• Energy Research

Poultry litter (PL) gasification was experimentally investigated using a lab-scale bubbling fluidised bed reactor. Characterisation of the gasification process was performed in terms of yields and compositions of both gas and tar, lower calorific value (LCV) of the product gas, cold gas efficiency (CGE) and carbon conversion efficiency (CCE). Experiments were carried out at different temperatures (700-750 °C) and equivalence ratios (ERs). The effect of gasifier temperature at a constant ER of 0.21 shows that an increase in temperature improved the gasification process performance whilst the total tar content decreased, implying that higher temperature enhances the conversion of biomass to product gas. The total gas yield increased from 0.93 to 1.24 N2-free m3/kgfeedstock-daf, LCV increased from 3.38 MJ/m3 to 4.2 MJ/m3, while the tar content was reduced by 24% (5.6-4.25 gtar/kgfeedstock-daf). The detailed analyses of tar compositions reveal that styrene and xylenes were the most abundant compounds in the secondary tar group. Moreover, naphthalene and 1, 2-methyl naphthalene were the dominant compounds found in tertiary polycyclic aromatic hydrocarbons (PAH) and alkyl tertiary groups, respectively. Furthermore, at the highest tested temperature of 750 °C and ER of 0.25, bed agglomeration took place causing the shutdown of the gasifier. The defluidisation of the bed occurred due to the high ash content of PL comprising of low melting temperature alkali compounds. The results obtained from this study showed the performance and potential challenges associated with gasifying PL in a fluidised bed reactor for the combined heat and power production at farm level.

The present study explored a thermochemical treatment method as an alternative approach to process animal feedlot (poultry litter). Fast pyrolysis of poultry litter experiments was conducted using a Pyroprobe 5200 reactor in the temperature range of 400-600 °C. The influence of reactor temperature on the yield of pyrolytic gases, condensate (bio-oil) and biochar yield was reported along with the mass balance. The biochar yield decreased consistently with an increase in temperature (from ~62 wt.% at 400 °C to ~ 40 wt.% at 600 °C), whereas the maximum bio-oil yield 23.2 wt.% was reported at 600 °C. The evolved pyrolytic gases were dominated by CO and CO2 and have shown an increasing trend with the temperature. Evolved gases were measured by a micro-gas Chromatograph. The yield of the liquid fraction (bio-oil) and biochar were quantified for the mass balance analysis. The yield of liquid and biochar are in agreement with previous work. Green Open Access added to TU Delft Institutional Repository 'You share, we take care!' - Taverne project https://www.openaccess.nl/en/you-share-we-take-care Otherwise as indicated in the copyright section: the publisher is the copyright holder of this work and the author uses the Dutch legislation to make this work public. Large Scale Energy Storage

Qualitative and quantitative measurements of tar from poultry litter gasification in an air-blown fluidised bed.

Abstract Purpose With its substantial CO2eq emissions, the agricultural sector is a significant greenhouse gas (GHG) emitter. Animal manure alone contributes 16% of the total agricultural emissions. With a rapidly increasing demand for animal-based protein, animal wastes are expected to rise if sustainable manure management practices are not implemented. Manures have the potential to be treated to generate valuable products (biofertiliser and biocrude) or feedstock for energy production. Thermochemical conversion technologies such as pyrolysis, combustion, supercritical gasification (SCWG), etc., have demonstrated their potential in manure management and valorisation. This study provides a broader overview of these technologies and envisages future manure valorisation trends. Methods The paper presents a state-of-the-art review of manure valorisation. Characterisation of manure, modelling and optimisation of thermochemical conversion technologies along with life cycle anaalysis (LCA) are also reviewed. Results The literature review highlighted that the thermochemical conversion technologies can generate bio-oils, syngas, H2, biofuels, heat, and biochar as carbon-free fertiliser. The reported calorific value of the produced bio-oil was in the range of 26 MJ/kg to 32 MJ/kg. However, thermochemical conversion technologies are yet to be commercialised. The major challenges associated with the scale-up of manure derived feedstocks are relatively high moisture and ash content, lower calorific value and higher concentration of impurities (N, Cl, and S). LCA studies conclude that gasification presents a sustainable option for manure valorisation as it is economical with modest environmental threats. Significance of Study This review briefly states the current challenges faced in manure management and presents the case for a sustainable valorisation of animal manures using thermochemical technologies. The economic, environmental and societal advantages of these technologies are presented in order to promote the scientific and industrial development of the subject in the academic and research community. Conclusions Thermochemical conversion technologies are promising for manure valorisation for energy and nutrient recovery. However, their commercialisation viability needs wide-ranging evaluations such as techno-economics, life-cycle analysis, technology take-up and identification of stakeholders. There should be clear-cut policies to support such technologies. It should be advocated amongst communities and industries, which necessitates marketing by the governments to secure a clean energy future for the planet. Graphical Abstract

Fly ash from a poultry litter gasification process and the potential of application of the fly ash as a fertiliser in line with the poultry litter protocol is investigated. The fines collected in the cyclone are mainly formed by ash which comprises between 70-83 wt.% of the fines on a dry basis, and to a lesser extent of carbon (elutriated char). The effect of the gasification operating conditions on the concentration of ash forming elements (inorganic compounds) in the fly ash, are discussed. In addition, the enrichment factor which defines the volatility, has been used and fly ash elements were categorised as Class I (non-volatile), Class II (semi-volatile with the possible occurrence of condensation) and Class III (highly volatile elements). Inorganic elements in fly ashes from poultry litter gasification experiments are categorised as Class I: Ca, Co, Cu, Fe, Hg, K, Mg, Mn, Na, Ni, P, Class II: Cd, Cr, Mo and Class III: Pb and Se. It has been found that the fly ash from the poultry litter gasification exceeds the upper acceptable limit set by Poultry Litter Protocol to be used as a fertiliser in agriculture systems.