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Among various bioreactors examined in anaerobic digestion and dark fermentation, UASB bioreactor has shown to be a promising alternative. However, mass transfer resistance and biomass washout have been the issues that reported as draw backs of the granular system in the literature. Another problem associated with such a system is its long start-up period as a result of biomass washout and long microbial granulation stage. In this paper, the results obtained from an UASFF bioreactor in methane (AD process) and hydrogen (DF process) production from POME, are presented to assess mass transfer of substrate into the granules and also study the role of internal packing used in the middle part of reactor in the process stability. The value of effectiveness factor, η, for AD and DF processes were calculated to be 0.96 and 0.94, respectively, indicating that there was no mass transfer resistance due to internal and/or external factors. The results showed that the packing material could retain biomass in the reactor and had outstanding contribution in the granulation enhancement. Its role as a supplementing treatment stage was more significant at low HRTs and up-flow velocities.

As smart cities become a global topic, interest in smart mobility, the core of smart cities, is also growing. The technology that comes closest to general users is “autonomous driving”. In particular, the successful market entry and establishment of some private companies proved that “autonomous driving” is not technology of the future but imminent reality. However, safety in autonomous vehicles that rely on sensors instead of the driver’s five senses has been the focus of attention from the beginning and continues to be so. In this study, we attempted to counter this interest. Based on the actual data of thirty traffic accidents, assuming the AEBS (Autonomous Emergency Braking System) was installed to assist the driver in safe driving, it was reinterpreted through simulation to see what changes occurred in the accident. In the computer program, PC-Crash, the results were first analyzed through simulation using Euro NCAP (New Car Assessment Program)’s AEBS test standards. Subsequently, the other variables in the AEBS were controlled and the accident was reinterpreted by changing only the angle of the radar detection sensor. As a result, it was confirmed that a total of 27 accidents out of thirty accidents could have been prevented with the AEBS. In addition, it proved that the crash avoidance rate of vehicles gradually increased as the radar angle increased.

The idea of shipping container house is no longer a revolutionized to western country but in Asia country particularly in Malaysia it is relatively new. The idea of container house is relatively new and there is no clear sign of how far does Malaysian citizen can accept this idea. There is no indicator of what are the expectations from Malaysian citizen about the container house. This research serves as basic references for both government and private sector to the future property industry development of shipping container house as well as shipping container non-residential building in Malaysia to pursue Malaysia’s unity, economic and national integration. The purpose of this study is to test the feasibility of using ISO shipping container to build low cost house. Four set of questionnaires are prepared to assess the opinion of respondents about the acceptance of shipping container house. The result obtained is that the acceptance level of the idea to live inside a container house is only 45% but the acceptance level of using shipping container as means of storage, office, and business development is highly acceptable by Malaysian citizen.

AbstractThis work reports the synthesis, characterization, photophysical, and photovoltaic properties of five new thieno[3,2‐b][1]benzothiophene isoindigo (TBTI)‐containing low bandgap donor–acceptor conjugated polymers with a series of comonomers and different side chains. When TBTI is combined with different electron‐rich moieties, even small structural variations can have significant impact on thin film morphology of the polymer:phenyl C70 butyric acid methyl ester (PCBM) blends. More importantly, high‐resolution electron energy loss spectroscopy is used to investigate the phase‐separated bulk heterojunction domains, which can be accurately and precisely resolved, enabling an enhanced correlation between polymer chemical structure, photovoltaic device performance, and morphology.

Abstract The variation of properties with temperature have many practical applications in the area of chemical engineering and metallurgy, in the process of extrusion, the materials moving between a feed roll and on carrier belt. Here our intention is to explore the consequences of temperature dependent viscosity and variable thermal conductivity on flow of nanoliquid in a rotating system. Fluid between parallel plates is taken. Energy expression incorporates the exponential heat source. This analysis also explores the attributes of modified Arrhenius energy function with chemical reaction. Boundary layer problems have been computed via NDSolve approach. The obtained solutions are sketched for various estimations of embedded variables of interest. Results pointed out that both axial and transverse velocities show decaying behavior for higher rotation parameter. Thermal field boosts up with an enhancement of thermophoretic and space dependent heat source variables. Moreover the rate of mass transport decays through dimensionless activation energy.

