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This paper studies the long-term energy management of a microgrid coordinating hybrid hydrogen-battery energy storage. We develop an approximate semi-empirical hydrogen storage model to accurately capture the power-dependent efficiency of hydrogen storage. We introduce a prediction-free two-stage coordinated optimization framework, which generates the annual state-of-charge (SoC) reference for hydrogen storage offline. During online operation, it updates the SoC reference online using kernel regression and makes operation decisions based on the proposed adaptive virtual-queue-based online convex optimization (OCO) algorithm. We innovatively incorporate penalty terms for long-term pattern tracking and expert-tracking for step size updates. We provide theoretical proof to show that the proposed OCO algorithm achieves a sublinear bound of dynamic regret without using prediction information. Numerical studies based on the Elia and North China datasets show that the proposed framework significantly outperforms the existing online optimization approaches by reducing the operational costs and loss of load by around 30% and 80%, respectively. These benefits can be further enhanced with optimized settings for the penalty coefficient and step size of OCO, as well as more historical references. Submitted to Applied Energy

In the quest for effective solutions to address Environ. Pollut. and meet the escalating energy demands, heterojunction photocatalysts have emerged as a captivating and versatile technology. These photocatalysts have garnered significant interest due to their wide-ranging applications, including wastewater treatment, air purification, CO2 capture, and hydrogen generation via water splitting. This technique harnesses the power of semiconductors, which are activated under light illumination, providing the necessary energy for catalytic reactions. With visible light constituting a substantial portion (46%) of the solar spectrum, the development of visible-light-driven semiconductors has become imperative. Heterojunction photocatalysts offer a promising strategy to overcome the limitations associated with activating semiconductors under visible light. In this comprehensive review, we present the recent advancements in the field of photocatalytic degradation of contaminants across diverse media, as well as the remarkable progress made in renewable energy production. Moreover, we delve into the crucial role played by various operating parameters in influencing the photocatalytic performance of heterojunction systems. Finally, we address emerging challenges and propose novel perspectives to provide valuable insights for future advancements in this dynamic research domain. By unraveling the potential of heterojunction photocatalysts, this review contributes to the broader understanding of their applications and paves the way for exciting avenues of exploration and innovation.

Lake ecosystems are extremely sensitive to nitrogen growth, which leads to water quality degradation and ecosystem health decline. Nitrogen depositions, as one of the main sources of nitrogen in water, are expected to change under future climate change scenarios. However, it remains not clear how nitrogen deposition to lakes respond to future meteorological conditions. In this study, a source-oriented version of Community Multiscale Air Quality (CMAQ) Model was used to estimate nitrogen deposition to 263 lakes in 2013 and under three RCP scenarios (4.5, 6.0 and 8.5) in 2046. Annual total deposition of 58.2 Gg nitrogen was predicted for all lakes, with 23.3 Gg N by wet deposition and 34.9 Gg N by dry deposition. Nitrate and ammonium in aerosol phase are the major forms of wet deposition, while NH3 and HNO3 in gas phase are the major forms of dry deposition. Agriculture emissions contribute to 57% of wet deposition and 44% of dry deposition. Under future meteorological conditions, wet deposition is predicted to increase by 5.5% to 16.4%, while dry deposition would decrease by 0.3% to 13.0%. Changes in wind speed, temperature, relative humidity (RH), and precipitation rates are correlated with dry and wet deposition changes. The predicted changes in deposition to lakes driven by meteorological changes can lead to significant changes in aquatic chemistry and ecosystem functions. Apart from future emission scenarios, different climate scenarios should be considered in future ecosystem health evaluation in response to nitrogen deposition.

Solar modules in utility-scale systems are expected to maintain decades of lifetime to rival conventional energy sources. However, cyclic thermomechanical loading often degrades their long-term performance, highlighting the importance of effective design to mitigate thermal expansion mismatches between module materials. Given the complex composition of solar modules, isolating the impact of individual components on overall durability remains a challenging task. In this work, we analyze a comprehensive data set that comprises bill-of-materials (BOM) and thermal cycling power loss from 251 distinct module designs to identify the predominant design factors and their impacts on the thermomechanical durability of modules. The methodology of our analysis combines machine learning modeling (random forest) and Shapley additive explanation (SHAP) to correlate design factors with power loss and interpret the model's decision-making. The interpretation reveals that silicon type (monocrystalline or polycrystalline), encapsulant thickness, busbar numbers, and wafer thickness predominantly influence the degradation. With lower power loss of around 0.6\% on average in the SHAP analysis, monocrystalline cells present better durability than polycrystalline cells. This finding is further substantiated by statistical testing on our raw data set. The SHAP analysis also demonstrates that while thicker encapsulants lead to reduced power loss, further increasing their thickness over around 0.6 to 0.7mm does not yield additional benefits, particularly for the front side one. In addition, other important BOM features such as the number of busbars are analyzed. This study provides a blueprint for utilizing explainable machine learning techniques in a complex material system and can potentially guide future research on optimizing the design of solar modules.

