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During the late Paleozoic ice age, tropical coastal depositions have been widely linked to high-frequency sea-level variations, but their linkage with the associated climate change was not fully understood. In the early Permian, two deglaciations occurred in the late Sakmarian and late Artinskian, respectively. During the late Artinskian deglacial warming and transgression, coal-bearing siliciclastic successions of the Liangshan Formation were developed in South China. Three facies associations were recognized from the Liangshan Formation successions in western South China and ascribed to coastal alluvial plain, estuarine, and deltaic environments. Detailed analysis of sedimentology, paleosol morphology, and sandstone petrology suggest a relatively dry-to-wet climate shift and estuarine to deltaic facies transition in the lower Liangshan Formation. This climate shift and facies transition can be temporally correlated based on regional stratigraphic correlations, although precise age constraints are needed to test this correlation. The estuarine interval of the lowest Liangshan Formation signified a rapid transgression during the late Artinskian deglaciation and likely formed during a relatively arid climate with locally small fluvial systems, which provided limited sediment supply. The subsequent transition to and initiation of deltaic deposition was broadly associated with the inferred climate shift and could be primarily resulted from a climate wetting-induced great increase in sediment supply, irrespective of the deglacial sea-level rise.

During the late Paleozoic ice age, tropical coastal depositions have been widely linked to high-frequency sea-level variations, but their linkage with the associated climate change was not fully understood. In the early Permian, two deglaciations occurred in the late Sakmarian and late Artinskian, respectively. During the late Artinskian deglacial warming and transgression, coal-bearing siliciclastic successions of the Liangshan Formation were developed in South China. Three facies associations were recognized from the Liangshan Formation successions in western South China and ascribed to coastal alluvial plain, estuarine, and deltaic environments. Detailed analysis of sedimentology, paleosol morphology, and sandstone petrology suggest a relatively dry-to-wet climate shift and estuarine to deltaic facies transition in the lower Liangshan Formation. This climate shift and facies transition can be temporally correlated based on regional stratigraphic correlations, although precise age constraints are needed to test this correlation. The estuarine interval of the lowest Liangshan Formation signified a rapid transgression during the late Artinskian deglaciation and likely formed during a relatively arid climate with locally small fluvial systems, which provided limited sediment supply. The subsequent transition to and initiation of deltaic deposition was broadly associated with the inferred climate shift and could be primarily resulted from a climate wetting-induced great increase in sediment supply, irrespective of the deglacial sea-level rise.

Climate warming is the greatest future challenge to the hydrosphere and the human community, especially in arid and semiarid regions. This study took the Golmud river watershed on the Tibetan Plateau as an example to numerically identify the development of groundwater flow systems in a large arid sedimentary basin and explore what would the dramatic climate warming pose on groundwater flow system. The numerical results show that the Golmud river watershed has developed three hierarchical groundwater flow systems. River seepage is the predominant recharge for the groundwater systems inside the basin. The local groundwater flow system discharges some 82.69% of all groundwater in the basin, followed by the intermediate system with 14.26% and the regional system with 3.05%. The local system is mainly distributed in the shallow area of the alluvial-pluvial fan at the piedmont and provides the dominant water resource for human exploitation and oasis ecological usages. Climate warming would increase about 30.78% of the quantity of the recharge water to the groundwater system inside the basin via river seepage due to the increasing precipitation and increased glacier melt in the headwater region of the watershed. These waters would pose disturbances to all groundwater flow systems but to different degrees. The local flow system exhibits the largest response to the climate warming with more than 90% of increased water cycled in and discharged through it. The significant groundwater level rising leads to the trailing edge of the overflow belt at the piedmont moving ∼5 km towards to the mountain pass, which would potentially pose a water disaster to the local region. The influences of climate warming on the intermediate and regional flow system are relatively limited. This study provides a preliminary understanding of the influences of climate warming on the groundwater flow systems in arid endorheic basins and is essential for tackling future climate change challenges faced by arid and semiarid regions.

Climate warming is the greatest future challenge to the hydrosphere and the human community, especially in arid and semiarid regions. This study took the Golmud river watershed on the Tibetan Plateau as an example to numerically identify the development of groundwater flow systems in a large arid sedimentary basin and explore what would the dramatic climate warming pose on groundwater flow system. The numerical results show that the Golmud river watershed has developed three hierarchical groundwater flow systems. River seepage is the predominant recharge for the groundwater systems inside the basin. The local groundwater flow system discharges some 82.69% of all groundwater in the basin, followed by the intermediate system with 14.26% and the regional system with 3.05%. The local system is mainly distributed in the shallow area of the alluvial-pluvial fan at the piedmont and provides the dominant water resource for human exploitation and oasis ecological usages. Climate warming would increase about 30.78% of the quantity of the recharge water to the groundwater system inside the basin via river seepage due to the increasing precipitation and increased glacier melt in the headwater region of the watershed. These waters would pose disturbances to all groundwater flow systems but to different degrees. The local flow system exhibits the largest response to the climate warming with more than 90% of increased water cycled in and discharged through it. The significant groundwater level rising leads to the trailing edge of the overflow belt at the piedmont moving ∼5 km towards to the mountain pass, which would potentially pose a water disaster to the local region. The influences of climate warming on the intermediate and regional flow system are relatively limited. This study provides a preliminary understanding of the influences of climate warming on the groundwater flow systems in arid endorheic basins and is essential for tackling future climate change challenges faced by arid and semiarid regions.

