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In this paper a novel generalised modelling framework for multi-energy systems containing storage elements is combined with a multi-objective model predictive control. The control objective is to both minimise the economic cost of importing energy into the system as well as providing the service of smoothing the profile of the electrical energy imported thus levelling the load and reducing peak demand. The capabilities of the approach are demonstrated by its application to a representative case study based on two buildings at the University of Manchester. Results show that model predictive control is capable of simultaneously addressing minimisation of economic cost as well as smoothing the electrical energy import.

This study highlights how Chinese economic development detrimentally impacted water quality in recent decades and how this has been improved by enormous investment in environmental remediation funded by the Chinese government. To our knowledge, this study is the first to describe the variability of surface water quality in inland waters in China, the affecting drivers behind the changes, and how the government-financed conservation actions have impacted water quality. Water quality was found to be poorest in the North and the Northeast China Plain where there is greater coverage of developed land (cities + cropland), a higher gross domestic product (GDP), and higher population density. There are significant positive relationships between the concentration of the annual mean chemical oxygen demand (COD) and the percentage of developed land use (cities + cropland), GDP, and population density in the individual watersheds (p < 0.001). During the past decade, following Chinese government-financed investments in environmental restoration and reforestation, the water quality of Chinese inland waters has improved markedly, which is particularly evident from the significant and exponentially decreasing GDP-normalized COD and ammonium (NH4+-N) concentrations. It is evident that the increasing GDP in China over the past decade did not occur at the continued expense of its inland water ecosystems. This offers hope for the future, also for other industrializing countries, that with appropriate environmental investments a high GDP can be reached and maintained, while simultaneously preserving inland aquatic ecosystems, particularly through management of sewage discharge.

It has long been established that mature forests are mosaics of patches in different development phases but it has seldom explicitly been taken into account in ecological studies. We demonstrate here that these development phases, which are related to the population dynamics of trees, play an important role in the distribution of fauna based on observations on frugivorous birds. In an area close to the Calakmul Biosphere Reserve in Mexico, we studied the abundance of large forest bird species in relation to forest development phases, with a methodology that seems promising for ecological diagnosis and prognosis in forest management planning. Fine-scale forest mapping and bird counts were carried out in two block-transects of 40 m x 3000 m. Tree sampling in a sub-transect was used to generate population characteristics of trees, Large bird species preferred mature or senescent forest patches, whereas relatively young, growing forest patches were avoided. Important large tree species such as Manilkara zapota, Thouinia paucidentata, Guaiacum sanctum and Esenbeckia pentaphylla, characteristic of older forest patches, showed skewed size distributions indicating stress or overexploitation. The population of M. zapota, a key fruiting species that accounted for 26.5% of the total woody biomass, was most heavily affected by stress. A future collapse in the population of M. zapota, a decrease of the total area of older forest, and a decline in the abundance of large birds is likely if stress on the system continues at this level. (C) 2008 Elsevier B.V. All rights reserved.

The influence of compost on the growth of bean plants irrigated with As-contaminated waters and its influence on the mobility of As in the soils and the uptake of As (as NaAs(III)O2) by plant components was studied at various compost application rates (3·10(4) and 6·10(4) kg ha(-1)) and at three As concentrations (1, 2 and 3 mg kg(-1)). The biomass and As and P concentrations of the roots, shoots and beans were determined at harvest time, as well as the chlorophyll content of the leaves and nonspecific and specifically bound As in the soil. The bean plants exposed to As showed typical phytotoxicity symptoms; no plants however died over the study. The biomass of the bean plants increased with the increasing amounts of compost added to the soil, attributed to the phytonutritive capacity of compost. Biomass decreased with increasing As concentrations, however, the reduction in the biomass was significantly lower with the addition of compost, indicating that the As phytotoxicity was alleviated by the compost. For the same As concentration, the As content of the roots, shoots and beans decreased with increasing compost added compared to the Control. This is due to partial immobilization of the As by the organic functional groups on the compost, either directly or through cation bridging. Most of the As adsorbed by the bean plants accumulated in the roots, while a scant allocation of As occurred in the beans. Hence, the addition of compost to soils could be used as an effective means to limit As accumulation in crops from As-contaminated waters.

Abstract The kinetics of methane hydrate decomposition was studied using a semibatch stirred-tank reactor. The decomposition was accomplished by reducing the pressure on a hydrate slurry in water to a value below the three-phase equilibrium pressure at the reactor temperature. The data were obtained at temperatures from 274 to 283 K and pressures from 0.17 to 6.97 MPa. The stirring rates were high enough to eliminate mass-transfer effects. Analysis of the data indicated that the decomposition rate was proportional to the particle surface area and to the difference in the fugacity of methane at the equilibrium pressure and the decomposition pressure. The proportionality constant showed an Arrhenius temperature dependence. An estimate of the hydrate particle diameters in the experiments permitted the development of an intrinsic model for the kinetics of hydrate decomposition.

The South is likely to suffer more from climate change than the North due to its already vulnerable situation and lack of the necessary resources to adapt to change. But do the interests of men and of women differ as regards climate change and does this have a South-North dimension? This paper attempts to establish whether gender issues need to be addressed in the climate change debate. Towards this goal, a number of different issues within the climate change debate, in particular the instruments proposed, are analysed. These include responsibility for emission of greenhouse gases (GHGs), studies on vulnerability to the effects of climate change, mitigation of emissions, capacity building for participation in flexible mechanisms and adaptation to climate change. We conclude that while there are many gender angles related to the climate change convention and the instruments therein, some are more strategic than others. There is little to be gained by looking at the responsibility for emissions on a gendered basis. But in mitigation activities, Clean Development Mechanism (CDM), capacity building, technology transfer, vulnerability studies and projects for adaptation, the poor, the majority of who are women, should be targeted and active participants in decision-making.

Abstract Thermal energy storage (TES) systems are growing to a relevant role in solar cooling applications. Hence, high energy density is a desirable property of the TES system. Phase change materials (PCM) helps to increase this characteristic. A high temperature pilot plant able to test different types of TES systems and materials was designed and built at the University of Lleida (Spain). This pilot plant is composed mainly of three parts: heating system, cooling system, and different storage tanks. Two identical storage tanks based on the shell-and-tubes heat exchanger, one of them including 196 squared fins in the bundle of the tubes and the other without, were experimentally tested. Hydroquinone was selected as the storage material, having a latent heat of 205 kJ/kg and a phase change temperature between 168 and 173 °C. The aim of this paper is to test experimentally, and compare the average effectiveness of the TES systems analyzed using PCM for solar cooling and refrigeration applications. It was found out that for the same tank configurations (shell-and-tubes) even changing drastically the dimensions of the tank or the number and the diameter of the tubes, the average effectiveness curve proposed in the literature fits well with the results showed here.

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