• Energy Research

The last decade witnessed a quantum increase in wind energy contribution to the U.S. renewable electricity mix. Although the overall environmental impact of wind energy is miniscule in comparison to fossil-fuel energy, the early stages of the wind energy life cycle have potential for a higher environmental impact. This study attempts to quantify the relative contribution of individual stages toward life cycle impacts by conducting a life cycle assessment with SimaPro® and the Impact 2002+ impact assessment method. A comparative analysis of individual stages at three locations, onshore, shallow-water, and deep-water, in Texas and the gulf coast indicates that material extraction/processing would be the dominant stage with an average impact contribution of 72% for onshore, 58% for shallow-water, and 82% for deep-water across the 15 midpoint impact categories. The payback times for CO2 and energy consumption range from 6 to 14 and 6 to 17 months, respectively, with onshore farms having shorter payback times. The greenhouse gas emissions (GHG) were in the range of 5–7 gCO2eq/kWh for the onshore location, 6–9 CO2eq/kWh for the shallow-water location, and 6–8 CO2eq/kWh for the deep-water location. A sensitivity analysis of the material extraction/processing stage to the electricity sourcing stage indicates that replacement of lignite coal with natural gas or wind would lead to marginal improvements in midpoint impact categories.

Electricity generation from coal is one of the leading contributors to greenhouse gas emissions in the U.S. and has adverse effects on the environment. Biomass from forest residue can be co-fired with coal to reduce the impact of fossil-fuel power plants on the environment. W. A. Parish power plant (WAP, Richmond, TX, USA) located in the greater Houston area is the largest coal and natural gas-based power generation facility in Texas and is the subject of the current study. A life cycle assessment (LCA) study was performed with SimaPro® and IMPACT 2002+ method, for the replacement of 5%, 10%, and 15% coal (energy-basis) with forest residue at the WAP power plant in Texas. Results from the LCA study indicate that life cycle air emissions of CO2, CO, SO2, PM2.5, NOX, and VOC could reduce by 13.5%, 6.4%, 9.5%, 9.2%, 11.6%, and 7.7% respectively when 15% of coal is replaced with forest residue. Potential life cycle impact decreased across 9 mid-point impact categories of, human/aquatic toxicity, respiratory organics/inorganics, global warming, non-renewable energy, mineral extraction, aquatic acidification, and terrestrial acidification/nitrification. The potential impact across damage/end-point categories of human health, ecosystem quality, climate change, and resources reduced by 8.7%, 3.8%, 13.2%, and 14.8% respectively for 15% co-firing ratio.

Houston, the fourth largest metropolis in the US, currently experiences severe air pollution. Major pollutants, such as VOCs, CO, NOx, PM, SOx, CH4, and CO2, are released from the transportation fleets. To decrease fossil fuel use and greenhouse gas emissions from fleet vehicles, more and more biodiesel is used in vehicles in the Houston metropolis. The GREET model was used for simulating the fuel cycle emissions of diesel vehicles using different biodiesel blends in Houston. The fuels examined were diesel-biodiesel blends of B0, B5, B20, B50, B80, and B100. The energy and water use and emissions from vehicles fueled with the blends were investigated. The study shows that the reductions in GHG emissions are significant at the Well-to-Pump stage, and all the emissions, except GHGs and NOx, reduce at the Pump-to-Wheel stage. The overall Well-to-Wheel analysis shows that biodiesel is beneficial for both passenger cars and heavy duty trucks. However, the benefits are more pronounced for passenger cars compared to heavy duty vehicles. When 50% of diesel passenger cars and HDDTs are switched to B20 in the Greater Houston area in 2025, the daily GHG emissions will be reduced by 2.0 and 712.1 CO2-equivalent tonnes, respectively.

The Houston-Dallas (I-45) corridor is the busiest route among 18 traffic corridors in Texas, USA. The expected population growth and the surge in passenger mobility may result in a significant impact on the regional environment. This study uses a life cycle framework to predict and evaluate the net changes of environmental impact associated with the potential development of a high-speed rail (HSR) System along the I-45 corridor through its life cycle. The environmental impact is estimated in terms of CO2 and greenhouse gas (GHG) emissions per vehicle/passenger-kilometers traveled (V/PKT) using life cycle assessment. The analyses are performed referring to the Ecoinvent 3.4 inventory database through the phases: material extraction and processing, infrastructure construction, vehicle manufacturing, system operation, and end of life. The environmental benefit is evaluated by comparing the potential development of the HSR system with those of the existing transportation systems. The vehicle component, especially operation and maintenance of vehicles, is the primary contributor to the total global warming potential with about 93% of the life cycle GHG emissions. For the infrastructure component, 56.76% of GHG emissions result from the material extraction and processing phase (23.75 kgCO2eq/VKT). Various life cycle emissions of HSR except PM are significantly lower than for passenger cars.

