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AbstractPreparation of uniform, spherical Li4Ti5O12 with high tap density is significant to achieve a high volumetric energy density in lithium‐ion batteries. Herein, Li4Ti5O12 microspheres with variable tap density and tunable size distribution were synthesized by a newly designed industrial spray‐drying approach. The slurry concentration, sintering time, sintering conditions after spraying, and the effect of lithium/titanium molar ratio on the lithium‐ion (Li+) storage capability were investigated. A narrow particle size distribution of around 10 μm and a high tap density close to 1.4 g cm−3 of the Li4Ti5O12 spheres can be obtained under the optimized conditions. The Li4Ti5O12 spheres can deliver a much higher capacity of 168 mAh g−1 at a rate of 1 C and show a high capacity retention of 97.7 % over 400 cycles. The synthetic conditions are confirmed to be critical for improving the electron conductivity and Li+ diffusivity by adjusting the crystal and spatial structures. As‐prepared high‐performance Li4Ti5O12 is an ideal electrode for lithium‐ion batteries or capacitors; meanwhile, the presented approach is also applicable for preparing other kind of spherical materials.

Abstract This paper uses research-quality, ground measurements of irradiance and temperature that are accurate to ±2% to estimate the electric energy yield of fixed solar modules for utility-scale solar power plants at 18 sites in Saudi Arabia. The calculation is performed for a range of tilt and azimuth angles and the orientation that gives the optimum annual energy yield is determined. A detailed analysis is presented for Riyadh including the impact of non-optimal tilt and azimuth angles on annual energy yield. It is also found that energy yield in March and October are higher than in April and September, due to milder operating temperatures of the modules. A similar optimization of tilt and azimuth is performed each month separately. Adjusting the orientation each month increases energy yield by 4.01% compared to the annual optimum, but requires considerable labour cost. Further analysis shows that an increase in energy yield of 3.63% can be obtained by adjusting the orientation at five selected times during the year, thus significantly reducing the labour requirement. The optimal orientation and corresponding energy yield for all 18 sites is combined with a site suitability analysis taking into account climate, topography and proximity to roads, transmission lines and protected areas. Six sites are selected as having high suitability and high energy yield: Albaha, Arar, Hail, Riyadh, Tabuk and Taif. For these cities the optimal tilt is only slightly higher than the latitude, however the optimum azimuth is from 20° to 53° west of south due to an asymmetrical daily irradiance profile.

Abstract Flow-accelerated corrosion (FAC) is a degradation mechanism that affects carbon steel piping in power plants. The failures and degradation due to FAC have necessitated numerous replacements in many power plants. Several computer codes around the world were developed as part of a systematic program or process to control FAC in power plant utilities. The typical plant model requires the input of the flow parameters, piping configuration and the plant water chemistry. The results on FAC rate are considered the key to proper selection of components for inspection. The lack of information on the effect of the upstream components located in the proximity limited the accuracy of the FAC prediction tools and hence will affect the accuracy in identifying potential inspection locations. In the present study 211 inspection data for 90° carbon steel elbows from several nuclear power plants were used to determine the effect of the proximity between two components on the FAC wear rate. The effect of the velocity as well as the distance between the elbows and the upstream components is discussed in the present analysis. Based on the analyzed trends obtained from the inspection data, significant increase in the wear rate of approximately 70% on average is identified to be due to the proximity.

Global fossil fuel reserves are declining due to differential uses, especially for power generation. Everybody can help to do their bit for the environment by using solar energy. Geographically, Bangladesh is a potential zone for harnessing solar energy. In March 2021, the renewable generation capacity in Bangladesh amounted to 722.592 MW, including 67.6% from solar, 31.84% from hydro, and 0.55% from other energy sources, including wind, biogas, and biomass, where 488.662 MW of power originated from over 6 million installed solar power systems. Concurrently, over 42% of rural people still suffer from a lack of electricity, where solar energy can play a vital role. This paper highlights the present status of various forms of solar energy progress in Bangladesh, such as solar parks, solar rooftops, solar irrigation, solar charging stations, solar home systems, solar-powered telecoms, solar street lights, and solar drinking water, which can be viable alternative sources of energy. This review will help decision-makers and investors realize Bangladesh’s up-to-date solar energy scenario and plan better for the development of a sustainable society.

