• Energy Research

AbstractThe combustion of solid fuels, including coal and biomass, is a main anthropogenic source of atmospheric particulate matter (PM). The hidden costs have been underestimated due to lack of consideration of the toxicity of PM. Here we report the unequal toxicity of inhalable PM emitted from energy use in the residential sector and coal-fired power plants (CFPPs). The incomplete burning of solid fuels in household stoves generates much higher concentrations of carbonaceous matter, resulting in more than one order of magnitude greater toxicity than that from CFPPs. When compared with CFPPs, the residential sector consumed only a tenth of solid fuels in mainland China in 2017, but it contributed about 200-fold higher of the population-weighted toxic potency-adjusted PM2.5 exposure risk. We suggest that PM2.5-related toxicity should be considered when making air pollution emission control strategies, and incomplete combustion sources should receive more policy attention to reduce exposure risks.

243 surface soil samples were collected from the Yangtze River Delta (YRD) region, and the concentration distributions and compositional profiles of 27 parent PAHs (PPAHs), nitro- and oxy-derivatives (NPAHs and OPAHs), respectively, and health risk of 16 PPAHs were determined. Atmospheric samples were collected at two sites with high topsoil concentrations of PAHs to assist in identifying the emission sources of PPAHs. The total concentrations of PPAHs, NPAHs and OPAHs fell in the ranges of 21.0-3563.2 ng/g, 0.4-4.6 ng/g and 2.1-834.1 ng/g, respectively. PPAHs in topsoil were dominated by low and medium molecular weight species. The main components of OPAHs were 9FO and ANQ. For NPAHs, only 1N-NAP was frequently detected. Overall, the northern parts of the YRD region were more heavily contaminated by PPAHs and their corresponding derivatives. The soil TOC fraction and GDP per capita were significantly correlated with the spatial distribution of PPAHs. Specific ratios of isomeric species and principal component analysis (PCA) designated combustion of industrial coal and biomass, and traffic exhaust as the main mixed emission sources of PPAHs in surface soils in this region. The detected NPAHs and OPAHs were significantly associated with the corresponding PPAHs. The estimated incremental lifetime cancer risk attributed to 16 PPAHs in surface soil was greater than 10-6, indicating a potential risk of contracting cancer by exposure to topsoil from the YRD region. The cumulative probability of cancer risk for both adults and children via three exposure pathways followed the sequence of dermal contact > ingestion > inhalation.

Peatland of the eastern Qinghai–Tibetan Plateau lies at the convergence of the East Asian and Indian monsoon systems in eastern Asia. To understand the evolution of this peatland and its potential to provide new insights into the Holocene evolution of the East Asian monsoon a 6 m peat core was collected from the undisturbed central part of a peat deposit near Hongyuan. The age-depth profile was determined using 16 14C-AMS age dates, the peat analysed for a range of environmental variables including carbon, nitrogen and hydrogen concentration, bulk density, δ13C and the associated spring water analysed for hydrogen and oxygen isotopes. The age-depth profile of the recovered peat sequence covers the period from 9.6 to 0.3 kyr BP and is linear indicating that the conditions governing productivity and decay varied little over the Holocene. Using changes in carbon density, organic carbon content and its δ13C, cold dry periods of permafrost characterised by low density and impeded surface drainage were identified. The low δ18O and δD values of the spring water emanating around the peat deposit, down to −13.8 and −102‰ (VSMOW), respectively, with an inverse relationship between electrical conductivity and isotopic composition indicate precipitation under colder and drier conditions relative to the present day. In view of the current annual mean air temperature of 1 °C this suggests conditions in the past have been conducive to permafrost. Inferred periods of permafrost correspond to independently recognised cold periods in other Holocene records from across China at 8.6, 8.2–7.8, 5.6–4.2, 3.1 and 1.8–1.5 kyr BP. The transition to a cold dry climate appears to be more rapid than the subsequent recovery and cold dry periods at Hongyuan are of longer duration than equivalent cold dry periods over central and eastern China. Light–dark banding peat on a scale of 15–30 years from 9.6 to 5.5 kyr BP may indicate a strong influence of decadal oscillations possibly the Pacific Decadal Oscillation and a potential link between near simultaneous climatic changes in the northwest Pacific, ENSO, movement of the Intertropical Convergence Zone and the East Asian Monsoon.

