• Energy Research

Diesel engine exhausts from a common rail 3.0 L F1C diesel engine were analyzed at two different load conditions of the WLTC testing cycle downstream of both the diesel particulate filter (DPF) and selective catalytic reactor (SCR) to verify their effect on the characteristics of carbon particulate matter. An array of chemical, physical and spectroscopic techniques (gas chromatography coupled with mass spectrometry (GC-MS), mobility analyzer, UV-Visible absorption and fluorescence spectroscopy) was applied for characterizing polycyclic aromatic hydrocarbons (PAH), heavy aromatic compounds and soot, constituting the particulate matter (PM) sampled from the exhaust. The engine was operated in half load (HL) (188 Nm, representing the more common condition for engine in urban traffic) and full load (FL) (452 Nm, representing the best performance of the engine operation) conditions, at the same engine speed (2000 rpm). Soot formation was enhanced in HL condition, with respect to FL, but, just because of the much lower soot amount, the after-treatment systems in this last condition resulted to be less efficient in the soot abatement. Indeed, the abatement through DPF was about 40% lower in the FL condition with respect to HL condition, and any significant further concentration decrease was found after SCR, in both conditions. By contrast, PAH concentration after DPF abatement was found to be higher in the HL with respect to FL condition. A further PAH concentration decrease of about 30% was found after the SCR in the HL condition whereas in FL the reduction was only about 5-6%. Also the heavy aromatic compounds having molecular weight above the GC-MS detection limit (300 u), were mitigated by SCR. Therefore, SCR did not cause a further soot reduction, whereas it was effective in largely reducing PAH and heavy aromatics emissions, especially in the lower temperature condition featuring the half-load condition, when combustion efficiency is worse. Moreover, SCR system reduced the emission of small particles probably due to an enhanced agglomeration of particles, with beneficial effect on the harmfulness to human health.

In this paper we report the use of the optical technique applied in the cylinder of an optically accessible engine equipped with the latest-generation diesel engine head of a European passenger car. The injection strategy with high percentage of EGR, characteristic of real engine operating point, was adopted. Alternative diesel fuels were used. In particular, rapeseed methyl ester (RME) and gas to liquid (GTL) were selected as representative of 1st and 2nd generation alternative diesel fuels, respectively. Combustion analysis was carried out in the engine combustion chamber by means of 2D spectroscopic measurements from UV to visible. These measurements helped to analyze the chemical and physical events occurring during the mixture preparation and the combustion development. Ultraviolet (UV) digital imaging was also performed and the presence of characteristic radical, like OH, in the various phases of combustion was detected as well. OH spatial distribution and temporal evolution were measured. Two color pyrometry technique was applied in order to measure the soot volume fraction within the combustion chamber. The GTL fuel showed better performance in terms of indicated mean effective pressure (IMEP) with respect to the diesel reference fuel with different effects on particulate matter (PM) and gaseous emissions. It showed the highest in cylinder soot production, while the OH radical had maximum intensity value close to the reference diesel (REF) one. On the other hand, the RME fuel showed a decrease in IMEP that can be adjusted with a little increase of fuel injected quantity, and very low production of soot in the cylinder and PM at the exhaust compared to the diesel reference fuel. Finally, the OH radical had the lowest intensity value.

Superior fuel economy, higher torque and durability have led to the diesel engine being widely used in a variety of fields of application, such as road transport, agricultural vehicles, earth moving machines and marine propulsion, as well as fixed installations for electrical power generation. However, diesel engines are plagued by high emissions of nitrogen oxides (NOx), particulate matter (PM) and carbon dioxide when conventional fuel is used. One possible solution is to use low-carbon gaseous fuel alongside diesel fuel by operating in a dual-fuel (DF) configuration, as this system provides a low implementation cost alternative for the improvement of combustion efficiency in the conventional diesel engine. An initial step in this direction involved the replacement of diesel fuel with natural gas. However, the consequent high levels of unburned hydrocarbons produced due to non-optimized engines led to a shift to carbon-free fuels, such as hydrogen. Hydrogen can be injected into the intake manifold, where it premixes with air, then the addition of a small amount of diesel fuel, auto-igniting easily, provides multiple ignition sources for the gas. To evaluate the efficiency and pollutant emissions in dual-fuel diesel-hydrogen combustion, a numerical CFD analysis was conducted and validated with the aid of experimental measurements on a research engine acquired at the test bench. The process of ignition of diesel fuel and flame propagation through a premixed air-hydrogen charge was represented the Autoignition-Induced Flame Propagation model included ANSYS-Forte software. Because of the inefficient operating conditions associated with the combustion, the methodology was significantly improved by evaluating the laminar flame speed as a function of pressure, temperature and equivalence ratio using Chemkin-Pro software. A numerical comparison was carried out among full hydrogen, full methane and different hydrogen-methane mixtures with the same energy input in each case. The use of full hydrogen was characterized by enhanced combustion, higher thermal efficiency and lower carbon emissions. However, the higher temperatures that occurred for hydrogen combustion led to higher NOx emissions.

