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Abstract The cooperative effect of hybrid Au-Ag nanoparticles and organic-inorganic cathode interfacial layers to advance the power conversion efficiency (PCE) of regio regular (rr) P3HT:PCBM based polymer solar cells (PSCs) are systematically demonstrated. In this work initially, two types of plasmonic nanoparticles (NPs), namely, citrate stabilized gold (AuNPs) and silver (AgNPs) were separately synthesized and then physically blend together with three different volume ratio [AuNPs + AgNPs (25:75), AuNPs + AgNPs (50:50) and AuNPs + AgNPs (75:25)]. These three blended NP solutions were then mixed together in the PEDOT:PSS (20 v/v %) hole extraction layer (HEL) to form three new NPs doped HEL and their effect on the rr-P3HT:PCBM based PSCs were systematically analyzed. For dual organic-inorganic cathode interfacial layers, two organic hole blocking materials, BPhen and BCP were used for enhanced charge collection in combination with LiF:Al as conventional cathode electrode. The collective effect of hybrid NPs with the dual cathode interfacial layers was examined with two varying active polymer blends, rr-P3HT:PC61BM and rr-P3HT:PC71BM. It has been found that the PCE increases considerably for both the active blend systems, with PEDOT:PSS + [AuNPs:AgNPs (25:75)] + BCP:LiF:Al as the modified cathode electrode. This is due to suitable electronic energy level matching of BCP:LiF:Al and active blend with the excellent surface plasmon property of the AuNPs:AgNPs (25:75) in the UV–Visible region compared to AuNPs:AgNPs (50:50) and AuNPs:AgNPs (75:25). Devices having configuration PEDOT:PSS + [AuNPs:AgNPs (25:75)] as HEL, rr-P3HT:PC71BM as active blend and BCP:LiF:Al provided PCE, ɳmax = 5.71% with Jsc = 16.44 mA/cm2, Voc = 0.58 V, FF = 60% and device with rr-P3HT:PC61BM as active blend layer was showing as PCE, ɳmax = 5.31% with Jsc = 14.77 mA/cm2, Voc = 0.58 V and FF = 62% with the same PEDOT:PSS + [AuNPs:AgNPs (25:75)] layer and BCP:LiF:Al. These results conclusively described a very simple technique in which the cooperative effect of plasmonic hybrid metals nanoparticles and dual cathode interfacial layers outstandingly enrich the PCE and in general the complete nature of rr-P3HT:PCBM based PSCs.

Abstract A general procedure for determining the optimum geometry of a reflector-augmented solar collector which produces a desired pattern of flux-augmentation is described. The example used for illustration is a stationary collector whose winter performance is to be improved. Consideration both a flat-plate collector with a bottom reflector and one with a top reflector led to distinct differences in their optimum configuration and performance being identified. Since either systems can be used to augment winter flux, a criterion for selecting the appropriate system is given. This criterion is based on the displacement in collector tilt from latitude inclination.

Analytical method is used to obtain the geometrical shape for non-imaging secondary (NIS) mirror in the application of concentrated photovoltaic (CPV). It is discussed in beam down optical system, NIS presents advantages to eliminate dark image, to reduce the solar disc effect, to improve the uniformity of the illumination, etc. comparing to the imaging secondary. The authors have emphasized that the geometrical shape of optical components in non-imaging optics can generally be high order surfaces not restricted to the quadratic surface in imaging optics and mostly "CPC" in early developed non-imaging optics. This paper has discussed the general criteria and two practical approaches for designing NIS. We listed some of the examples in this paper to form NIS by rotating a segment of linear or quadratic or cubic curve around the central axis of primary reflector. The method to calculate the parameters of such segment is described. Although in present discussion, we are referring the usage in PV concentrator, the method is generally applied in other optical fields. (C) 2013 Elsevier Ltd. All rights reserved.

