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Abstract The oxidation characteristics of several small methyl and ethyl esters with carbon number less than six were investigated in laminar flames. The kinetics of such fuels are subsets of those of larger alkyl esters that are constituents of practical biodiesel fuels. A total of seven fuels, namely methyl formate, methyl acetate, methyl propionate, methyl butanoate, ethyl formate, ethyl acetate, and ethyl propionate were considered. Experiments were conducted at atmospheric pressure, elevated reactant temperatures, and over a wide range of equivalence ratios. Laminar flame speeds were determined in the counterflow configuration in which flow velocities were measured using particle image velocimetry. Several detailed kinetic models were tested against the experimental data, and insight was provided into the high-temperature combustion kinetics of the aforementioned fuels. Based on comparisons between experimental and computed results it became apparent that the chemistry of alkyl-ester combustion chemistry is evolving and much needs to be done in order to derive improved rate constants for a wide range of elementary steps.

Abstract The effect of the thermal environment on performance and productivity has been a focus of interest among indoor environmental researchers for nearly a century, but most of that work has been conducted in relative isolation from the cognate disciplines of human performance evaluation. The present review examines thermal environmental effects on cognitive performance research conducted across multiple disciplines. After differentiating performance from productivity, we compare the two dominant conceptual models linking thermal stress to performance; (1) the inverted-U concept and (2) the extended-U relationship. The inverted-U specifies a single optimum temperature (or its corresponding subjective thermal sensation) at which performance is maximised. In contrast, the extended-U model posits a broad central plateau across which there is no discernible thermal effect on cognitive performance. This performance plateau is bounded by regions of progressive performance decrements in more extreme thermal conditions. The contradictions between these opposing conceptual models might derive from various confounding factors at play in their underlying research bases. These include, inter alia, environment-related, task-related, and performer-related factors, as well as their associated two-way and three-way interaction effects. Methodological discrepancies that might also contribute to the divergence of these conceptual models are evaluated, along with the proposed causal mechanisms underlying the two models. The weight of research evidence reviewed in this paper suggests that the extended-U hypothesis fits the relationship between moderate thermal environments and cognitive performance. In contrast to the inverted-U relationship, implemention of the extended-U in indoor climate control implies substantial reductions in building energy demand, since it permits the heating and cooling setpoint deadband to expand across the full width of the thermal comfort zone, or even slightly further during emergencies such as peak demand events on the electricity grid. Use of personal comfort systems can further extend the thermostat setpoint range beyond the comfort zone.

Abstract Additional experimental data concerning the kinetics of Ni-Mo codeposition were obtained by investigating cathodic polarization using a rotating disc electrode. The Ni-Mo alloys were deposited from an ammonium citrate bath. The alloy deposition was controlled by activation in the case of low values of the cathode potential and by diffusion in the case of higher values. The hydrogen discharge was found to be diffusion controlled. The inductive influence of nickel results in depolarization of the reduction of molybdenum which cannot be deposited separately. An increase in the disc rotation speed caused an increase in the maximum cathode efficiency and in the molybdenum content of the alloy.

In this study, levulinic acid (LA) was produced from rice straw biomass in co-solvent biphasic reactor system consisting of hydrochloric acid and dichloromethane organic solvent. The modified protocol achieved a 15% wt LA yield through the synergistic effect of acid and acidic products (auto-catalysis) and the designed system allowed facile recovery of LA to the organic phase. Further purification of the resulting extractant was achieved through traditional column chromatography, which yielded a high purity LA product while recovering ∼85% wt. Upon charcoal treatment of the resultant fraction generated an industrial grade target molecule of ∼99% purity with ∼95% wt recovery. The system allows the solvent to be easily recovered, in excess of 90%, which was shown to be able to be recycled up to 5 runs without significant loss of final product concentrations. Overall, this system points to a method to significantly reduce manufacturing cost during large-scale LA preparation.

