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Forest soil acidification caused by acid deposition is a serious threat to the forest ecosystem. To investigate the liming effects of biomass ash (BA) and alkaline slag (AS) on the acidic topsoil and subsoil, a three-year field experiment under artificial Masson pine was conducted at Langxi, Anhui province in Southern China. The surface application of BA and AS significantly increased the soil pH, and thus decreased exchangeable acidity and active Al in the topsoil. Soil exchangeable Ca2+ and Mg2+ in topsoil were significantly increased by the surface application of BA and AS, while an increase in soil exchangeable K+ was only observed in BA treatments. The soil acidity and active Al in subsoil were decreased by the surface application of AS. Compared with the control, soluble monomeric and exchangeable Al in the subsoil was decreased by 38.0% and 29.4% after 3 years of AS surface application. There was a minimal effect on soluble monomeric and exchangeable Al after the application of BA. The soil exchangeable Ca2+ and Mg2+ in the subsoil increased respectively by 54% and 141% after surface application of 10 t ha-1 AS. The decrease of soil active Al and increase of base cations in subsoil were mainly attributed to the high migration capacity of base cations in AS. In conclusion, the effect of surface application of AS was superior to BA in ameliorating soil acidity and alleviating soil Al toxicity in the subsoil of this Ultisol.

Paper mill sludge (PMS) is a residual biomass that is generated at paper mills in large quantities. Currently, PMS is commonly disposed in landfills, which causes environmental issues through chemical leaching and greenhouse gas production. In this research, we are exploring the potential of fast pyrolysis process for converting PMS into useful bio-oil and biochar products. We demonstrate that by subjecting PMS to a combination of acid hydrolysis and torrefaction pre-treatment processes it is possible to alter the physicochemical properties and composition of the feedstock material. Fast pyrolysis of pretreated PMS produced bio-oil with significantly higher selectivity to levoglucosenone and significantly reduced the amount of ketone, aldehyde, and organic acid components. Pretreatment of PMS with combined 4% mass fraction phosphoric acid hydrolysis and 220 °C torrefaction processed prior to fast pyrolysis resulted in a 17 times increase of relative selectivity towards levoglucosenone in bio-oil product along with a reduction of acids, ketones, and aldehydes combined from 21 % to 11 %. Biochar, produced in higher yield, has characteristics that potentially make the solid byproduct ideal for soil amendment agent or sorbent material. This work reveals a promising process system to convert PMS waste into useful bio-based products. More in-depth research is required to gather more data information for assessing the economic and sustainability aspects of the process.

Seagrass systems of the Western Pacific region are biodiverse habitats, providing vital services to ecosystems and humans over a vast geographic range. SeagrassNet is a worldwide monitoring program that collects data on seagrass habitats, including the ten locations across the Western Pacific reported here where change at various scales was rapidly detected. Three sites remote from human influence were stable. Seagrasses declined largely due to increased nutrient loading (4 sites) and increased sedimentation (3 sites), the two most common stressors of seagrass worldwide. Two sites experienced near-total loss from of excess sedimentation, followed by partial recovery once sedimentation was reduced. Species shifts were observed at every site with recovering sites colonized by pioneer species. Regulation of watersheds is essential if marine protected areas are to preserve seagrass meadows. Seagrasses in the Western Pacific experience stress due to human impacts despite the vastness of the ocean area and low development pressures.

Abstract The Chinese government has taken measures to realize energy-savings and emission reductions, such as promoting innovations, adjusting the industrial structure, balancing regional development, and reforming markets. The aim of this paper is to assess the effects of these measures on China's CO2 emissions by using a newly proposed decomposition approach, which identified eight new factors related to the above realistic measures, i.e., energy saving and production technologies, industrial energy and production efficiencies, regional energy and production efficiencies, and pure energy and production efficiencies. The main findings indicate benefits from considerable technological progress in energy-saving and production during 2000–2016 period, and two technological factors contributed the most to emissions abatement and cumulatively reduced 5372.43 Mt and 1291.72 Mt CO2 emissions. The efforts of industrial restructuring promoted energy and production efficiency improvement, which further facilitated emission reduction. In contrast, the pure energy and production efficiency changes cumulatively led to 1080.26 Mt and 1135.85 Mt CO2 emissions growth during the whole sample period, suggesting that severe resource misallocation problems may exist in both the energy market and output market. Additionally, the Chinese government failed to narrow the technology gap between developed regions and underdeveloped regions, further restricting emission reduction.

