• Energy Research

Abstract Phase change materials (PCMs) utilized for thermal energy storage applications are verified to be a promising technology due to their larger benefits over other heat storage techniques. Apart from the advantageous thermophysical properties of PCM, the effective utilization of PCM depends on its life span. Moreover, PCMs which are utilized for different solar thermal energy storage applications are required longer thermal and chemical stability for the extended performance of a system. This review shows the in-depth details on thermal stability and reliability of different PCMs such as organic, inorganic, eutectics, and composites materials for heat storage applications. Different methods for measuring the thermophysical properties along with the classification of PCMs based on applications and temperature ranges have been discussed. This paper also covers the selection criteria and commercial viability of PCMs for different domestic and industrial applications. In addition to this, the effect of thermal cycle testing on the properties of different organic, inorganic, eutectic, and composite PCMs has been summarized. The present article can be highly useful for researchers and practice engineers in the areas related to thermal energy storage applications.

Dye sensitized solar cells (DSSCs) are widely studied for the safe and reliable energy supply. Due to its low fabrication cost, eco-friendly production and competitive efficiency, this is the promising technology. The components of DSSC which combine to form a photo conversion device are the conducting substrate, dye, photoanode, catalyst and electrolyte. Each component has its own importance but among them photoanode is probability the main component which determines the energy conversion efficiency. Various photoanode materials have been trialled to date. Among them Zn and TiO2 are widely recognized, researched and investigated. In this review attempt will be made to examine the strategies to improve the efficiency of TiO2 photoanode. This review is dedicated to the TiO2 photoanode, its properties, issues related to TiO2 photoanode, various improvement approaches, fabrication methods successfully trialled so far followed by market potential of the DSSC technology, conclusion and recommendations.

Sustainable supplier selection and order allocation (SSSOA) is paramount to sustainable supply chain management. It is a complex multi-dimensional decision-making process augmented with the triple bottom line of sustainability. This research presents a multi-phase decision framework to address a SSSOA problem for the multi-echelon renewable energy equipment (Solar PV Panels) supply chain. The framework comprises of fuzzy Multi-Criteria Decision-Making techniques augmented with fuzzy multi-objective mixed-integer non-linear programming mathematical model. The various economic, environmental, and social objectives were optimized for a multi-period, multi-modal transportation network of the supply chain. The results show that among the various sustainable criteria selected in this study, product cost, environmental management system, and health and safety rights of employees are the most important for decision-makers. The results of the mathematical model highlighted the impact of multimodal transportation on overall cost, time, and environmental impact for all periods. An analysis of results revealed that transfer cost and customer clearance cost contribute significantly towards overall cost. Furthermore, defect rate was also observed to play a critical role in supplier selection and order allocation.

Low thermal conductivity is the major obstacle for the wide range utilization of phase change materials (PCMs), especially organic PCMs, for most practical applications in thermal engineering. This study investigates the potential of enhancing the charging and discharging rates of organic PCM (RT44HC) by introducing polyethylene glycol (PEG) and activated carbon macroparticles (ACMPs). Different concentrations of PEG and ACMPs ranging from 0.3 wt% to 2 wt% were tested separately. The optimized concentrations found were used as dual reinforcements to attain the highest possible thermal conductivity. The specimens were tested for a complete charging–discharging cycle using an improvised thermal apparatus. Use of ACMP alone resulted in a minimal reduction in complete charging–discharging time due to the settlement of ACMPs at the bottom after 2–3 heating–cooling cycles. However, the addition of PEG with ACMPs exhibited a reduction in charging–discharging time due to the formation of a stable dispersion. PEG served as a stabilizing agent for ACMPs. The lowest charging–discharging time of 180 min was exhibited by specimens containing 1 wt% PEG and 0.5 wt% ACMPs which is 25% lower compared to bare PCM.