Single ion conducting gel polymer electrolytes (GPEs) are characterized as having a certain amount of ionic liquid or solvent incorporated into a single ion-conducting polymer matrix and may afford the advantages of high conductivity and low electrolyte polarization under battery operation. Single ion conducting polymers often suffer from low conductivity due to their reliance on polymer segmental motion to achieve sufficient ion mobility. However, by incorporating specific solvents into a single ion conducting matrix, mobility of the polymer can be enhanced while still maintaining the advantages of single ion conduction. Although many of the solvents used to swell GPEs are mixtures of flammable organic solvents (such as dimethyl carbonate), there are many potential non-reactive, low vapor pressure solvents that could effectively solvate alkali-ion based GPEs and plasticize the polymer matrix to enhance ion conductivity. Adipate-based solvents are a group of non-volatile plasticizers with low viscosities and low vapor pressures at room temperature derived from adipic acid. The ester groups in these solvents may effectively solvate alkali ions such as Na+, leading to higher conductivity, while circumventing issues of flammability found in current alkali-ion conducting electrolytes. This study investigates the properties of sodium-ion conducting GPEs that have been swollen with varying adipate-based solvents and the subsequent dielectric response from the solvent addition. Dielectric relaxation spectroscopy was used to characterize the Na+ conductivity, static dielectric constant, ion-conducting content, and mobility of the membranes before and after the non-volatile solvent uptake. Understanding this relationship will pave the path toward safer, more efficient solid-state polymer electrolytes for battery applications.

Single ion conducting gel polymer electrolytes (GPEs) are characterized as having a certain amount of ionic liquid or solvent incorporated into a single ion-conducting polymer matrix and may afford the advantages of high conductivity and low electrolyte polarization under battery operation. Single ion conducting polymers often suffer from low conductivity due to their reliance on polymer segmental motion to achieve sufficient ion mobility. However, by incorporating specific solvents into a single ion conducting matrix, mobility of the polymer can be enhanced while still maintaining the advantages of single ion conduction. Although many of the solvents used to swell GPEs are mixtures of flammable organic solvents (such as dimethyl carbonate), there are many potential non-reactive, low vapor pressure solvents that could effectively solvate alkali-ion based GPEs and plasticize the polymer matrix to enhance ion conductivity. Adipate-based solvents are a group of non-volatile plasticizers with low viscosities and low vapor pressures at room temperature derived from adipic acid. The ester groups in these solvents may effectively solvate alkali ions such as Na+, leading to higher conductivity, while circumventing issues of flammability found in current alkali-ion conducting electrolytes. This study investigates the properties of sodium-ion conducting GPEs that have been swollen with varying adipate-based solvents and the subsequent dielectric response from the solvent addition. Dielectric relaxation spectroscopy was used to characterize the Na+ conductivity, static dielectric constant, ion-conducting content, and mobility of the membranes before and after the non-volatile solvent uptake. Understanding this relationship will pave the path toward safer, more efficient solid-state polymer electrolytes for battery applications.

Efforts in Disaster Risk Reduction (DRR) are widely geared towards integrating indigenous knowledge and science. Several conceptual frameworks have thus evolved towards co-creating knowledge and co-designing DRR measures from the standpoint of the communities-at-risk. This is claimed to foster optimization and sustainability of measures. This study tests the effectiveness of this standpoint argument based on the case of floods in the Rwenzori, western Uganda, where a mismatch is noted between research, policy, and action. A protocol was developed to stimulate dialogue on knowledge co-creation and co-designing of DRR measures among participants from three stakeholder groups: scientists, policymakers, and communities-at-risk. Beyond convergence on some measures among participants, equitable deliberations were observed among the different stakeholders. This enabled three processes: coalescing some of the proposed measures, the emergence of hybrid worldviews, and co-design of alternative options. The co-designed options fall within the contemporary conceptualization of nature-based solutions and sustainability. This meant that they are adoptable and optimizable over time by communities-at-risk. This constructive knowledge integration and co-design of DRR options were favored by three attributes: coalescing overlaps in theorizations of processes, embracing diversity in ontological values, and self-critiques among policymakers. Lessons are drawn on how these attributes facilitate bridging gaps between science, policy, and action in DRR.

Efforts in Disaster Risk Reduction (DRR) are widely geared towards integrating indigenous knowledge and science. Several conceptual frameworks have thus evolved towards co-creating knowledge and co-designing DRR measures from the standpoint of the communities-at-risk. This is claimed to foster optimization and sustainability of measures. This study tests the effectiveness of this standpoint argument based on the case of floods in the Rwenzori, western Uganda, where a mismatch is noted between research, policy, and action. A protocol was developed to stimulate dialogue on knowledge co-creation and co-designing of DRR measures among participants from three stakeholder groups: scientists, policymakers, and communities-at-risk. Beyond convergence on some measures among participants, equitable deliberations were observed among the different stakeholders. This enabled three processes: coalescing some of the proposed measures, the emergence of hybrid worldviews, and co-design of alternative options. The co-designed options fall within the contemporary conceptualization of nature-based solutions and sustainability. This meant that they are adoptable and optimizable over time by communities-at-risk. This constructive knowledge integration and co-design of DRR options were favored by three attributes: coalescing overlaps in theorizations of processes, embracing diversity in ontological values, and self-critiques among policymakers. Lessons are drawn on how these attributes facilitate bridging gaps between science, policy, and action in DRR.