<div class="section abstract"><div class="htmlview paragraph">Electrification of transport, together with the decarbonization of energy production are suggested by the European Union for the future quality of air. However, in the medium period, propulsion systems will continue to dominate urban mobility, making mandatory the retrofitting of thermal engines by applying combustion modes able to reduce NOx and PM emissions while maintaining engine performances. Low Temperature Combustion (LTC) is an attractive process to meet this target. This mode relies on premixed mixture and fuel lean in-cylinder charge whatever the fuel type: from conventional through alternative fuels with a minimum carbon footprint. This combustion mode has been subject of numerous modelling approaches in the engine research community. This study provides a theoretical comparative analysis between multi-zone (MZ) and Transported probability density function (TPDF) models applied to LTC combustion process. The generic thermo-kinetic balances for both approaches have been analyzed in term of similarities. Only onion-skin for MZ models have been considered in this study. The governing assumptions linked to sub-models for each approach to describe mixing process for TPDF and interzonal heat and mass transport for MZ are discussed. This step identifies the calibrated model parameters for each approach and their effects on the accuracy in predicting LTC mode simulations. This work shows that the transported probability density function model has fewer parameters to calibrate compared to multi-zone model. Transported probability density function seems easier to use for LTC process.</div></div>

Particle size distributions (PSDs) are measured at the exhaust of a diesel engine burning a sulphur-free diesel fuel and a blend of the fuel with a rapeseed methyl-ester. Different operating conditions of load and engine speed are analyzed. Particles with sizes ranging from few nanometers up 1 ?m are generated during combustion in the engine. Operating conditions and fuel characteristics strongly affect the PSDs confirming that particles are generated from fuel oxidation and pyrolysis rather than from the oxidation of lube oil or from other sources in the engine. The higher is the engine load, the higher the emission of mass concentration of particulate matter but the lower their number concentration. At fixed engine loads, the increase of the engine speed produces more particles and with larger mean sizes. The use of the biofuel blended with a commercial fuel reduces the total mass concentration of particulate matter but strongly increases the number concentration of sub-10 nm particles

In the present paper, infrared (IR) measurements were performed in order to study the development of injection and combustion in a transparent Euro 5 diesel engine operating in premixed mode. An elongated single cylinder engine equipped with the multi-cylinder head of commercial passenger car and with common rail (CR) injection system, respectively, was used. A sapphire window was set in the bottom of the combustion chamber, and a sapphire ring was placed between the head and the top of the cylinder line. Measurements were carried out through both accesses by a new high-speed infrared (IR) digital imaging system obtaining information that was difficult to achieve by the conventional UV- visible camera. IR camera was able to detect the emitted light in the wavelength range 1.5-5 ìm that is relevant for the emission bands of CO2 and H2O. The evaporation phase of pre and main injection, and subsequent combustion evolution were analyzed. Moreover, IR imaging was carried out by means of “ad hoc” filter to evaluate the spatial distribution of CO2 inside the cylinder. Images sequence during the whole engine cycle, starting from the intake and stopping to the exhaust phase, was observed from both optical windows. A comparison with visible imaging was carried out. IR measurements showed the ability to determine temporal and spatial distribution of fuel during evaporation phase and evaluate the combustion process evolution for longer time than visible imaging. Moreover, the IR camera was revealed very useful tool to detect the emitted light after a long operation time of the engine. The camera was able to acquire images of the reactions that happen in the combustion chamber and above the piston head even if the optical windows were obscured by the soot produced from the previous combustion cycles.

This paper deals with the combustion characteristics and exhaust emissions of a diesel engine fuelled with conventional diesel fuel and a biodiesel blend, in particular a 20% v/v concentration of rapeseed methyl ester (RME) mixed with diesel fuel. The investigation was carried out on a prototype three-cylinder engine with 1000 cc of displacement for quadricycle applications. The engine is equipped with a direct common-rail injection system that reaches a maximum pressure of 1400 bar. The engine was designed to comply with Euro 4 and BS IV exhaust emission regulations without a diesel particulate filter. Both in-cylinder pressure and rate of heat release traces were analyzed at different engine speeds and loads. Gaseous emissions were measured at the exhaust. A smoke meter was used to measure the particulate matter concentration. The sizing and the counting of the particles were performed by means of an engine exhaust particle sizer spectrometer. It was found that the number-size distribution of particles is strongly dependent on the engine operating conditions. The effect of biofuel on particle emissions is more evident ad high engine speed.

The aim of this study is to investigate the combustion process and pollutant formation in a small compression ignition engine for quadricycles. The engine is a three-cylinder, 1028 cc, with a CR injection system. It was designed to meet Euro 4 emission standard that is a future regulation for quadricycles. Two optical accesses for endoscopes were realized in the first cylinder to investigate the combustion process. Two-color pyrometry was applied to combustion images to detect both the flame temperature and the soot concentration. The engine ran with diesel fuel and both blended and pure biofuel. Operating condition at 1400 rpm, medium load was tested. A correlation between incylinder data of flame temperature and soot concentration with NOx and PM emissions at exhaust, respectively, was found. It was observed a variation of engine calibration, at fixed power output, when the engine runs with biodiesel resulting in an increase of NOx emissions