• Energy Research

In this study, in terms of the mechanisms of nitric oxide (NO) emissions, research was carried out to consider the impact of physical and chemical properties of wood and herbaceous biomass processed into pellets and briquettes in the course of the combustion process (in individual phases) in a low-power heating device. Combustion tests in the grate heating device showed statistically significant differences in the combustion process and thus carbon monoxide (CO), nitric oxide (NO), and sulfur dioxide (SO2) emissions in the fuel form and the combustion phase. In terms of assessing the ecological and energy parameters of the combustion process, the nitrogen content in biomass was not the most important factor indicating the formation of NO emissions. Usually, the strongest correlations were observed with the formation of NO emissions in the first phase of combustion, which was related to the emissions of CO and SO2. In the second and third flame phases, a significant reduction in NO emissions was observed, which was poorly positively dependent on the nitrogen contained in the fuel. In addition, it has been shown that the fuel geometric features greatly influence NO content in the exhaust gases in the first combustion phase. It is also indicated that further research is required, considering the possibility of reducing volatile flue gas fractions, which will lead to the development of low-emission and highly efficient biofuel combustion technologies in low-power heating devices.

In this study, in terms of the mechanisms of nitric oxide (NO) emissions, research was carried out to consider the impact of physical and chemical properties of wood and herbaceous biomass processed into pellets and briquettes in the course of the combustion process (in individual phases) in a low-power heating device. Combustion tests in the grate heating device showed statistically significant differences in the combustion process and thus carbon monoxide (CO), nitric oxide (NO), and sulfur dioxide (SO2) emissions in the fuel form and the combustion phase. In terms of assessing the ecological and energy parameters of the combustion process, the nitrogen content in biomass was not the most important factor indicating the formation of NO emissions. Usually, the strongest correlations were observed with the formation of NO emissions in the first phase of combustion, which was related to the emissions of CO and SO2. In the second and third flame phases, a significant reduction in NO emissions was observed, which was poorly positively dependent on the nitrogen contained in the fuel. In addition, it has been shown that the fuel geometric features greatly influence NO content in the exhaust gases in the first combustion phase. It is also indicated that further research is required, considering the possibility of reducing volatile flue gas fractions, which will lead to the development of low-emission and highly efficient biofuel combustion technologies in low-power heating devices.

This paper presents an analysis of selected qualitative characteristics of pellets produced from rape straw obtained from cultivations subjected to different fertilization treatments and from mixtures of straw selected for testing with crude glycerol obtained as a by-product from biodiesel production. The assessment focused on the following qualities of the obtained pellets: Moisture content, mechanical durability, heating value and main elements, that is, carbon, hydrogen, nitrogen, sulphur, chlorine and oxygen. The obtained results indicated that the different treatment regimens applied in spring rape cultivations had a significant impact on the physicochemical qualities of the straw. In terms of the heating value, traditional fertilization with multi-component fertilizer (NPK) yielded slightly lower chemical parameters (lower carbon content and heat of combustion) than in the case of straw obtained from the control sample and from the plot fertilized with digestate. Furthermore, in all of the analysed mixtures, the 10% addition of raw glycerol improved the mechanical characteristics of the produced straw pellets. After the 10% glycerol addition, in terms of the energetic use of these biofuels, the parameters of the fuel, such as heating value and net heating value, were slightly decreased.

This paper presents an analysis of selected qualitative characteristics of pellets produced from rape straw obtained from cultivations subjected to different fertilization treatments and from mixtures of straw selected for testing with crude glycerol obtained as a by-product from biodiesel production. The assessment focused on the following qualities of the obtained pellets: Moisture content, mechanical durability, heating value and main elements, that is, carbon, hydrogen, nitrogen, sulphur, chlorine and oxygen. The obtained results indicated that the different treatment regimens applied in spring rape cultivations had a significant impact on the physicochemical qualities of the straw. In terms of the heating value, traditional fertilization with multi-component fertilizer (NPK) yielded slightly lower chemical parameters (lower carbon content and heat of combustion) than in the case of straw obtained from the control sample and from the plot fertilized with digestate. Furthermore, in all of the analysed mixtures, the 10% addition of raw glycerol improved the mechanical characteristics of the produced straw pellets. After the 10% glycerol addition, in terms of the energetic use of these biofuels, the parameters of the fuel, such as heating value and net heating value, were slightly decreased.

