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The focus of this research lies on fundamental research to provide guidelines for the design of new nanocatalyst toward improvement of the performance of proton exchange membrane fuel cells (PEMFCs). To achieve this overarching goal, several specific steps were taken with aims to: (1) provide guidelines for the design of new catalysts; (2) promote nanocatalyst applications towards alternative energy applications; and (3) integrate advanced instrumentation into nanocharacterization and fuel cell (FC) electrochemical behavior. In tandem with these goals, the cathode catalysts were extensively refined to improve the performance of PEMFCs and minimize noble metal usage. In this study, the major accomplishment was producing aligned carbon nanotubes (ACNTs), which were then modified by platinum (Pt) nanoparticles via a post-functionalization colloidal chemistry approach. The Pt-ACNTs demonstrated improved cathodic catalycity, by building better device endurance and decreased Pt loading. It was also determined that surface mechanical properties, such as elastic modulus and hardness were increased. Collectively, these enhancements provided an improved FC device. The electrochemical analyses indicated that the power density of the PEMFCs was increased to 900 mW/cm2 and current density to 3000 mA/cm2, respectively. The Pt loading was controlled at lower than 0.2 mg/cm2 to decrease the manufacturing expenses.

Recycled polylactic acid (PLAr) was reinforced with treated nanocellulosic hemp fibers for biocomposite fabrication. Cellulosic fibers were extracted from hemp fibers chemically and treated enzymatically. Treated nanocellulosic fibers (NCF) were analyzed by Fourier-transform infrared spectroscopy, X-ray diffraction, and scanning electron microscopy. Biocomposite fabrication was done with PLAr and three concentrations of treated NCF (0.1%, 0.25%, and 1% (v/v)) and then studied for thermal stability and mechanical properties. Increased thermal stability was observed with increasing NCF concentrations. The highest value for Young’s modulus was for PLAr + 0.25% (v/v) NCF (250.28 ± 5.47 MPa), which was significantly increased compared to PLAr (p = 0.022). There was a significant decrease in the tensile stress at break point for PLAr + 0.25% (v/v) NCF and PLAr + 1% (v/v) NCF as compared to control (p = 0.006 and 0.002, respectively). No significant difference was observed between treatments for tensile stress at yield.

Inter-turn winding faults in five-phase ferrite-permanent magnet-assisted synchronous reluctance motors (fPMa-SynRMs) can lead to catastrophic consequences if not detected in a timely manner, since they can quickly progress into more severe short-circuit faults, such as coil-to-coil, phase-to-ground or phase-to-phase faults. This paper analyzes the feasibility of detecting such harmful faults in their early stage, with only one short-circuited turn, since there is a lack of works related to this topic in multi-phase fPMa-SynRMs. Two methods are tested for this purpose, the analysis of the spectral content of the zero-sequence voltage component (ZSVC) and the analysis of the stator current spectra, also known as motor current signature analysis (MCSA), which is a well-known fault diagnosis method. This paper compares the performance and sensitivity of both methods under different operating conditions. It is proven that inter-turn faults can be detected in the early stage, with the ZSVC providing more sensitivity than the MCSA method. It is also proven that the working conditions have little effect on the sensitivity of both methods. To conclude, this paper proposes two inter-turn fault indicators and the threshold values to detect such faults in the early stage, which are calculated from the spectral information of the ZSVC and the line currents.

Oil shale is a kind of potential alternative energy source for petroleum and has attracted the attention of energy researchers all over the world. Borehole hydraulic mining has more prominent advantages than both conventional open-pit mining and underground mining. It is very important to attempt to use the borehole hydraulic mining method to exploit underground oil shale. The nozzle is the key component of borehole hydraulic mining and reasonable mining parameters are also crucial in exploiting underground oil shale efficiently. The straight cone nozzle and the oil shale of Huadian area will be taken as the research objects. The self-developed, multifunctional, experimental device can test both the jet’s performance as well as the breaking of oil shale by the high-pressure water jet using the straight cone nozzle and varying structural parameters. Comprehensive analysis of the results of an orthogonal experimental design, including range analysis and variance analysis, demonstrate the optimal structural parameters of a straight cone nozzle as follows: the outlet diameter is 4 mm, the length to diameter ratio is 2.5, and the contraction angle is 60°. In addition, in order to maximize the efficiency of borehole hydraulic mining for Huadian oil shale, the non-submerged jet should be placed parallel to the oil shale bedding. These results can provide scientific and valuable references for borehole hydraulic mining of oil shale.

Finding a numerical method to model solute transport in porous media with high heterogeneity is crucial, especially when chemical reactions are involved. The phase space formulation termed the multi-advective water mixing approach (MAWMA) was proposed to address this issue. The water parcel method (WP) may be obtained by discretizing MAWMA in space, time, and velocity. WP needs two transition matrices of velocity to reproduce advection (Markovian in space) and mixing (Markovian in time), separately. The matrices express the transition probability of water instead of individual solute concentration. This entails a change in concept, since the entire transport phenomenon is defined by the water phase. Concentration is reduced to a chemical attribute. The water transition matrix is obtained and is demonstrated to be constant in time. Moreover, the WP method is compared with the classic random walk method (RW) in a high heterogeneous domain. Results show that the WP adequately reproduces advection and dispersion, but overestimates mixing because mixing is a sub-velocity phase process. The WP method must, therefore, be extended to take into account incomplete mixing within velocity classes.

The global increase in energy demand and exponential exhaustion of fossil recourses has favored the development of new systems of electricity production. Photovoltaic solar energy is undoubtedly one that has the highest application in housings, due to its simplicity and easy implementation. In this work, a new prototype of photovoltaic solar tracker with Arduino platform was developed. Feedback control system that allows carrying out solar tracking with two axes using a stepper motor and linear actuator was established through an electronic circuit based on photodiodes. Moreover, real construction of the prototype was carried out, where the effectiveness of the design and its capacity to draw a maximum benefit of an incident radiation can be observed, placing the panel perpendicularly to the received energy and improving its performance for its application in future installations in housings. Results obtained from the comparison between the developed prototype and a static panel oriented according to the latitude of the area, show about 18% energy gain.