• Energy Research
• Australian Research Council (ARC) close
• CN close
• DE close
• UA close

The catalytic active sites of NiFe and NiFeCr (oxy)hydroxides are revealed byoperandospectroscopic techonologies for alkaline water oxidation.

Abstract. Dynamic global vegetation models are used to predict the response of vegetation to climate change. They are essential for planning ecosystem management, understanding carbon cycle–climate feedbacks, and evaluating the potential impacts of climate change on global ecosystems. JULES (the Joint UK Land Environment Simulator) represents terrestrial processes in the UK Hadley Centre family of models and in the first generation UK Earth System Model. Previously, JULES represented five plant functional types (PFTs): broadleaf trees, needle-leaf trees, C3 and C4 grasses, and shrubs. This study addresses three developments in JULES. First, trees and shrubs were split into deciduous and evergreen PFTs to better represent the range of leaf life spans and metabolic capacities that exists in nature. Second, we distinguished between temperate and tropical broadleaf evergreen trees. These first two changes result in a new set of nine PFTs: tropical and temperate broadleaf evergreen trees, broadleaf deciduous trees, needle-leaf evergreen and deciduous trees, C3 and C4 grasses, and evergreen and deciduous shrubs. Third, using data from the TRY database, we updated the relationship between leaf nitrogen and the maximum rate of carboxylation of Rubisco (Vcmax), and updated the leaf turnover and growth rates to include a trade-off between leaf life span and leaf mass per unit area.Overall, the simulation of gross and net primary productivity (GPP and NPP, respectively) is improved with the nine PFTs when compared to FLUXNET sites, a global GPP data set based on FLUXNET, and MODIS NPP. Compared to the standard five PFTs, the new nine PFTs simulate a higher GPP and NPP, with the exception of C3 grasses in cold environments and C4 grasses that were previously over-productive. On a biome scale, GPP is improved for all eight biomes evaluated and NPP is improved for most biomes – the exceptions being the tropical forests, savannahs, and extratropical mixed forests where simulated NPP is too high. With the new PFTs, the global present-day GPP and NPP are 128 and 62 Pg C year−1, respectively. We conclude that the inclusion of trait-based data and the evergreen/deciduous distinction has substantially improved productivity fluxes in JULES, in particular the representation of GPP. These developments increase the realism of JULES, enabling higher confidence in simulations of vegetation dynamics and carbon storage.

Stomata regulate photosynthesis and transpiration, and these processes are critical for plant responses to abiotic stresses such as salinity. A barley double haploid population with 108 lines derived from a cross between CM72 (salt-tolerant) and Gairdner (salt-sensitive) was used to detect quantitative trait loci (QTLs) associated with stomatal and photosynthetic traits related to salinity tolerance.A total of 11 significant QTLs (LOD > 3.0) and 11 tentative QTLs (2.5 < LOD < 3.0) were identified. These QTLs are distributed on all the seven chromosomes, except 5H and explain 9.5-17.3% of the phenotypic variation. QTLs for biomass, intercellular CO2 concentration, transpiration rate and stomatal conductance under control conditions co-localised together. A QTL for biomass also co-located with one for transpiration rate under salinity stress. A linkage was found between stomatal pore area and gas exchange. A QTL for salinity tolerance also co-localised with QTLs for grain yield and biomass on chromosome 3H. Based on the draft barley genome, the candidate genes for salinity tolerance at this locus are proposed.The lack of major QTLs for gas exchange and stomatal traits under control and saline conditions indicates a complex relationship between salinity and leaf gas exchange due to the fact that these complex quantitative traits are under the control of multiple genes.

A promising technology for renewable energy is energy piles used to heat and cool buildings. In this research, the effects of bio-cementation via microbially induced calcite precipitation (MICP) using mixed calcium and magnesium sources and the addition of fibres on the thermal conductivity of soil were investigated. Firstly, silica sand specimens were treated with cementation solutions containing different ratios of calcium chloride and magnesium chloride to achieve maximum thermal conductivity improvement. Three treatment cycles were provided, and the corresponding thermal conductivity was measured after each cycle. It was found that using 100% calcium chloride resulted in the highest thermal conductivity. This cementation solution was then used to treat bio-cemented soil samples containing fibres, including polyethylene, steel and glass fibres. The fibre contents used included 0.5%, 1.0% and 1.5% of the dry sand mass. The results show that the glass fibre samples yielded the highest thermal conductivity after three treatment cycles, and SEM imaging was used to support the findings. This research suggests that using MICP as a soil improvement technique can also improve the thermal conductivity of soil surrounding energy piles, which has high potential to effectively improve the efficiency of energy piles.

Abstract Non-Newtonian fluid flows through packed beds are common in many industries. Our understanding of this flow system is very limited, and the correlations for describing the fluid-particle interaction are not fully established. To overcome these problems, this paper presents a comprehensive study of this system on a sub-particle scale, with a special reference to the interaction between fluid rheology and bed properties. This is done by conducting about five hundred Lattice Boltzmann simulations under different conditions. The fluid rheology is represented by the power-law model to consider the shear-thinning, shear thickening and Newtonian behaviors of fluids. The simulation condition covers a wide range of bed porosity, particle size distribution and Reynolds number (Re). The results show that the effect of fluid rheology on the fluid behavior is strong. This effect varies significantly with bed porosity which is a function of particle size distribution. The interplay between fluid rheology and bed properties is however not strong in determining the distributions of particle-fluid interaction force. Based on the simulation data, a new drag correlation is established and validated against the experimental data in the literature. This correlation is more accurate and consistent than those reported in the past. It can estimate the mean drag forces on individual particles of different sizes, and is recommended to be used generally in the modeling of particle-fluid flows either for Newtonian fluids or for non-Newtonian fluids obeying the power-law model.

Widespread tree mortality associated with drought has been observed on all forested continents and global change is expected to exacerbate vegetation vulnerability. Forest mortality has implications for future biosphere-atmosphere interactions of carbon, water and energy balance, and is poorly represented in dynamic vegetation models. Reducing uncertainty requires improved mortality projections founded on robust physiological processes. However, the proposed mechanisms of drought-induced mortality, including hydraulic failure and carbon starvation, are unresolved. A growing number of empirical studies have investigated these mechanisms, but data have not been consistently analysed across species and biomes using a standardized physiological framework. Here, we show that xylem hydraulic failure was ubiquitous across multiple tree taxa at drought-induced mortality. All species assessed had 60% or higher loss of xylem hydraulic conductivity, consistent with proposed theoretical and modelled survival thresholds. We found diverse responses in non-structural carbohydrate reserves at mortality, indicating that evidence supporting carbon starvation was not universal. Reduced non-structural carbohydrates were more common for gymnosperms than angiosperms, associated with xylem hydraulic vulnerability, and may have a role in reducing hydraulic function. Our finding that hydraulic failure at drought-induced mortality was persistent across species indicates that substantial improvement in vegetation modelling can be achieved using thresholds in hydraulic function.