Abstract Pollution control strategies currently in use by electric power systems are reviewed and a new minimum emission dispatch (MED) method is developed. This new method minimizes overall emission levels at an increased cost in large-scale power systems while simultaneously accommodating local pollution level requirements, as well as economic constraints.

In the present study, we explored the temperature evolution and hydrogen desorption properties of the Mg50Ni50 alloy through both numerical simulation and experimental analyses. Desorption kinetics characterization was carried out using the volumetric method, specifically employing a Sievert's-type apparatus to investigate solid-gas reactions. The experiments covered a temperature range from 313 K to 353 K, with an initial hydrogen pressure of 12 bar. Simultaneously, a mathematical approach was employed to numerically investigate the temperature evolution within the hydride bed. Using COMSOL Multiphysics as a simulator, a numerical simulation was conducted based on experimental data. The study examined the impact of cooling temperature on hydride temperature evolution. Results revealed that hydrogen desorption kinetics of the amorphous Mg50Ni50 alloy are more significant compared to those of Mg2Ni compounds. Moreover, the effect of the warming temperature on the equilibrium pressure can also be observed in the hydrogen desorption isotherm curves. The experimental study of the Mg50Ni50 alloy provided activation energy data, along with determination of hydride formation enthalpy and entropy. On the other hand, we showed that the hydride temperature is maximum at the hydride-hydrogen interface within the hydride center.

Given the considerable scale of distribution networks in urban and rural areas, as well as the lack of management records, adjustments of switches during the distribution system operation are poorly documented. Such deficiency results in the inaccuracy of models stored in the distribution network automation system, and thus misleads the state estimation. With the emergence of information and communication technology, a large number of the feeder and residential smart meter data are accumulated. Such data can help recognize the operation modes of distribution networks by analyzing the relationships between the on/off states of switches and the voltage correlations among buses. However, the limited quantity and quality of the sampling data restrict the implementation of data-driven recognition. In this paper, a physical-probabilistic-network (PPN) model applied for inferring overall operation mode of distribution networks is proposed. Based on which, a belief propagation-based algorithm is proposed for the inference even under situations when there are only partial bus voltages data available. Meanwhile, the required variable for inference can be reduced from the active trail analysis. Experiment results are used to compare its performance with classic methods and to prove its effectiveness and advantages.

Abstract In this paper, the prevention of negative technogenic impact on the environment of oil sludge by using it as a secondary resource is considered. Oil sludge from various objects of oil fields in Kazakhstan (Mangystau region) has been studied. The possibilities of using oil (after its separation from oil sludge by bioremidiation) as a partial substitute for bitumen base in the production of modified bitumen are considered. The main physical and mechanical characteristics of modified bitumen are determined. The results confirm that the modified bitumen prepared with oil sludge and oil separated by bioremiation method meets the requirements for polymer-bitumen binder to Kazakhstan standards and is suitable for the production of modified bitumen in its physico-chemical characteristics.

Abstract Wellbore pressure gradient in gas wells is significant in designing deliquification technologies and optimizing production. At present, no model has yet to be established specifically for gas wells at a wide gas flowrate range. When calculating pressure gradient in a specific gas field, engineers must evaluate these widely used models and get the best performance model at a certain range. To establish a more comprehensive model in horizontal gas wells, an experimental study was conducted to investigate the flow behavior of liquid-gas two-phase flow at different gas and liquid velocities and inclined angles in a 50 mm visual pipe. The evaluation of these widely used models against the experimental data shows that no model can predict liquid holdup at different gas velocity ranges, and huge deviations due to several reasons can be observed. After conducting a comprehensive analysis, a new liquid holdup correlation was proposed based on the Mukherjee–Brill model by correlating from the experimental results, which have parametric ranges closer to the production of gas wells. This new model adopts a new dimensionless gas velocity number to characterize flow similarities and better scale up pressure from the experiment to the gas wells. By validating against experimental data and field data, the results indicate that the new two-phase flow model has stable performance and can accurately predict pressure gradients at different ranges of pressure and gas/liquid velocities.