Production of hydrogen by means of renewable energy sources is a way to eliminate dependency of the system on the electric grid. This study is based on a technique involving coupling of an oxyhydrogen (HHO) electrolyzer with solar PV to produce clean HHO gas as a fuel. One of objectives of this study was to develop a strategy to make the electrolyzer independent of other energy sources and work as a standalone system based on solar PV only. A DC-DC buck convertor is used with an algorithm that can track the maximum power and can be fed to the electrolyzer by PV while addressing its intermittency. The electrolyzer is considered to be an electrical load that is connected to solar PV by means of a DC-DC convertor. An algorithm is designed for this DC-DC convertor that allows maximization and control of power transferred from solar PV to the electrolyzer to produce the maximum HHO gas. This convertor is also responsible for operating the electrolyzer in its optimum operating region to avoid overheating. The DC-DC converter has been tested under simulated indoor conditions and uncontrolled outdoor conditions. Analysis of this DC-DC convertor based on maximum power tracking algorithm showed 94% efficiency.

The ever-increasing water stress and availability of fresh drinking water are becoming a major challenge in rural and urban communities. The current high-end and large-scale technologies are becoming way more expensive and not friendly to the environment. In this regard, solar still is becoming a prominent and promising future technology due to its environment-friendly nature, less maintenance and operational costs, and simple design. The technological challenge regarding solar still is its low distillate yield. In this study, an attempt has been made to investigate the effect of tin oxide (SnO2) on the absorption surface of solar still towards improvement in sunlight absorption, which would lead to high distillate production rates. Various concentrations of SnO2, i.e., 0.5wt%, 1 wt%, 3 wt%, 5 wt%, 7 wt%, 10 wt%, 15 wt%, and 20 wt%, have been mixed in black and applied on the absorber plate to further optimize the suitable concentration. The experiments have been performed in both indoor (simulated) and outdoor conditions. An increase in surface temperature of absorber plate has been observed with increasing concentration of SnO2 under both the indoor and outdoor conditions, which is due to high solar spectrum absorption properties of SnO2 in the ultraviolet (UV) and near to far-infrared (IR) regions. The highest surface temperature of 101.61°C has been observed for specimens containing 15 wt% SnO2 in black paint under indoor conditions at 1000W/m2 irradiation levels, which is 53.67% higher compared to bare aluminum plate and 16.91% higher compared to only black paint coated aluminum plate. On the other hand, the maximum temperature of 74.96°C has been recorded for the identical specimens containing 15 wt% SnO2 under uncontrolled outdoor conditions. The recorded temperature is 47.96% higher than the bare aluminum plate and 14.88% higher than the black paint-coated aluminum plate. The difference of maximum temperatures under indoor and outdoor conditions is due to uncontrolled outdoor conditions and convective losses.

Solar light absorber surface is probably one of the most important components in solar still that dictates the distillate yield. In this work, a systematic study is conducted to investigate the effect of particle size and concentration of titanium oxide (TiO2) in black paint in increasing the solar still absorber surface temperature. The various available particle sizes, i.e., 20, 150, and 400 nm, are mixed in black paint with varying concentrations and are applied on the absorber plate. XRD is used for phase identification of as-received powders. UV-Vis spectroscopy is used to examine light absorption properties. Finally, extensive indoor testing (using an improvised solar simulator) and outdoor testing are conducted to optimize the concentration. An increase in surface temperature is observed with the introduction of TiO2 nanoparticles in black paint. Furthermore, the increase in particle size leads to an increase in temperature. The highest surface temperatures of 104.86°C, 105.42°C, and 106.32°C are recorded for specimens with particles sizes 20 nm (at 15 wt% concentration), 150 nm (at 10 wt% concentration), and 400 nm (at 7 wt% concentration), respectively. Furthermore, the highest temperature of 69.69°C is recorded for TiO2-400 nm specimens under outdoor conditions, which is 15.97% higher than that of the bare aluminum plate. The increase in surface temperature may be due to high UV absorption. Moreover, an increase in particle size leads to high light-scattering ability, further improving the light-harvesting ability.