This study focused on the effects of plant compositions on removal rates of pollutants in microcosms through investigating rhizosphere microbial populations, photosynthetic efficiency and growth characteristics. Mixed-culture groups improved the removal efficiency of TN and TP significantly but exhibited lower COD removal rates. Total plant biomasses were improved as the species richness increased, but the N/P content in the plants was mainly affected by the type of species. The mixed-culture groups showed lower photosynthesis rates and oxygen supply generated from roots under high irradiation. Microbial communities of the cultured groups in the rhizosphere exhibited significant differences. According to principal component analysis (PCA), the fungi were the typical microbes of SPA, SPAB, and SPABC, resulted in improvement in nutrient accumulation. These results demonstrated that a mixed culture strategy can represent the overyielding of biomass, promote the photo-protection mechanism, and will further increase the removal rates of pollutants in a constructed wetland.

Yard waste is either dumped or is being openly burned to get rid of it, instead of using it as a valuable renewable energy source. In this study, hydrothermal carbonization of yard waste was conducted to valorize it as a solid bio fuel, using a batch reactor. The effect of process parameter on yield, energy and physicochemical properties of the valorized solid bio fuel (hydrochar) was examined in this study by varying reaction temperature (160-200 °C for 2 h) and reaction time (2-24 h at 200 °C). The calorific value of hydrochar was within a range of 17.72-24.59 MJ/kg as compared to 15.37 MJ/kg for untreated yard waste. Hydrochar mass yield decreased from 78.6% at operating temperature - time of 160 °C -2 h to 45.6% at 200 °C -24 h. The plot of atomic ratios (H/C and O/C) demonstrates improvement in the coalification process which was mainly governed by decarboxylation and dehydration reactions. The grindability of the prepared hydrochar was comparable to that of coal. Hydrochar produced at lower reaction condition (160-200 °C at 2 h) have better flowability as compared to that produced at higher reaction condition (4-24 h at 200 °C). The reaction time longer than 12 h has a minimal effect on the yield, energy and physicochemical properties of hydrochar. Increasing reaction time and temperature improved the ignition and burnt temperature of hydrochar. All reaction condition has an energy ratio (energy output to energy input) of more than one making HTC process a net energy producer.

Net primary production (NPP), the difference between CO2 fixed by photosynthesis and CO2 lost to autotrophic respiration, is one of the most important components of the carbon cycle. Our goal was to develop a simple regression model to estimate global NPP using climate and land cover data. Approximately 5600 global data points with observed mean annual NPP, land cover class, precipitation, and temperature were compiled. Precipitation was better correlated with NPP than temperature, and it explained much more of the variability in mean annual NPP for grass- or shrub-dominated systems (r2 = 0.68) than for tree-dominated systems (r2 = 0.39). For a given precipitation level, tree-dominated systems had significantly higher NPP (approximately 100-150 g C m(-2) yr(-1)) than non-tree-dominated systems. Consequently, previous empirical models developed to predict NPP based on precipitation and temperature (e.g., the Miami model) tended to overestimate NPP for non-tree-dominated systems. Our new model developed at the National Center for Ecological Analysis and Synthesis (the NCEAS model) predicts NPP for tree-dominated systems based on precipitation and temperature; but for non-tree-dominated systems NPP is solely a function of precipitation because including a temperature function increased model error for these systems. Lower NPP in non-tree-dominated systems is likely related to decreased water and nutrient use efficiency and higher nutrient loss rates from more frequent fire disturbances. Late 20th century aboveground and total NPP for global potential native vegetation using the NCEAS model are estimated to be approximately 28 Pg and approximately 46 Pg C/yr, respectively. The NCEAS model estimated an approximately 13% increase in global total NPP for potential vegetation from 1901 to 2000 based on changing precipitation and temperature patterns.

A brief review of energy use patterns in three economic sectors; namely, residential, industrial and transport sectors is provided in this paper. The transport sector is the largest energy-consuming sector in Thailand, followed by the industrial and residential sectors, respectively. In order to reduce both imported energy and environmental emissions, energy conservation programs would be implemented. This paper forecasts the growth in energy demand and corresponding emissions to the year 2020 for those three sectors by using a model based on the end-use approach. The energy savings from the energy conservation strategies, such as energy efficiency improvement and energy demand management, are assessed and also the implications on electricity generation expansion planning are examined. The integrated resource planning (IRP) model is used to find the least-cost electricity generation expansion plans. Energy conservation options, including energy efficiency improvement programs, are introduced in the residential and industrial sectors. Public transportation and engine technology improvements are introduced in the transport sector. The effects of energy conservation options are analyzed using a scenario-based approach. The results of analysis reveal that the improvement of public transportation can reduce future energy requirements and CO2 emissions in 2020 by 635 thousand ton of oil equivalent (toe) and 2024 thousand ton of CO2 equivalent, respectively. If all options are simultaneously implemented, the potential of energy savings and CO2 mitigation in 2020 are estimated to be 1240 thousand toe and 3622 thousand ton of CO2 equivalent, respectively.