Abstract In this work, film-based optical elements are used as a passive solar concentrator for Building Integrated Photovoltaic (BIPV) window applications. Micro-facets are used to induce total internal reflection allowing window glass to function as a wave guide, thus redirecting light onto the back side of bifacial photovoltaic (BFPV) cells. Seasonal variations in the incident angle at solar noon were considered for Chicago, IL. Three optical models were developed using commercial optical software, validating that the optical elements have a significant impact on the amount of light energy allowed to reach the back side of the bifacial cell. Further, an experimental validation was conducted using two commercially available films. Using a 1:1 film to PV-cell ratio, the first film demonstrated a maximum of 26.3% increase in power on the back side of the bifacial cell. The second film type allowed a maximum of 30.2% increase. Both films allowed solar energy to reach the back side of the cell over the range of incident angles that were evaluated, making it useful as a passive solar concentrator. Finally, both 2:1 and 3:1 film to PV-cell ratios were evaluated for each of the two film types. A maximum power increase of 35.1% was observed. The results indicate that film-based optical elements have potential as a passive solar concentrator for BIPV applications.

A linear correlation between UV-A and 380 nm was developed by means of the TUV 4.1 radiative transfer model. The prediction error of the correlation was evaluated with data from Buenos Aires, Argentina, 2001, and from 2006, Almeria, Spain. Percent random mean square error (RMSE%) was calculated for intervals of 10° of solar zenith angles, ranging 4.75% at 20° to 37.70% at 90° in clear days and 22.16% at 20° to 26.17% at 90° for cloudy days in Buenos Aires Argentina, and 1.27% at 20° to 11.27% at 90° for clear days in Almeria, Spain. Clouded days were not assessed with the data from Spain. In Argentina, the UV-A radiometer is located in a rural area and the 380 nm radiometer is located in an urban area 6 km away. Hence the real error of the proposed model is closer to that found in Spain were both measurements were performed at the same site. The objective of the work is to achieve a simple and precise method to assess UV-A availability for environmental applications of solar energy, particularly for solar water treatment, at any desired latitude.

Modeling the performance of some concentrating solar systems for thermal power plants may require high temporal resolution irradiance as input, in order to account for the impact of the cloud transient effects. This work proposes a simple method of generating synthetic irradiance of 10-min intervals from the hourly mean values. Boundary conditions are imposed to preserve the expected behavior under clear sky situations. The procedure consists basically on adding a random fluctuation, which characteristic amplitude depends on the sky conditions, to the hourly interpolated values. The assessment of the method with ground data have shown to main aspects to remark: daily and monthly means from the synthetic data are below 5% of root mean squared deviation compared to the original time series; despite the noticeable uncertainty in the 10-min synthetic irradiance values, the dynamic behavior of the fluctuations is comparable to the original data.

In this paper, a detailed model for the transient simulation of solar cavity receivers for concentrating solar power plants is presented. The proposed model aims to consider all the major phenomena influencing the performance of a cavity receiver, including radiation, convection and conduction heat transfer mechanisms. For the radiation heat exchange within the cavity, the radiosity method is implemented, where the view factor calculation for all the active and passive surfaces is performed by a ray tracing algorithm programmed in a free software environment for statistical computing, namely R. A one-dimensional modeling approach is used for the tubes constituting the receiver active panels, through which the heat transfer fluid (HTF) is pumped. The governing partial differential equations are solved numerically by applying the finite volume method. Convective heat losses are modeled through different correlations for natural and forced convection heat losses from the specific literature. Once the thermal behavior has been haracterized, the geometry of the model is later fixed to check the consistency of the model and to study its dynamic characteristics. A specific 51.6 MWth, PS10 like receiver is used in this paper, although the implemented model has the flexibility to allow a variable number of panels and geometric configurations. At last, an adaptive neural controller, designed and trained offline, controls the outlet temperature of the molten salts to the desired operating value. Results for transient simulations are shown in the paper, demonstrating the plausibility of the estimations obtained with the developed model. The proposed model has been implemented in the Modelica language and based on the Modelica Standard Library (MSL) modeling approach.