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Abstract The absorption refrigeration system driven by low grade heat sources, especially the waste heat sources, becomes more and more attractive in recent decades. However, most traditional absorption systems cannot achieve a high utilization rate of the waste heat with limited heat capacity. These systems are usually designed to obtain heat in the generator, which means that the waste heat sources cannot be utilized to the temperature lower than the generator temperature. This paper proposed a new structure heated by heat conduction oil in the generator and electric heating rings around the stripping section. This structure can simulate the temperature-distributed heat sources when the electric heating rings work. It can also simulate a traditional generator when the electric heating rings do not work. Influences of different heat distributions are analyzed in detail in this paper. The results show that the heat sources utilization rate will increase with the increase of the heat in the stripping section, while the coefficient of performance will be negatively affected by the increasing heat in the stripping section. By optimizing the heating structure, the coefficient of performance can be similar to that of a traditional system when the heat is just added in the middle and lower part of stripping section. The optimum utilization rate of heat sources in this test model can reach 1.8 times to that of a traditional system. Under this heating model, the lowest temperature required in the heating section is 82 °C when the heat conduction oil inlet temperature is 169 °C. It is much lower than the temperature inside the generator, which is 137.3 °C.

Phytoplankton communities are crucial components of aquatic ecosystems, and since they are highly interactive, they always form complex networks. Yet, our understanding of how interactive phytoplankton networks vary through time under changing environmental conditions is limited. Using a 29-year (339 months) long-term dataset on Lake Taihu, China, we constructed a temporal network comprising monthly sub-networks using "extended Local Similarity Analysis" and assessed how eutrophication, climate change, and restoration efforts influenced the temporal dynamics of network complexity and stability. The network architecture of phytoplankton showed strong dynamic changes with varying environments. Our results revealed cascading effects of eutrophication and climate change on phytoplankton network stability via changes in network complexity. The network stability of phytoplankton increased with average degree, modularity, and nestedness and decreased with connectance. Eutrophication (increasing nitrogen) stabilized the phytoplankton network, mainly by increasing its average degree, while climate change, i.e., warming and decreasing wind speed enhanced its stability by increasing the cohesion of phytoplankton communities directly and by decreasing the connectance of network indirectly. A remarkable shift and a major decrease in the temporal dynamics of phytoplankton network complexity (average degree, nestedness) and stability (robustness, persistence) were detected after 2007 when numerous eutrophication mitigation efforts (not all successful) were implemented, leading to simplified phytoplankton networks and reduced stability. Our findings provide new insights into the organization of phytoplankton networks under eutrophication (or re-oligotrophication) and climate change in subtropical shallow lakes.

Xuanwei City (formerly known as Xuanwei County) locates in the northeastern of Yunnan Province and is rich in coal, iron, copper and other mines, especially the smoky (bituminous) coal. Unfortunately, the lung cancer morbidity and mortality rates in this region are among China's highest, with a clear upward trend from the mid-1970s to mid-2000s. In 2004-2005, the crude death rate of lung cancer was 91.3 per 100,000 in the whole Xuanwei City, while that for Laibin Town in this city was 241.14 per 100,000. The epidemiologic distribution (clustering patterns by population, time, and space) of lung cancer in Xuanwei has some special features, e.g., high incidence in rural areas, high incidence in females, and an early age peak in lung cancer deaths. The main factor that associates with a high rate of lung cancer incidence was found to be indoor air pollution caused by the indoor burning of smoky coal. To a certain extent, genetic defects are also associated with the high incidence of lung cancer in Xuanwei. Taken together, lung cancer in this smoky coal combustion region is a unique model for environmental factor-related human cancer, and the current studies indicate that abandoning the use of smoky coal is the key to diminish lung cancer morbidity and mortality.

Abstract Stable aqueous TiO2 nanofluids with different particle (agglomerate) sizes and concentrations are formulated and measured for their static thermal conductivity and rheological behaviour. The nanofluids are then measured for their heat transfer and flow behaviour upon flowing upward through a vertical pipe in both the laminar and turbulent flow regimes. Addition of nanoparticles into the base liquid enhances the thermal conduction and the enhancement increases with increasing particle concentration and decreasing particle (agglomerate) size. Rheological measurements show that the shear viscosity of nanofluids decreases first with increasing shear rate (the shear thinning behaviour), and then approaches a constant at a shear rate greater than ∼100 s−1. The constant viscosity increases with increasing particle (agglomerate) size and particle concentration. Given the flow Reynolds number and particle size, the convective heat transfer coefficient increases with nanoparticle concentration in both the laminar and turbulent flow regimes and the effect of particle concentration seems to be more considerable in the turbulent flow regime. Given the particle concentration and flow Reynolds number, the convective heat transfer coefficient does not seem to be sensitive to the average particle size under the conditions of this work. The results also show that the pressure drop of the nanofluid flows is very close to that of the base liquid flows for a given Reynolds number.

