ultimate Strength increased in shells that were exposed to higher temperatures, but Young’s Modulus and Peak Load did not differ among control, temperature, and pH treatments. Apple snails in higher temperature tanks increased their shell length over the five-week trials. Although snail morphometrics did not differ between sexes, male shells exhibited a higher Peak Load, Young’s Modulus, and Ultimate Strength compared to female shells. Our findings are consistent with previous gastropod studies, in that a lower pH is associated with a decrease in shell size, and higher temperatures yield larger snail shells with a higher ultimate strength. Peak Load did not significantly differ among treatments, which suggests that the cross-sectional area is relatively important when considering this species mechanical performance today and in future climates. Due to the intense nutritional and calcium demands of egg production, female snails may be more susceptible to weakened shells due to low pH environments caused by climate change.
Integrative and Comp... arrow_drop_down Integrative and Comparative BiologyArticle . 2024 . Peer-reviewedLicense: OUP Standard Publication ReuseData sources: Crossrefadd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
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more_vert Integrative and Comp... arrow_drop_down Integrative and Comparative BiologyArticle . 2024 . Peer-reviewedLicense: OUP Standard Publication ReuseData sources: Crossrefadd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1093/icb/icae013&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Thesis 2024 United KingdomPublisher:Apollo - University of Cambridge Repository Authors: Silseth, Tobias;doi: 10.17863/cam.109687
From the British debate on the depletion of coal in 1865 to the First World Power Conference held in London in 1924, scientists, engineers, industrialists, and politicians produced new interpretations of the past, present, and future in terms of the mobilisation of energy resources. This thesis identifies an emerging ‘energy developmentalism’, which called for maximising energy use to maintain or improve a nation’s place in international competition. Energy developmentalism was not a marginal worldview confined to ‘energeticists’, but a coherent set of claims, measurements, and arguments that informed energy governance on an international scale. Rather than focusing on a single resource, energy developmentalism applied a unified schema to all energy sources, including those like solar and tidal energy that were still mostly theoretical. Drawing on sources from across Europe, while staying grounded in political changes in Britain and France, makes it possible to understand how a general formula for transforming raw materials with maximum efficiency was applied differently depending on specific political contexts. This period saw the articulation of problems like the depletion of resources, the difference between renewable and nonrenewable energy, the intermittency of renewables, the overreliance on a single source of energy, and the centrality of energy to modern economies – problems that are often associated with later periods. Scientific measurements of efficiency, horsepower, and kilowatts became operators in political debates centred on questions of national standing and progress. Even as oil became increasingly important in the world economy, the delegates at the First World Power Conference transformed a vision of a renewable energy future into one of a general expansion of energy consumption as the basis of progress. In so doing, they downplayed the continued importance of fossil fuels and equated ‘conservation’ with the fullest possible use of all energy sources, renewable or not.
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You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
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more_vert add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.17863/cam.109687&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Other literature type , Project deliverable 2021Publisher:Zenodo Masera, Kemal; Tannous, Hadi; Tassou, Savvas; Stojceska, Valentina; Kew, Peter; Reay, David;This report aims to provide concept designs to integrate the SunDial/TES system with the MANDREKAS and ArcelorMittal end-users. These concept designs are important to understand how the ASTEP system will be integrated with the end-users including the tailored designs for the specific needs of each end-user. The end-user specific ASTEP system is introduced and existing heating/cooling systems are explained in schematic diagrams. A small number of integration options are presented in detailed schematics. Possible integration components such as steam generator for MANDREKAS and pipe heater for ArcelorMittal are investigated at the component level. In addition, key fluid properties at the critical locations such as inlet and outlet of the components are summarised.
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You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
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visibility 49visibility views 49 download downloads 2 Powered bymore_vert add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.5281/zenodo.5772202&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Article 2023 Czech RepublicPublisher:Elsevier BV Jiří Laurin; David Uličný; Dave Waltham; Petr Toman; Michael Warsitzka; Bradley B. Sageman;Climate-controlled changes in eustatic sea level (ESL) are linked to transfers of water between ocean and land, thus offering a rare insight into the past hydrological cycle. In this study, we examine the timing and phase of Milankovitch-scale ESL cycles in the peak Cretaceous greenhouse, the early Turonian (-93-94 million years, Myr, ago). A high-resolution astronomical framework established for the Bohemian Cretaceous Basin (central Europe) suggests a -400-kyr pace and a distinct asymmetry of interpreted ESL cycles. The rising limbs of ESL change constitute only 20-30 % of the cycle, and are encased entirely within the falling phase of the 405-kyr eccentricity. The intervening ESL falls (<= 6 m in magnitude) are more protracted, starting within 70 kyr prior to the eccentricity minima and culminating -60 kyr after the 405-kyr eccentricity maxima. Despite similarities to the sawtooth shape of -100-kyr glacioeustatic oscillations of the Late Pleistocene, the time scales and phasing are unparalleled in the Pleistocene icehouse. A similar, 405-kyr pace is found in ice-volume variations of the early Miocene, but the timing of glacioeustatic change relative to eccentricity forcing is incompatible with the phase of greenhouse sea-level oscillations. The phasing points to major differences in the geographic location and insolation sensitivity of the key hydrological reservoirs under icehouse and greenhouse regimes. The inferred structure of greenhouse eustasy points to low- or middle-latitude water storage, likely aquifers, that charge (expand) with rising seasonality variations and discharge (contract) with declining seasonality amplitudes on the 405-kyr scale. The net volume of water transferred on these time scales is within 2.2 x 106 km3, equivalent to <= 10 % of the present-day storage in the uppermost 2 km of continental crust. Potential additive interference with steric eustasy, proportionally relevant during greenhouse regimes, could reduce the volumes required for continental storage.