Nowadays, heating using wood, briquettes, or pellets is a curious replacement to fossil fuels such as coal, oil, or gas. Unfortunately, the combustion of biofuels, especially in low-power boilers with unstable operating conditions, releases a lot of gas pollutants (e.g., carbon monoxide (CO), nitric oxide (NO), and various organic compounds) that are usually generated due to the incomplete product combustion. The combustion of biofuel in grate boilers with top-down ignition is a new approach, popular in society (mainly used for coal fuels), which improves the combustion process and reduces the amount of pollutants emitted. This study evaluated the impact of ignition techniques on the emission level of gas pollutants during the combustion of wood logs, briquettes, and pellets of pine in grate-based charging boilers. The combination of top ignition mode with pinewood logs allowed us to achieve a reduction of 6% in CO and sulfur dioxide (SO2) emission into the atmosphere. However, the combination of top-down ignition mode with pellets and briquettes produced, in fully operational conditions, 1- to 18-fold higher levels of CO and SO2 respectively, than bottom-up ignition, after an initial period of low level CO and SO2 emissions. During the tests (mainly with ignition from top), substantial emissions of NO were observed of up to 400 mg·m−3 at 10% O2. Therefore, further research is required to decrease emission related to the content of nitrogen in biomass. In this respect, research of impact on the combustion temperature of such emissions is needed.

Nowadays, heating using wood, briquettes, or pellets is a curious replacement to fossil fuels such as coal, oil, or gas. Unfortunately, the combustion of biofuels, especially in low-power boilers with unstable operating conditions, releases a lot of gas pollutants (e.g., carbon monoxide (CO), nitric oxide (NO), and various organic compounds) that are usually generated due to the incomplete product combustion. The combustion of biofuel in grate boilers with top-down ignition is a new approach, popular in society (mainly used for coal fuels), which improves the combustion process and reduces the amount of pollutants emitted. This study evaluated the impact of ignition techniques on the emission level of gas pollutants during the combustion of wood logs, briquettes, and pellets of pine in grate-based charging boilers. The combination of top ignition mode with pinewood logs allowed us to achieve a reduction of 6% in CO and sulfur dioxide (SO2) emission into the atmosphere. However, the combination of top-down ignition mode with pellets and briquettes produced, in fully operational conditions, 1- to 18-fold higher levels of CO and SO2 respectively, than bottom-up ignition, after an initial period of low level CO and SO2 emissions. During the tests (mainly with ignition from top), substantial emissions of NO were observed of up to 400 mg·m−3 at 10% O2. Therefore, further research is required to decrease emission related to the content of nitrogen in biomass. In this respect, research of impact on the combustion temperature of such emissions is needed.

Methane from environmentally friendly anaerobic digestion may be an alternative non-renewable source that is depleting. One of the substrates for that process may be lignocellulose-based materials. The article concerns comparing the environmental impact as well as technical and energy indicators of alternative ways of producing methane from the anaerobic digestion of Pennisetum hybrid. Five scenarios were analyzed: methane production from the anaerobic digestion of the raw grass, the grass subjected to alkaline pretreatment (with 2% NaOH solution at two temperatures), and the grass subjected to mechanical pretreatment (ground to obtain particle sizes <0.18 mm and 0.25–0.38 mm). Multi-criteria decision (MCA) analysis was carried out with the use of five indicators, including life cycle assessment results as well as methane production parameters, in order to optimize this sustainable way of bioenergy production. The purpose of this study was to identify the most cost-effective and environmentally friendly method of Pennisetum hybrid pretreatment in order to optimize the methane production process in terms of environmental, technical, and economic aspects. According to the obtained results, it was stated that the most advantageous solution for the majority of the analyzed indicators turned out to be the mechanical pretreatment with grinding the lignocellulosic biomass into a particle size <0.18 mm.