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The Environmental Displacement Dataset (EnDis) quantifies human movement in response to sudden-onset natural hazards, including floods, storms, wildfires, landslides, earthquakes, and volcanic activity.

The most widely used process for hydrogen production is steam methane reforming. It can be carried out using a membrane reactor in which simultaneous hydrogen production and purification occur. Mathematical modeling of these reactors plays a key role in the selection of the design and operating parameters that yield high performance for the reactor. This review study discusses, synthesizes, and compares different mathematical modeling studies on the packed bed membrane reactors for hydrogen production from methane found in the literature. Different approaches used in these modeling studies for the hydrogen permeation steps, reaction kinetic expressions, phases involved (pseudo-homogeneous and heterogeneous), and spatial dimensions (one, two, and three dimensional) are given.

Climate-controlled changes in eustatic sea level (ESL) are linked to transfers of water between ocean and land, thus offering a rare insight into the past hydrological cycle. In this study, we examine the timing and phase of Milankovitch-scale ESL cycles in the peak Cretaceous greenhouse, the early Turonian (-93-94 million years, Myr, ago). A high-resolution astronomical framework established for the Bohemian Cretaceous Basin (central Europe) suggests a -400-kyr pace and a distinct asymmetry of interpreted ESL cycles. The rising limbs of ESL change constitute only 20-30 % of the cycle, and are encased entirely within the falling phase of the 405-kyr eccentricity. The intervening ESL falls (<= 6 m in magnitude) are more protracted, starting within 70 kyr prior to the eccentricity minima and culminating -60 kyr after the 405-kyr eccentricity maxima. Despite similarities to the sawtooth shape of -100-kyr glacioeustatic oscillations of the Late Pleistocene, the time scales and phasing are unparalleled in the Pleistocene icehouse. A similar, 405-kyr pace is found in ice-volume variations of the early Miocene, but the timing of glacioeustatic change relative to eccentricity forcing is incompatible with the phase of greenhouse sea-level oscillations. The phasing points to major differences in the geographic location and insolation sensitivity of the key hydrological reservoirs under icehouse and greenhouse regimes. The inferred structure of greenhouse eustasy points to low- or middle-latitude water storage, likely aquifers, that charge (expand) with rising seasonality variations and discharge (contract) with declining seasonality amplitudes on the 405-kyr scale. The net volume of water transferred on these time scales is within 2.2 x 106 km3, equivalent to <= 10 % of the present-day storage in the uppermost 2 km of continental crust. Potential additive interference with steric eustasy, proportionally relevant during greenhouse regimes, could reduce the volumes required for continental storage.

The incorporation of recycled materials in concrete as a partial replacement of cement is becoming an alternative strategy for decreasing energy-intensive and CO2 emissions imputable to the cement manufacture, while investigating new potential uses of such multifunctional materials for environmental sustainability opportunities. Therefore, low-cost and worldwide availability of by-products materials is being assessed for sensible heat thermal energy storage applications based on cementitious materials. A greater concern is especially required focusing on the thermal stability of cement paste under high temperature cycled conditions. Moreover, compatibility between cement type and supplementary cementitious materials is determinant for the proper performance reliability. In this study, benchmark cement types were selected, i.e., ordinary Portland and calcium aluminate. Six supplementary cementitious materials were added to both types of cement in a content of 10 % and 25 %. Thermo-mechanical properties were studied before and after 10 thermal cycles from 290 to 650 ◦C. Results after thermal cycling showed that calcium aluminate cement paste mixtures maintained their integrity. However, most ordinary Portland cement paste mixtures were deteriorated: only mixtures with 25 % cement replacement with chamotte, flay ash, and ground granulated blast furnace slag remained without cracks. Calcium aluminate cement paste mixtures obtained the highest compressive strength, for partial replacement of cement with 10 % of chamotte, ground granulated blast furnace slag, and iron silicate. The incorporation of supplementary cementitious materials did not increase the thermal conductivity. This work was partially funded by the Ministerio de Ciencia, Innovación y Universidades de España (RTI2018-093849-B-C31 - MCIU/AEI/FEDER, UE) and by the Ministerio de Ciencia, Innovación y Universidades - Agencia Estatal de Investigación (AEI) (RED2018-102431-T). The authors at University of Lleida would like to thank the Catalan Government for the quality accreditation given to their research group (2017 SGR 1537). GREiA is certified agent TECNIO in the category of technology developers from the Government of Catalonia. This work is partially supported by ICREA under the ICREA Academia programme and by the Italian project ‘SOS-CITTA’ supported by Fondazione Cassa di Risparmio di Perugia under grant agreement No 2018.0499.026. Laura Boquera acknowledgments are due to the PhD school in Energy and Sustainable Development from University of Perugia. Laura Boquera would like to acknowledge the financial support provided by UNIPG – CIRIAF InpathTES project. The authors also thank the companies that provided the material to make possible this experimental research: Arciresa, Abrasivos Mendiola EDERSA—Masaveu Industria, General Admixtures S.p.A, Mapei, Ciments Molins industrial, and Promsa for the material supplied in this research. Financial support of the UNIPG-CIRIAF team has been achieved from the Italian Ministry of University and Research (MUR) in the framework of the Project FISR 2019: “Eco Earth” (code 00245) and it is gratefully acknowledged.