Repository of the Cz... arrow_drop_down Repository of the Czech Academy of SciencesArticle . 2023Data sources: Repository of the Czech Academy of SciencesEarth and Planetary Science LettersArticle . 2023 . Peer-reviewedLicense: Elsevier TDMData sources: Crossrefadd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
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more_vert Repository of the Cz... arrow_drop_down Repository of the Czech Academy of SciencesArticle . 2023Data sources: Repository of the Czech Academy of SciencesEarth and Planetary Science LettersArticle . 2023 . Peer-reviewedLicense: Elsevier TDMData sources: Crossrefadd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1016/j.epsl.2023.118421&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Doctoral thesis 2024 SwitzerlandPublisher:Lausanne, EPFL Authors: Cattry, Alexandre Dominique M.;Photo-electrochemical (PEC) devices allow for converting solar energy into chemical energy and for the production of energetically dense solar fuels. Light absorption, charge separation and transport, electrochemical reactions, and ionic transport are required in such devices, all processes happening simultaneously. PEC devices - compared to competing, conventional PV-electrolysis systems - offer the promise of less complexity in design and implementation and more flexibility in their use. Nevertheless, PEC devices' economic and performance competitiveness is not well understood, given their low technology readiness level. No study has considered accurate multi-physical, multi-scale, and multi-dimensional performance models, degradation aspects, and uncertainty in the performance and cost metrics. Addressing some of these unknowns and focusing on the conversion of solar energy into two different solar fuels (H2 from water and CO from CO2), the objective of this thesis is threefold: (i) conduct a system-level techno-economic analysis based on a systematic and physical performance model (including degradation), and address uncertainty via a probabilistic approach (Monte Carlo (MC) method); (ii) based on the insight gained from the techno-economic analysis, identify most promising design and operational principles, substantiated by experimental investigation of an example case to assess practical feasibility; and (iii) develop two intricate multi-dimensional, multi-physical models: one for an innovative PEC device designed to operate with water vapor, and the other for a PEC device utilizing concentrated solar light engaged in the conversion of CO2 to CO. Overall, this thesis provides a combination of experimental demonstration and simulation tools to conduct feasibility studies, predict costs, and provide design guidelines and operational conditions for PEC devices in diverse electrochemical processes. This scope extends the use of PEC devices beyond the traditional liquid water splitting reaction, encompassing applications such as water vapor splitting, energy storage, and CO2 reduction.
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You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.5075/epfl-thesis-10076&type=result"></script>'); --> </script>
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more_vert add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.5075/epfl-thesis-10076&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Conference object , Other literature type 2021 Russian FederationPublisher:IEEE Authors: Ziuzev, A.; Nakataev, A.; Shelyug, S.; Ippolitov, V.;The paper presents a computer simulation of the operation of three independent electric drives with a periodic load, connected to a common power supply network. Two cases are considered - operation of electric drives in one phase and in different phases. An analysis of their impact on the electrical supply network is carried out, the results are compared with the permissible Russian standards. An analytical optimization method based on the analysis of power graphs of electric drives with periodic load was considered. The article contains an overview of possible methods for regulating the working phase of the mechanism.
Institutional reposi... arrow_drop_down Institutional repository of Russian State Vocational Pedagogical UniversityConference object . 2021https://doi.org/10.1109/iwed52...Conference object . 2021 . Peer-reviewedLicense: IEEE CopyrightData sources: Crossrefadd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
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For further information contact us at helpdesk@openaire.eu2 citations 2 popularity Top 10% influence Average impulse Average Powered by BIP!