LiNi0.9Mn0.1−xAlxO2 (NMA) (x = 0.01, 0.03, 0.05) cathodes were synthesized via the co-precipitation method and continued with the calcination process in a tube furnace at 750 °C under flowing oxygen gas for 12 h. X-ray diffraction (XRD) revealed a well-formed and high-purity phase with a hexagonal structure. LiNi0.9Mn0.07Al0.03O2 (NMA 973) had the best electrochemical performance with the lowest redox peak separation, the smallest charge transfer resistance (71.58 Ω cm−2), the highest initial specific discharge capacity of 172 mAh g−1 at 0.1C, and a capacity retention of 98% after 100 cycles. Under high current density at 1 C, NMA 973 had excellent specific discharge capacity compared to the other samples. The optimal content of Mn and Al elements is a crucial factor to obtain the best electrochemical performance of NMA. Therefore, NMA 973 is a promising candidate as a cathode for high-energy-density lithium-ion batteries.

Heat energy storage systems were fabricated with the impregnation method using MgO and Mg(OH)2 as supporting materials and polyethylene glycol (PEG-6000) as the functional phase. MgO and Mg(OH)2 were synthesized from the salt Mg(NO3)·6H2O by performing hydrothermal reactions with various precipitating agents. The precipitating agents were NaOH, KOH, NH3, NH3 with pamoic acid (PA), or (NH4)2CO3. The result shows that the selection of the precipitating agent has a significant impact on the crystallite structure, size, and shape of the final products. Of the precipitating agents tested, only NaOH and NH3 with PA produce single-phase Mg(OH)2 as the as-synthesized product. Pore size distribution analyses revealed that the surfaces of the as-synthesized MgO have a slit-like pore structure with a broad-type pore size distribution, whereas the as-synthesized Mg(OH)2 has a mesoporous structure with a narrow pore size distribution. This structure enhances the latent heat of the phase change material (PCM) as well as super cooling mitigation. The PEG/Mg(OH)2 PCM also exhibits reproducible behavior over a large number of thermal cycles. Both MgO and Mg(OH)2 matrices prevent the leakage of liquid PEG during the phase transition in phase change materials (PCMs). However, MgO/PEG has a low impregnation ratio and efficiency, with a low thermal storage capability. This is due to the large pore diameter, which does not allow MgO to retain a larger amount of PEG. The latent heat values of PEG-1000/PEG-6000 blends with MgO and Mg(OH)2 were also determined with a view to extending the application of the PCMs to energy storage over wider temperature ranges.

Structural, optoelectronic, photovoltaic, and supplementary characterization data for “Benzylammonium-Mediated Formamidinium Lead Iodide Perovskite Phase Stabilization for Photovoltaics”, DOI:10.1002/adfm.202101163. Figure_2_XRD.zip: Data described in Figure 2 (XRD patterns) as Origin (.opj) software file. Figure_3_NMR_data.zip: Data described in Figure 3 (NMR spectra) in the file structure of the TopSpin software, which is available from Bruker. Figure_4_spectra.zip: Data described in Figure 4 (UV-vis absorption, PL and IPCE spectra) as Origin (.opj) software files. Figure_5_PV.zip: Data described in Figure 5 (photovoltaic characterization) as Origin (.opj) software files. Figure_6_spectra.zip: Data described in Figure 6 (PLQY and TRPL) as Origin (.opj) and *.csv files. Figure_7_stability.zip: Data described in Figure 7 (stability analysis) as Origin (.opj) software files. Figure_SI.zip: Data described in the Supporting Information Figures S1, S2, S3, S5, and S6 (XRD data, reciprocal space maps, radial profiles of q-maps, UV-vis absorption spectra, PL spectra, and additional photovoltaic characterization) as Origin (.opj), text (.txt), and image (.tiff) files.