Abstract In the present study, Ru modified hierarchical zeolites xRu-MZSM were developed for cellulose fast pyrolysis. Comprehensive catalyst characterizations including XRD, XPS, N2 adsorption-desorption, Py-IR and so on, were performed to unveil the essential structural properties. The chemical modification and Ru decoration remarkably regulated the distribution of Bronsted/Lewis acid sites. The presence of RuOx species would supply abundant strong Lewis acid sites for participating catalytic cracking, dehydration, decarbonylation, decarboxylation, cyclization, aromatization, etc., in cooperation with Bronsted acid sites. In-situ generated active Ru0 centers during cellulose pyrolysis might facilitate the proceeding of deoxygenation, hydride transfer, and dehydrogenation. Among the as-prepared catalysts screened, 2Ru-MZSM was much more efficient in aromatics production from cellulose fast pyrolysis compared to parent ZSM, wherein the total aromatics yield achieved 16.8% at temperature of 650 °C and heating rate of 10 °C/ms with corresponding E value as low as 23.40 kJ/mol. Also, plausible reaction mechanism for xRu-MZSM involved cellulose fast pyrolysis was proposed in detail.

Arbuscular mycorrhizal (AM) fungi play key roles in plant nutrition and plant productivity. AM fungal responses to either plant identity or fertilization have been investigated. However, the interactive effects of different plant species and fertilizer types on these symbiotic fungi remain poorly understood. We evaluated the effects of the factorial combinations of plant identity (grasses Avena sativa and Elymus nutans and legume Vicia sativa) and fertilization (urea and sheep manure) on AM fungi following 2-year monocultures in a sown pasture field study. AM fungal extraradical hyphal density was significantly higher in E. nutans than that in A. sativa and V. sativa in the unfertilized control and was significantly increased by urea and manure in A. sativa and by manure only in E. nutans, but not by either fertilizers in V. sativa. AM fungal spore density was not significantly affected by plant identity or fertilization. Forty-eight operational taxonomic units (OTUs) of AM fungi were obtained through 454 pyrosequencing of 18S rDNA. The OTU richness and Shannon diversity index of AM fungi were significantly higher in E. nutans than those in V. sativa and/or A. sativa, but not significantly affected by any fertilizer in all of the three plant species. AM fungal community composition was significantly structured directly by plant identity only and indirectly by both urea addition and plant identity through soil total nitrogen content. Our findings highlight that plant identity has stronger influence than fertilization on belowground AM fungal community in this converted pastureland from an alpine meadow.

The world's largest alpine pastures are found on the Tibetan Plateau, where considerable climate changes and human impacts have been experienced. Identifying their contributions to terrestrial productivity is essential if we are to adapt to, or mitigate the effects of, climate change. In this work, we begin by showing how the current warming and wetting of the climate over the last three decades has favored plant growth, as consistently captured by satellite observations and 15 models. However, the interactions between climate factors explain less of the variation in greenness observed by satellites after the 2000s, implying non-climatic influences. Next, we show that there is a significant negative impact of livestock grazing on pasture greenness, especially in peak summer. Official statistics across 72 counties verify these negative impacts, especially in poorer pastures with a higher density of grazing livestock. The variation in grazing density has a stronger negative effect on vegetation growth during the early part of the growing season after the 2000s, as compared with that before the 2000s. We found a compensatory effect of grazing and climate on alpine grassland growth, and the grazing regulates the response of vegetation greenness to climate change by modulating the dependency of vegetation growth on temperature. Thus, we suggest there is a weakening influence of climate on the greenness of alpine pastures, largely due to a strengthening influence of management, which should be considered by both the scientific community and policymakers.

Abstract Comprehensive information about the concentrations, distribution, and modes of occurrence of elements in coal are important from the environmental and economic point of view. Although a great number of previous studies have investigated the geology of coalbed methane in the Qinshui Basin, only a few studies focused on the inorganic constituents in coal. More specifically, the mode of occurrences of valuable element Li in the No. 3 Coal is still unclear, although Li was found enriched. In this study, we present mineral characteristics, as well as multi-element data on the Permian No. 3 Coal from the Sucun and Gaohe Mines, Changzhi City, southern Qinshui Basin. The studied coals are characterized by low- to medium-ash yield (Ad = 5.72%- 28.18%, 12.34% on average), low volatile matter yield (Vdaf = 8.49–15.17%, 10.96% on average), suggesting a low volatile bituminous coal to semi-anthracite. NH4-illite and kaolinite are the main minerals in the coals detected by XRD, and trace amount of minerals calcite, dolomite, quartz, pyrite and diaspore can also be found. The major elements of the studied No. 3 coals are dominated by SiO2 and Al2O3, ranging 2.49–16.45 wt% and 2.13–12.9 wt% (on a whole-coal basis), respectively. Li is enriched in the No. 3 coals (5

Converting woody biomass to bioethanol might be more affordable, environmentally friendly, and efficient for making biofuel commercially feasible, but it would still need a significant optimization process and expand pilot-scale research. A combination of commercial low enzymes loading at 10 FPU/g glucan and compound additives utilizing Tween 80, PEG8000 and sophorolipid applied from lab-scale to pilot-scale have been studied in this work at economically viable dosages for enhancing bioethanol production. In lab-scale saccharification and fermentation, pretreated poplar at a high solid loading of 20% yielded the highest ethanol titers of 30.96 g/L and theoretical ethanol yield of 92.79%. Additionally, pilot-scale operation was used to investigate the bioethanol amplification, a final volume of 33 m3 which yielded the greatest ethanol amount of 599.6 kg from poplar wood while gaining on-site value-added production of hemicellulosic and cellobiose liquor 1122 kg and lignin residues 2292 kg.

Isolated cobalt atoms with CoN4configuration are decorated into a multichannel carbon matrix for efficient electrocatalytic oxygen reduction reaction.