With California's ambitious goal to achieve decarbonization of the electrical grid by the year 2045, significant challenges arise in power system investment planning. Existing modeling methods and software focus on computational efficiency, which is currently achieved by simplifying the associated unit commitment formulation. This may lead to unjustifiable inaccuracies in the cost and constraints of gas-fired generation operations, and may affect both the timing and the extent of investment in new resources, such as renewable energy and energy storage. To address this issue, this paper develops a more detailed and rigorous mixed-integer model, and more importantly, a solution methodology utilizing surrogate level-based Lagrangian relaxation to overcome the combinatorial complexity that results from the enhanced level of model detail. This allows us to optimize a model with approximately 12 million binary and 100 million total variables in under 48 hours. The investment plan is compared with those produced by E3's RESOLVE software, which is currently employed by the California Energy Commission and California Public Utilities Commission. Our model produces an investment plan that differs substantially from that of the existing method and saves California over 12 billion dollars over the investment horizon.

Climate change, along with infectious diseasespathogens notably Batrachochytrium dendrobatidis (Bd), B. salamandrivorans (Bsal), Ranavirus, and PerkinseaPerkinsus, continue to devastate global amphibian populations, contributing to the greatest vertebrate extinctions of the Anthropocene. These pathogens, primarily favoring cooler, subtropical conditions, demonstrate a significant overlap in their climatic niches, thus affecting a broad range species. Here, we aim to explore the role of global warming and other climatic factors in the dispersal and evolution of these pathogens and to predict the future implications for amphibian populations worldwide. Given the limitations of data availability We conducted a thorough analysis of the climatic niche conservatism (NC) and evolution (CNE) of these pathogens using the currently available distributional data, including our own. We used , We engaged in a comprehensive analysis of the climatic niche conservatism (NC) and evolution (CNE) of these pathogens, utilizing predictive models to anticipate potential shifts in their future distribution and evaluate the capacity for CNE in response to climate change. We show that Bd and Bsal are likely to experience a total reduction in their current potential distributions by 2040, while Ranavirus and PerkinseaPerkinsus may expand their distributions. Interestingly, CNE has played a significant role in influencing the climatic niches of Bd and Bsal, with lineage dependent variations. However, there was no strong correlation found between virulence of Bd and its climatic niche. On the contrary, ranaviruses Ranaviruses and PerkinseaPerkinsus showed evidence of sporadic and recent CNE. Moreover, the emergence of lineages adapted to warmer climates suggests an ongoing CNE and a potential evolutionary response to climate change. With increased infection risk, particularly for Asian amphibians (from Ranavirus and PerkinseaPerkinsus), and the vulnerability of the southern hemisphere (except Bsal) due to limited prior exposure, this study underscores the urgent need for close monitoring and preventive measures, including stringent biosecurity protocols such as risk analysis and pre-border pathogen screening. Our study provides a critical framework for international collaboration and guideline development for amphibian trade, while contributing to the deeper dialogue on mitigating impacts of climate change on wildlife diseases.

Existing modeling approaches for long-duration energy storage (LDES) are often based either on an oversimplified representation of power system operations or limited representation of storage technologies, e.g., evaluation of only a single application. This manuscript presents an overview of the challenges of modeling LDES technologies, as well as a discussion regarding the capabilities and limitations of existing approaches. We used two test power systems with high shares of both solar photovoltaics- and wind (70% - 90% annual variable renewable energy shares) to assess LDES dispatch approaches. Our results estimate that better dispatch modeling of LDES could increase the associated operational value by 4% - 14% and increase the standard capacity credit by 14% - 34%. Thus, a better LDES dispatch could represent significant cost saving opportunities for electric utilities and system operators. In addition, existing LDES dispatch modeling approaches were tested in terms of both improved system value (e.g., based on production cost and standard capacity credit) and scalability (e.g., based on central processing unit time and peak memory usage). Both copper plate and nodal representations of the power system were considered. Although the end volume target dispatch approach, i.e., based on mid-term scheduling, showed promising performance in terms of both improved system value and scalability, there is a need for robust and scalable dispatch approaches for LDES in transmission-constrained electric grids. Moreover, more research is required to better understand the optimal operation of LDES considering extreme climate/weather events, reliability applications, and power system operational uncertainties. Comment: 45 pages, 16 figures, Submitted to Renewable and Sustainable Energy Reviews