Abstract In the current transition to a smarter and more efficient transportation system, battery electric vehicle mileage and the time required for charging are still two main constraints that need to be overcome to enable a larger penetration of electric vehicles. Moreover, the few charging stations available are a consequence of the “supply and demand” problem. Consequently, wireless dynamic recharging can be a complementary solution to address the problems of light-duty electric mobility and an added-value towards autonomous vehicles. Consequently, this paper presents an innovative approach based on real world mobility patterns collected for a sample in the city of Lisbon, Portugal, to assess users’ electric vehicle feasibility by assessing different recharging scenarios, comparing stationary and dynamic recharging scenarios. The results indicate that at least 15 % more drivers would be eligible to own an electric vehicle if wireless charging was available. Moreover, wireless charging reduces the range of battery used, with stationary charging requiring circa 3.2 times more battery range. The developed approach confirms that wireless dynamic recharging can significantly change the framework of current electric mobility limitations, reducing range anxiety issues, contributing to redesign electric vehicle battery capacity and overcome barriers in stationary charging deployment and availability.

Growing interest of the European Union to introduce new emission regulations seeking to lower the particle cut-off size down to the current limit set at 23 nm, has made crucial to achieve an extensive comprehension on their nature. In this regard, it is necessary to deepen their knowledge under different engine technologies, operating conditions, fuel properties and after-treatment devices and how their measure is affected by the sampling and dilution procedure. This paper provides a study on the sub-23 nm particles emitted from a small direct/port fuel injection, spark ignition engine fueled with gasoline, ethanol and a 30% v/v ethanol/gasoline blend, at different operating conditions. Particles were measured both upstream and downstream of a three-way catalyst. The conditions of the sampling were changed in order to investigate the volatile organic fraction. For this purpose, the exhaust gas sample was diluted through a Particulate Measurement Programme compliant system. The temperature of the first dilution stage and of evaporation chamber were changed to discriminate the volatile compounds by enhancing the condensation and the nucleation processes. An engine Exhaust Particle Sizer was used for the sizing and the counting of the particles in the range 5.6-560 nm. The results show a strong dependence of the sub-23 nm particle emissions from the engine operating condition and the fuel type. A moderate impact of the three-way catalyst was instead observed. Moreover, a significant effect of the dilution parameters in the sampling system was noted pointing out the importance to define an appropriate protocol for the measurement of the sub-23 nm particles.

Worldwide, the energy consumption of refrigeration systems increased by 50% in the last 20 years. Currently, active refrigeration systems are often used to maintain cold chains in industry. However, there are remarkable drawbacks in the operation of active systems such as susceptibility to blackouts in the power supply and vibrations during their operation. Therefore, to overcome the aforementioned problems, passive cold chain transport using latent thermal energy storage systems arose as a potential solution. However, these systems require long charging times due to the low thermal conductivity of most phase change materials. In that sense, this paper presents a novel design of a cold storage battery with metal foam enhanced phase change material. The peak efflux of energy and solidification time of the battery is correlated as a function of the inlet temperature and mass flow rate of the heat transfer fluid with a root mean square deviation of 11.4%. The solidification time prediction allows determining the geometry which results in the maximum efflux of energy density for a given energy density. Moreover, the cold battery is placed in an insulated container to analyse its performance during transport. Results show that the tested refrigeration battery can act as a standalone refrigeration system during 15 h. However, improvements in the design of the insulated container are suggested to increase the performance of the system along the discharging cycle.

For the design of ground-source heat-pump systems, the local subsoil is an invariant factor. To improve the evaluation of the local heat exchange capability, significant efforts recently have been devoted to identifying the ground thermal conductivity vertical profile. In recent years, an innovative method using hybrid optic fiber cables inserted into the ground has been developed. The technique relies on copper wires that thermally stimulate the ground. Optical fibers measure the temperature variation over time all along the cable at a high spatial and temporal resolution. In this work, the hybrid cable was grouted into a 125-m well located in the Po Plain in Northern Italy. The provided core defined the geological environment as a continuous succession of unconsolidated alluvial deposits of very limited thickness, grouped in 15 different granulometric units. Three enhanced thermal response test (ETRT) data sets were acquired in different seasons; for 5 days of heating followed by 5 days of recovery, the soil temperature was recorded continuously along the well, with a spatial resolution of 1 m. A new approach using a multiple linear regression is proposed to analyze the data sets to distinguish the thermal conductivity of each individual granulometric unit. The obtained thermal conductivity values were compared and discussed considering the standard thermal response test outputs and the thermal conductivity data obtained from direct measurements performed on the cores. The analytical method's reliability stands due to the high repeatability of the obtained results, despite the increased complexity of the treated geological setting.

A correlation analysis based on Markowitz Portfolio Theory and data from meteorological station are used to develop a decision-making tool for the optimal spatial installation of renewable energy sources from Wind turbines and PV panels. A case study involving power generation plants and weather stations in the region of Tuscany in Italy is developed. The results show that temporal correlations of solar and wind generation profiles are characterized by correlation and anticorrelation. This feature is used for supporting deci­sion-making on investments in renewable energy at the territorial level.