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Abstract The organic Rankine cycle (ORC) has been growing in importance as a technology for producing electricity from low temperature waste and renewable heat sources. In small-scale applications, the most used working fluid has been HFC-245fa, although this is being substituted for low GWP alternatives. A new HCFO working fluid, HCFO-1224yd(Z), has appeared as a possible alternative for HFC-245fa. In this study, this alternative working fluid is analysed and, finally, the working fluid is experimentally tested as drop-in alternative in a commercial ORC system. The main purpose is to determine the feasibility of using HCFO-1224yd(Z) as a drop-in replacement for HFC-245fa in a real facility that was initially designed to operate with HFC-245fa. The results show how the use of HCFO-1224yd(Z) offers power output that ranges from 7.5% to 17.4% lower than that provided by HFC-245fa. Although HFC-245fa offers higher power output, the results show that HCFO-1224yd(Z) offers up to 7.7% higher cycle net efficiency; this is due to the higher input thermal rate required by HFC-245fa. Finally, HCFO-1224yd(Z) has been stated as a suitable alternative to HFC-245fa as a drop-in replacement in a small-scale, low-temperature ORC, which increases its attractiveness for heat source with higher temperatures.

Abstract Both steady-state AC and DC power flow models are commonly used for techno-economic studies of power systems. The DC-based approach limits the computational burden by assuming small-angle approximation, ignoring power losses, reactive power flows, and voltage variations. It, therefore, matters to understand if this approach affects system vulnerability, reliability, and contingency assessments. To this aim, we use the time-sequential Monte Carlo simulation and an N-k′-1 scenario for reliability and contingency analyses, respectively. Further, we introduce a new index for vulnerability assessment. The IEEE reliability test system (RTS) and the modified RTS are modeled. The results show that the DC model underestimates the reliability indices by about 20% and more than 90% in a stressed network. We also show a small error of 5%, owing to the assumptions of the DC model, which can lead to inaccurate simulations concerning the cascading failures. Finally, the sources of the inaccuracy in the DC-based model are investigated. The results prove that AC power flow model should be privileged for the line capacity-based assessments.

AbstractAlthough canopy height has long been a focus of interest in ecology, it has remained difficult to study at large spatial scales. Recently, satellite‐borne LiDAR equipment produced the first systematic high resolution maps of vegetation height worldwide. Here we show that this new resource reveals three marked modes in tropical canopy height ~40, ~12, and ~2 m corresponding to forest, savanna, and treeless landscapes. The distribution of these modes is consistent with the often hypothesized forest‐savanna bistability and suggests that both states can be stable in areas with a mean annual precipitation between ~1,500 and ~2,000 mm. Although the canopy height states correspond largely to the much discussed tree cover states, there are differences, too. For instance, there are places with savanna‐like sparse tree cover that have a forest‐like high canopy, suggesting that rather than true savanna, those are thinned relicts of forest. This illustrates how complementary sets of remotely sensed indicators may provide increasingly sophisticated ways to study ecological phenomena at a global scale.

Coherence in Photosynthesis It is unclear how energy absorbed by pigments in antenna proteins is transferred to the central site of chemical catalysis during photosynthesis. Hildner et al. (p. 1448 ) observed coherence—prolonged persistence of a quantum mechanical phase relationship—at the single-molecule level in light-harvesting complexes from purple bacteria. The results bolster conclusions from past ensemble measurements that coherence plays a pivotal role in photosynthetic energy transfer. Hayes et al. (p. 1431 , published online 18 April) examined a series of small molecules comprised of bridged chromophores that also manifest prolonged coherence.

Capítulos en libros This paper assesses the scalability and replicability of smart grid projects, by means of the identification of limitations and barriers faced by these projects. Factors have been identified that impact a project s scalability and replicability by means of a review of demonstration projects. The factors are of technical, economic, regulatory and social acceptance nature, and they describe requirements for scalability and replicability. Data was collected from ongoing European smart grid demonstration projects through the use of an elaborated questionnaire on the identified factors. Which allowed to quantify the status quo to what extent projects have taken these factors into account. Dew to their nature the derived factors can be categorized in technical, economic and regulatory & stakeholder related factor areas The obtained results allowed the identification of barriers, i.e. limitations regarding the scalability and replicability of smart grid projects. In particular projects face barriers regarding the absence of standards, the physical limits of the existing infrastructure, the absence of cost-benefit analyses, the neglect of varying macro-economic factors, stakeholder involvement and from the dependency of projects on regional or national regulatory frameworks and market designs. info:eu-repo/semantics/publishedVersion

The lifetime and reliability of power transformers are primarily dependent on the hot-spot temperature in the windings, as temperature is the most important factor determining the insulation degradation rate. Key to removing the heat from the transformer is the radiator which must be carefully designed to keep the temperatures within limits under all operating conditions whilst minimizing the transformer size, weight and cost. This paper compares the analytical method used to predict the radiator performance with computational fluid dynamics (CFD) models in terms of heat dissipation. It is found that the analytical method and CFD models give similar results in the air natural (AN) cooling modes, whereas the analytical method overestimates the heat dissipation in the air forced (AF) cooling modes. Moreover, the thermal conduction effect in the radiator wall is investigated under different operating conditions and for different radiator sizes using the CFD models. The simulation results indicate that the radiator wall contributes to 6%-10% of the total heat dissipation under some circumstances and therefore should not be simply ignored in radiator models.

The recommended power quality (PQ) indices in electric power systems are defined based on the discrete Fourier transform (DFT). DFT is mostly evaluated applying fast Fourier transform (FFT) algorithm which requires signals to be periodic in nature. Hence, it evaluates PQ indices accurately for stationary PQ disturbances only. However, in case of nonstationary PQ disturbances signal is aperiodic and FFT results in erroneous assessment due to spectral leakage phenomena. Furthermore, FFT cannot provide time information of the PQ indices as computation is performed in frequency domain only. Which is significant shortcoming of the FFT when dealing with time-varying PQ disturbances to extract dynamic signature of the signal. Thereby, this paper presents a framework of redefining PQ indices for stationary and nonstationary PQ disturbances employing time-frequency distribution (TFD) method. Among all TFDs, reduced interference distribution (RID) represents the most suitable properties for analyzing time-varying PQ disturbances. Hence, in this work, it is employed to reformulate PQ indices typically used in electric power systems. The results of two synthetic examples considering stationary and nonstationary PQ disturbances imply that the RID-based redefined PQ indices are closer to the actual values. Also, they provide more accurate results than the existing transient PQ indices and traditional FFT-based method.

A literature review was conducted aiming at investigating the use of Sustainability, Lean, Green and eco-efficiency concepts, as well as meaningful combinations of those, on the field of Production and Operations Management. The study reports on the scientific papers published in all major journals in the field over the period 2001–2015. A set of 83 papers from 40 journals were selected for further analyzes, aiming at uncovering the existing level of awareness and use of the synergic and symbiotic relationship between Lean Manufacturing and Green Production. The findings show that a modest share of papers, about 30 %, explicitly recognize the Lean-Green joint approach. The same study testifies a clear growth pattern, which is patently reinforced in the last two and a half years, on the number of papers that behold a combined approach towards more efficient and cleaner production activities. The research has highlighted that the Lean-Green link does, in fact, exist and is gaining momentum, but requires further reinforcements from the scientific community, as well as from the companies, to deliver excelled and environmentally sound production systems. FCT Strategic Project PEst2015-2020, reference UID/CEC/00319/2013. info:eu-repo/semantics/publishedVersion