more_vert Institutional reposi... arrow_drop_down Institutional repository of Russian State Vocational Pedagogical UniversityConference object . 2021https://doi.org/10.1109/iwed52...Conference object . 2021 . Peer-reviewedLicense: IEEE CopyrightData sources: Crossrefadd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
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For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Thesis 2021Embargo end date: 15 Jan 2021 United KingdomPublisher:Apollo - University of Cambridge Repository Authors: Rebecca Haboucha;doi: 10.17863/cam.63327
Climate change has been widely recognised as one of the most urgent and growing threats to natural and cultural heritage in the twenty-first century, and the indelible impact of humanity has led to the definition of a new geological epoch, the Anthropocene. Indigenous peoples are disproportionately affected by natural and human-induced changes to the environment. Their vulnerability is exacerbated by centuries of cultural and territorial disenfranchisement within settler-colonial nations. This dissertation aims at understanding Indigenous perceptions of heritage in the face of climate change and its intersection with the impacts of settler- colonialism. It analyses how these on-the-ground perceptions can, in turn, inform heritage organisations and contribute to safeguarding the many facets of tangible and intangible Indigenous heritage for future generations in the Anthropocene. This is accomplished through a comparative, transnational case study of two communities each from the Dehcho First Nations in the Northwest Territories, Canada, and the Aymara and Quechua peoples in northern Chile. I use a multi-method approach consisting of semi-structured interviews, oral histories and participant observation. The data is complemented by environmental and heritage legislation and grey literature at multiple organisational scales for both case studies. Three lines of enquiry are explored through an applied comparative thematic analysis: i) the perceptions of climate change and associated land loss/change among Indigenous groups and how this impacts each group’s notions of challenges to its cultural identity; ii) the intersection of the effects of post- colonialism, ongoing industrial activities and climate change on the intergenerational transmission of ancestral knowledge and notions of place attachment; and iii) how international, national and regional political and sociocultural rhetoric on environmental and heritage conservation affect local, grassroots considerations for safeguarding heritage. The similarities and contrasts of the Dehcho First Nations, Aymara and Quechua experiences of climate change across the North-South divide are related from the grassroots to arrive at redefining heritage practices in the Anthropocene. The results demonstrate that decolonising heritage is not only necessary, but that this decolonisation depends on building and actively engaging in intercultural empathy through the global threat of climate change. In order to understand how Indigenous practices, places, and items are valorised—attributed value—as heritage in the face of climate change, one must empathise with the cultural loss that exists in the temporal and cognitive spaces between Indigenous individuals’ moments of nostalgic reference and today.
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You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
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For further information contact us at helpdesk@openaire.euAccess RoutesGreen 0 citations 0 popularity Average influence Average impulse Average Powered by BIP!
more_vert add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
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For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Doctoral thesis 2021 SwitzerlandPublisher:Lausanne, EPFL Authors: Alanazi, Anwar Qasem M;The semiconducting hybrid-organic inorganic halide perovskites have excellent optical and electronic properties that attract the interest of scientists and researchers. Perovskite solar cells have seen the most rising-rate in the chart of solar cell efficiency from 3 to over 25% in less than ten years. In the last three years, most researchers have been focusing on the α-FAPbI3-based perovskite solar cells due to having a lower bandgap (1.45 eV) which is closer to the Shockley-Queisser optimum (1.1- 1.4eV) to gain high efficiency. A distinctive feature of FAPbI3 is that it is more thermally stable compared to MAPbI3. However, the α-FAPbI3 perovskite is not stable at room temperature as it converts to the undesirable Ύ-phase. The 2D- Ruddlesden-Popper-phase-doped 3D FAPbI3 enhancing the stability of the structure, albeit the bandgap is increased rendering a less optimal bandgap. The main achievement of this thesis is discovering that the doping of FAPbI3 with large alkyl ammonium moieties enhances efficiency and stability while maintaining the bandgap of pure α-FAPbI3 perovskite phase. I describe the resulting composition by the formula (A)xFAPbI3, where A represents the large alkyl ammonium iodide species. I study the stabilization of α-FAPbI3 via doping with 5-amino valeric acid hydroiodide (AVAI). By using solid-state NMR, we demonstrate the atomic-level interaction between this molecular modulator and the perovskite lattice and propose a structural model of the stabilized three-dimensional structure, further aided by density functional theory (DFT) calculations. We find the presence of AVAI produces highly crystalline films with large, micrometer-sized grains and enhanced charge-carrier lifetimes, as probed by transient absorption spectroscopy. Optical measurements confirm that there is no effect on the bandgap of FAPbI3 after doping. The devices based on (AVAI)0.25FAPbI3 exhibit superior operational stability in comparison with neat FAPbI3 while achieving power conversion efficiency of 19%. A similar approach based on benzylammonium iodide (BzI) has been used. The structural and optical characterization of films based on (BzI)xFAPbI3 composition demonstrate that there is no 2D phase forming under these conditions. Moreover, solid-state NMR results show BzI interacting on the atomic level with α-FAPbI3 by binding to the 3D perovskite through hydrogen bonding interaction and stabilizing it against the detrimental α-to-Ύ phase transition. Perovskite solar cells based on the (BzI)0.25FAPbI3composition achieve power conversion efficiencies exceeding 20%, which is accompanied by enhanced shelf-life and operational stability, maintaining 80% of the performance after one year at ambient conditions. Finally, films based on (BzI)0.25FAPbI3 compositions are further investigated upon aging under the ambient conditions, as they show an unexpected transition from black to red color without transition to expected yellow Ύ phase, unlike the reference FAPbI3. I perform different measurements to investigate the nature of this red phase as a function of annealing temperature compare these properties to the corresponding Ruddlesden-Popper phase (Bz2FAn-1PbnI3n+1). The red phase was found to be a mixture of a 2D phase (n = 2) Bz2FAPb2I7 and Ύ-FAPbI3, which acts as a barrier to the α-to-Ύ phase transition.
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For further information contact us at helpdesk@openaire.eu0 citations 0 popularity Average influence Average impulse Average Powered by BIP!
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