Abstract The interest in the use of non-noble metal catalysis is quite relevant to biomass processing due to costs, environmental concerns and the substantial scale of these operations. The aim of this article is to cover all aspects of the use of iron based catalysts in various biomass processing applications, especially focusing on the developments in the last five years. The appeal of metallic iron and its compounds in catalysis as well as the diversity of the type of transformations are discussed in the introduction sections of this review. The recent advances in the use of iron or its compounds in biomass pretreatment, saccharification, liquefaction and pyrolysis are reviewed as major topics in the review article. In addition, the use iron based catalysts in processing biomass derived small molecules to fuel; polymer and chemical feedstocks are also discussed in the article.

AbstractSolid absorbents made with polyethylenimine (PEI), which is loaded on different porous substrates, are promising for postcombustion carbon dioxide capture. Herein, theoretical studies of polyamine applications, including PEI for carbon dioxide capture, are reviewed and the development of experimental work on carbon dioxide capture by using PEI summarized. The mechanisms of carbon dioxide capture are discussed at different reaction sites of the polyamines, such as primary, secondary, and tertiary amine groups. Experimental achievements in carbon dioxide capture are investigated by the incorporation of PEI with different support materials, such as mesoporous silica; nanotubes; membranes; and other materials, such as alumina, zeolite, resin, metal–organic frameworks, and glass fibers, through impregnation, grafting, and synthesis. The excellent carbon dioxide capture capacity and great stability of PEI‐impregnated nanomaterials highlight PEI as one of the greatest candidates for carbon dioxide capture from flue gas or air.

AbstractA comprehensive computational fluid dynamic (CFD) model of CEES‐developed polyethylenimine impregnated protonated titanate nanotubes (PEI‐PTNTs) was developed using the Multiphase Flow with Interphase eXchanges (MFiX) package to evaluate the performance of the PEI‐PTNTs in a 1‐MW pilot‐scale carbon capture reactor developed by the National Energy Technology Laboratory (NETL). In this CFD model, the momentum, continuity, and energy transport equations were integrated with the first‐order chemistry model for chemical kinetics of heterogeneous reactions to predict the adsorption of CO2 onto amine‐based sorbent particles and the reactor temperature. Based on the amount of the CO2 adsorption obtained in the small‐scale experiment, the coefficients for the chemical reaction equations of PEI‐PTNTs are adjusted. The adjusted PEI‐PTNTs model is applied to the simplified numerical model of 1‐MW pilot‐scale carbon capture system, which is calibrated through the comparison between our simulation results and the results provided by NETL. This calibrated CFD model is used for selecting the optimized flow rate of the gas phase. Our study shows that the optimized gas flow rate to absorb 100% CO2 without loss is 1.5 kg/s, but if higher absorption rate is preferable despite some loss of CO2 absorption in the reactor, a higher flow rate than 1.5 kg/s can be selected.

In the Greater Houston Area, mobile sources contribute to the highest share of NOx emissions and the second-highest share of VOC emissions. The Houston METRO system that operates public buses is a key element of Houston’s infrastructures that could reduce the emissions of criteria air pollutants (CAPs) and greenhouse gases (GHGs), thus improving the regional air quality. We used life-cycle assessment (LCA) and life-cycle cost analysis (LCCA) to evaluate the environmental sustainability of electric buses and compared it to diesel buses. The LCA simulations demonstrate that life-cycle emissions of GHGs, VOCs, NOx, and black carbon associated with electric buses are lower than conventional diesel and diesel hybrid buses. These lower emissions are mainly attributed to the fact that natural gas currently makes up about 50% of the fuel used to generate electricity in Texas. However, other emissions such as PM10, PM2.5, SOx, N2O, and primary organic carbon are higher and would lead to the higher environmental cost of electric buses than diesel buses. The environmental cost analysis estimates that the annual cost savings of electric buses in 2040 would significantly support the long-term goal of environmental sustainability in the Greater Houston area.