• Energy Research

Applied energy 378(Part A), 124820 (2025). doi:10.1016/j.apenergy.2024.124820 Published by Elsevier Science, Amsterdam [u.a.]

Lithium-ion batteries are fuelling the advancing renewable-energy based world. At the core of transformational developments in battery design, modelling and management is data. In this work, the datasets associated with lithium batteries in the public domain are summarised. We review the data by mode of experimental testing, giving particular attention to test variables and data provided. Alongside highlighted tools and platforms, over 30 datasets are reviewed.

AbstractBattery characterization and prognosis are essential for analyzing underlying electrochemical mechanisms and ensuring safe operation, especially with the assistance of superior data‐driven artificial intelligence systems. This review provides a unique perspective on recent progress in data‐driven battery characterization and prognosis methods. First, recent informative image characterization and impedance spectrum as well as high‐throughput screening approaches on revealing battery electrochemical mechanisms at multiple scales are summarized. Thereafter, battery prognosis tasks and strategies are described, with the comparison of various physics‐informed modeling strategies. Considering unlocking mechanisms from tremendous battery data, the dominant role of physics‐informed interpretable learning in accelerating energy device development is presented. Finally, challenges and prospects on data‐driven characterization and prognosis are discussed toward accelerating energy device development with much‐enhanced electrochemical transparency and generalization. This review is hoped to supply new ideas and inspirations to the next‐generation battery development.

Lithium-ion batteries have found applications in many parts of our daily lives. Predicting their remaining useful life (RUL) is thus essential for management and prognostics. Most approaches look at early life prediction of RUL in the context of designing charging profiles or optimising cell design. While critical, said approaches are not directly applicable to the regular testing of cells used in applications. This article focuses on a class of models called ‘one-cycle’ models which are suitable for this task and characterized by versatility (in terms of online prediction frameworks and model combinations), prediction from limited input, and cells’ history independence. Our contribution is fourfold. First, we show the wider deployability of the so-called one-cycle model for a different type of battery data, thus confirming its wider scope of use. Second, reflecting on how prediction models can be leveraged within battery management cloud solutions, we propose a universal Exponential-smoothing (e-forgetting) mechanism that leverages cycle-to-cycle prediction updates to reduce prediction variance. Third, we use this new model as a second-life assessment tool by proposing a knee region classifier. Last, using model ensembling, we build a “model of models”. We show that it outperforms each underpinning model (from in-cycle variability, cycle-to-cycle variability, and empirical models). This ‘ensembling’ strategy allows coupling explainable and black-box methods, thus giving the user extra control over the final model.

High-performance batteries greatly benefit from accurate, early predictions of future capacity loss, to advance the management of the battery and sustain desirable application-specific performance characteristics for as long as possible. Li-ion cells exhibit a slow capacity degradation up to a knee-point, after which the degradation accelerates rapidly until the cell’s End-of-Life. Using capacity degradation data, we propose a robust method to identify the knee-point within capacity fade curves. In a new approach to knee research, we propose the concept ‘knee-onset’, marking the beginning of the nonlinear degradation, and provide a simple and robust identification mechanism for it. We link cycle life, knee-point and knee-onset, where predicting/identifying one promptly reveals the others. On data featuring continuous high C-rate cycling (1C–8C), we show that, on average, the knee-point occurs at 95% capacity under these conditions and the knee-onset at 97.1% capacity, with knee and its onset on average 108 cycles apart.After the critical identification step, we employ machine learning (ML) techniques for early prediction of the knee-point and knee-onset. Our models predict knee-point and knee-onset quantitatively with 9.4% error using only information from the first 50 cycles of the cells’ life. Our models use the knee-point predictions to classify the cells’ expected cycle lives as short, medium or long with 88–90% accuracy using only information from the first 3–5 cycles. Our accuracy levels are on par with existing literature for End-of-Life prediction (requiring information from 100-cycles), nonetheless, we address the more complex problem of knee prediction.All estimations are enriched with confidence/credibility metrics. The uncertainty regarding the ML model’s estimations is quantified through prediction intervals. These yield risk-criteria insurers and manufacturers of energy storage applications can use for battery warranties. Our classification model provides a tool for cell manufacturers to speed up the validation of cell production techniques.

Feature-based machine learning models for capacity and internal resistance (IR) curve prediction have been researched extensively in literature due to their high accuracy and generalization power. Most such models work within the high frequency of data availability regime, e.g., voltage response recorded every 1–4 s. Outside premium fee cloud monitoring solutions, data may be recorded once every 3, 5 or 10 min. In this low-data regime, there are little to no models available. This literature gap is addressed here via a novel methodology, underpinned by strong mathematical guarantees, called ‘path signature’. This work presents a feature-based predictive model for capacity fade and IR rise curves from only constant-current (CC) discharge voltage corresponding to the first 100 cycles. Included is a comprehensive feature analysis for the model via a relevance, redundancy, and complementarity feature trade-off mechanism. The ability to predict from subsampled ‘CC voltage at discharge’ data is investigated using different time steps ranging from 4 s to 4 min. It was discovered that voltage measurements taken at the end of every 4 min are enough to generate features for curve prediction with End of Life (EOL) and its corresponding IR values predicted with a mean absolute percentage error (MAPE) of approximately 13.2% and 2.1%, respectively. Our model under higher frequency (4 s) produces an improved accuracy with EOL predicted with an MAPE of 10%. Full implementation code publicly available.

The degradation of lithium-ion cells with respect to increases of internal resistance (IR) has negative implications for rapid charging protocols, thermal management and power output of cells. Despite this, IR receives much less attention than capacity degradation in Li-ion cell research. Building on recent developments on ‘knee’ identification for capacity degradation curves, we propose the new concepts of ‘elbow-point’ and ‘elbow-onset’ for IR rise curves, and a robust identification algorithm for those variables. We report on the relations between capacity’s knees, IR’s elbows and end of life for the large dataset of the study. We enhance our discussion with two applications. We use neural network techniques to build independent state of health capacity and IR predictor models achieving a mean absolute percentage error (MAPE) of 0.4% and 1.6%, respectively, and an overall root mean squared error below 0.0061. A relevance vector machine, using the first 50 cycles of life data, is employed for the early prediction of elbow-points and elbow-onsets achieving a MAPE of 11.5% and 14.0%, respectively.

Lithium-ion batteries can last many years but sometimes exhibit rapid, nonlinear degradation that severely limits battery lifetime. In this work, we review prior work on “knees” in lithium-ion battery aging trajectories. We first review definitions for knees and three classes of “internal state trajectories” (termed snowball, hidden, and threshold trajectories) that can cause a knee. We then discuss six knee “pathways”, including lithium plating, electrode saturation, resistance growth, electrolyte and additive depletion, percolation-limited connectivity, and mechanical deformation—some of which have internal state trajectories with signals that are electrochemically undetectable. We also identify key design and usage sensitivities for knees. Finally, we discuss challenges and opportunities for knee modeling and prediction. Our findings illustrate the complexity and subtlety of lithium-ion battery degradation and can aid both academic and industrial efforts to improve battery lifetime.