Alkylated PAHs (APAHs) have been shown to be more toxic and persistent than their non-alkylated parent compounds. However, little is known about the extent of soil contamination by these pollutants. To help understand agricultural soil pollution by these compounds at a regional scale, a total of 18 methylated PAHs (MPAHs, a major class of APAHs) in 243 soil samples were analyzed. These soil samples were collected from 11 sites in the Yangtze River Delta (YRD) region, a representative fast developing area in China. The total concentration of MPAHs (∑18MPAHs) ranged from 5.5 to 696.2 ng/g dry soil, with methylnaphthalenes (M-NAPs) and methylphenanthrenes (M-PHEs) accounting for more than 70% of the compositional profile. Relatively high concentrations of ∑18MPAHs were found in Jiaxing and Huzhou areas of Zhejiang province, as well as on the border between the cities of Wuxi and Suzhou. Different MPAH groups showed dissimilar spatial distribution patterns. The spatial distribution of lower molecular weight MPAHs was related to agricultural straw burning and emissions/depositions from industrial activities, whereas that of higher molecular weight MPAHs was much more a function of the total organic carbon (TOC) content of soil. Although coal, biomass (crop straw and wood), and petroleum combustion were identified to be the major emission sources for most of the sampling sites, the areas with relatively severe pollution with ∑18MPAHs resulted from the localized hotspots of petroleum leakage. Isomeric MPAHs with methyl group substituted at 2- (β) position exhibited significantly higher concentrations than those substituted at 1- (α) position. Results of this work help to understand soil pollution by MPAHs, and are useful for designing effective strategies for pollution control so as to ensure food safety in areas with fast economic growth.

Mega-cities are large sources of air pollution on a regional base. Differences in energy structures, geographical settings and regional climate features lead to a large variety of air pollution sources from place to place. To understand the seasonality of air pollution sources is critical to precise emission inventories and a sound protection of human health. Based on a year-round dataset, the sources of PAHs in the air of Guangzhou were drawn by principal factor analysis (PCA) in combination with diagnostic ratios, and the seasonality of these sources were analyzed by PCA/MLR (multiple linear regressions) and discussed. The average total gaseous and particulate PAHs concentrations were 313 and 23.7 ng m(-3), respectively, with a higher concentration of vapor PAHs in summer and particulate PAHs in winter. In addition to vehicle exhaust, which contributed 69% of the particulate PAHs, coal combustion was still an important source and contributed 31% of the particulate PAHs. Relatively constant contribution from coal combustion was found through the year, implying that coal combustion in power plants was not a seasonally dependent source. Evaporation from contaminated ground may be an important source of light PAHs in summer, providing an average contribution of 68% to the total PAHs in this study. By comparing the PAH concentrations and meteorological parameters, we found that higher concentrations of particulate PAHs in winter resulted from enhanced vehicle exhaust under low temperature and accumulation of pollutants under decreased boundary layer, slower wind speed, and long-term dryness conditions. It is suggested that the typical subtropical monsoon climate in South China, cool and dry in winter, hot and humid in summer, may play a key role in controlling the source seasonality (by enhancing vehicle exhaust in winter, ground evaporation in summer), and hence the ambient concentrations of PAHs in the air.

Carbonaceous aerosols were studied at three background sites in south and southwest China. Hok Tsui in Hong Kong had the highest concentrations of carbonaceous aerosols (OC=8.7±4.5μg/m(3), EC=2.5±1.9μg/m(3)) among the three sites, and Jianfeng Mountains in Hainan Island (OC=5.8±2.6μg/m(3), EC=0.8±0.4μg/m(3)) and Tengchong mountain over the east edge of the Tibetan Plateau (OC=4.8±4.0μg/m(3), EC=0.5±0.4μg/m(3)) showed similar concentration levels. Distinct seasonal patterns with higher concentrations during the winter, and lower concentrations during the summertime were observed, which may be caused by the changes of the regional emissions, and monsoon effects. The industrial and vehicular emissions in East, Southeast and South China, and the regional open biomass burning in the Indo-Myanmar region of Asia were probably the two major potential sources for carbonaceous matters in this region.

To reduce operational costs and carbon footprints, it is highly desirable to achieve energy neutrality in municipal wastewater treatment plants (WWTPs). We reviewed more than 100 nitrification/deni...

In the present study, pot experiments were conducted to investigate the effects of foliar application of two silica (Si) sols on the alleviation of cadmium (Cd) toxicity in contaminated soil to rice. Results showed that the foliar application of Si sols significantly increased the dry weight of grains (without husk) and shoots in rice grown in Cd contaminated soil, whereas the Cd concentration in the grains and shoots decreased obviously. The total accumulation of Cd in rice grains also decreased with the application of both of the Si sols, but no significant effect was found on the Cd accumulation in the shoots. For the optimal effect, Si-sol-B should be foliar applied at the tillering-stage during rice growth. The mechanism of Si foliar application to alleviate the toxicity and accumulation of Cd in grains of rice may be related to the probable Cd sequestration in the shoot cell walls.