The heat generation from recent advanced computer chips is increasing rapidly. This creates a challenge in cooling the chips while maintaining their temperatures below the threshold values. Another challenge is that the heat generation in the chip is not uniform where some chip components generate more heat than other components. This would create a large temperature gradient across the chip, resulting in inducing thermal stresses inside the chip that may lead to a high probability to damage the chip. The locations in the chip with heat rates that correspond to high heat fluxes are known as hotspots. This research study focuses on using thermoelectric modules (TEMs) for cooling chip hotspots of different heat fluxes. When a TEM is used for cooling a chip hotspot, it is called a thermoelectric cooler (TEC), which requires electrical power. Additionally, when a TEM is used for converting a chip’s wasted heat to electrical power, it is called a thermoelectric generator (TEG). In this study, the TEMs are used for cooling the hotspots of computer chips, and a TEC is attached to the hotspot to reduce its temperature to an acceptable value. On the other hand, the other cold surfaces of the chip are attached to TEGs for harvesting electrical power from the chip’s wasted heat. Thereafter, this harvested electrical power (HEP) is then used to run the TEC attached to the hotspot. Since no external electrical power is needed for cooling the hotspot to an acceptable temperature, this technique is called a sustainable self-cooling framework (SSCF). In this paper, the operation principles of the SSCF to cool the hotspot, subjected to different operating conditions, are discussed. As well, considerations are given to investigate the effect of the TEM geometrical parameters, such as the P-/N-leg height and spacing between the legs in both operations of the TEC mode and TEG mode on the SSCF performance.

The growing population and increasing urbanization have led to a surge in domestic wastewater generation, posing significant challenges for effective and sustainable treatment. The present study demonstrates a novel and sustainable approach for the onsite treatment of domestic wastewater using an integrated settler-based biofilm reactor (ISBR) with efficient biogas generation. The ISBR provides an optimized environment for the growth of biofilm, facilitating the removal of organic pollutants and pathogens. Moreover, the ISBR enables the recovery of a valuable resource in the form of biogas, thus enhancing the overall utility of the treatment process. The performance of the ISBR was comprehensively evaluated at laboratory scale through treating the actual domestic wastewater generated from the hostel of Manipal University Jaipur. The ISBR system was operated under an ambient environment at a hydraulic retention time (HRT) of 24 h. The results demonstrated remarkable efficiency in terms of chemical oxygen demand (COD), total suspended solids (TSS), and coliforms removal, with average removal efficiency being more than 90%. According to the COD mass balance analysis, 48.2% of the influent COD was recovered as bioenergy. The chromatogram revealed a high percentage of methane gas in the collected biogas sample. The field emission scanning electron microscope (FESEM) analysis of the accumulated sludge in the ISBR system depicted the morphology of methanogenic bacteria. Both the experimental and theoretical results confirmed the feasibility and sustainability of the ISBR system at the onsite level.

Abstract This article introduces an effective stochastic operation framework for optimal energy management of the shipboard power systems including large, nonlinear and dynamic loads. The proposed framework divides the ship power system into several agents, which coordinate with each other based on their demands/supplies until. The alternating direction method of multipliers (ADMM) is deployed as the multi-agent framework to solve the reformulated distributed energy management problem in the ship. Two types of turbo-generators are considered in the proposed system model, including single-shaft and twin-shaft models, to increase the part-load efficiency in certain times when facing variable speed operation. The proposed distributed framework is equipped with a recursive mechanism, which helps the ship system for running optimal load scheduling when facing insufficient power generation. In order to model the uncertainty effects associated with the forecast error in the interval-ahead load demand, a stochastic framework based on unscented transform is devised which can work in the nonlinear and correlated environments of shipboard power systems. Due to the nonlinear cost function in each agent, a powerful optimization algorithm based on modified θ-firefly algorithm (Mθ-FOA) is proposed. This is a phasor algorithm, which helps for escaping from premature convergence and getting trapped in local optima. The appropriate performance of the proposed stochastic model is examined on the real dataset of a ship power system. The simulation results show the high robustness, guarantied consensus, economic operation and feasible solution when power generation shortage based on load shedding in the system.