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Abstract In this paper, energy and exergy analyses of the geothermal-based hydrogen production via thermochemical water decomposition using a new, four-step copper–chlorine (Cu–Cl) cycle are conducted, and the respective cycle energy and exergy efficiencies are examined. Also, a parametric study is performed to investigate how each step of the cycle and its overall cycle performance are affected by reference environment temperatures, reaction temperatures, as well as energy efficiency of the geothermal power plant itself. As a result, overall energy and exergy efficiencies of the cycle are found to be 21.67% and 19.35%, respectively, for a reference case.

As climate change moves insect systems into uncharted territory, more knowledge about insect dynamics and the factors that drive them could enable us to better manage and conserve insect communities. Climate change may also require us to revisit insect management goals and strategies and lead to a new kind of scientific engagement in management decision-making. Here we make five key points about the role of insect science in aiding and crafting management decisions, and we illustrate those points with the monarch butterfly and the Karner blue butterfly, two species undergoing considerable change and facing new management dilemmas. Insect biology has a strong history of engagement in applied problems, and as the impacts of climate change increase, a reimagined ethic of entomology in service of broader society may emerge. We hope to motivate insect biologists to contribute time and effort toward solving the challenges of climate change.

Abstract Dolomite, a naturally occurring Ca-based sorbent, shows superior recycling stability in carbonation/calcination cycles for CO2 capture. However, the separation between Ca and Mg in sorbent during recycling weakens the resistance for sintering from MgO, leading to a drastic reduction in the CO2 carrying activity (spent sorbent). This paper presents a novel method for the reactivation of spent dolomite sorbents. Notable activity recovery is achieved by ball milling of the spent sorbent with H2O and dry ice. Powder X-ray diffraction (XRD) results confirm the transformation from oxide (CaO/MgO) to carbonate (CaCO3/CaMg(CO3)2), so that the segregated Ca and Mg in spent sorbent are re-mixed at the atomic level, which is mainly responsible for this effective reactivation. Water plays an irreplaceable role in this process by providing a liquid environment to accelerate the diffusion of the reactants and ionic reactions. In addition, thermogravimetric analysis was carried out on a series of samples with different ball-milling times to determine the suitable reactivation conditions for CO2 capture.

Abstract Hydrogen is considered a potential game changer for world energy systems and a solution to climate change concerns, as it generates zero waste and it is suited for power generation and transportation. Despite its several advantages, there are significant technical challenges in deploying a stable hydrogen economy including improving its process efficiencies, lowering production costs, maintaining cost-effective transmission and distribution, and exploiting inexpensive and sustainable feedstocks. In this context, a detailed study was conducted to analyze the production sources, technologies, storage and transport systems, and global potential exportable feedstocks to produce hydrogen. A comprehensive analysis of current hydrogen production technologies with their energy efficiencies and hydrogen selling prices was reported in this study. Various hydrogen production technologies with their capital investments and CO2 emissions were also presented. Potential feedstocks for hydrogen production were identified and analyzed through a product space model, which characterizes a network of global exportable products based on their similarities and productive knowledge. It was established that the hydrogen production feedstocks and sources currently used are primarily available in six countries: the United States of America, France, Russia, Sweden, the Netherlands, and Spain. Broadly, the results revealed that the United States of America and Russia shared the highest hydrogen feedstock exports, indicating a higher probability of hydrogen production in these countries. Except for Russia, all the studied countries fell in the most desired quadrant, indicating that they can move in all product space directions to exploit unexplored hydrogen feedstocks for better sustainable economic growth.

This work was aimed to comprehensively evaluate the potential for sustainable development of China's shale gas industry. It will contribute to the sustainable development of China's energy and economic. Factors of resource, technology, economy and environment were selected to develop the DPSIR framework evaluation indicators in system for shale gas based on the previous research. Next, The PPFCI (projection pursuit fuzzy clustering model) technique was developed by combining the projection pursuit model with a fuzzy clustering iterative model. So that it can deal with the multi-source, high-dimensional, fuzzy data of the proposed evaluation indicators. And then, the RAGA (accelerated genetic algorithm based on real coding) algorithm was developed to run the PPFCI technique. The results show that core technical capability, investment in projects of prevention of geological disasters, and ecological environment damage indicators were the key factors affecting the sustainability of China's shale gas industry. The potential for sustainable development of China's shale gas industry was relatively low. And it was unbalanced in different provinces. The potential for sustainable development of the southwest region was better than the northwest region. Among them, the development of Sichuan was more stable than Chongqing, with a 99% probability of maintaining a stable and sustainable development state, while Chongqing province has a 15%-20% probability to fluctuate towards the poles.

It has long been established that mature forests are mosaics of patches in different development phases but it has seldom explicitly been taken into account in ecological studies. We demonstrate here that these development phases, which are related to the population dynamics of trees, play an important role in the distribution of fauna based on observations on frugivorous birds. In an area close to the Calakmul Biosphere Reserve in Mexico, we studied the abundance of large forest bird species in relation to forest development phases, with a methodology that seems promising for ecological diagnosis and prognosis in forest management planning. Fine-scale forest mapping and bird counts were carried out in two block-transects of 40 m x 3000 m. Tree sampling in a sub-transect was used to generate population characteristics of trees, Large bird species preferred mature or senescent forest patches, whereas relatively young, growing forest patches were avoided. Important large tree species such as Manilkara zapota, Thouinia paucidentata, Guaiacum sanctum and Esenbeckia pentaphylla, characteristic of older forest patches, showed skewed size distributions indicating stress or overexploitation. The population of M. zapota, a key fruiting species that accounted for 26.5% of the total woody biomass, was most heavily affected by stress. A future collapse in the population of M. zapota, a decrease of the total area of older forest, and a decline in the abundance of large birds is likely if stress on the system continues at this level. (C) 2008 Elsevier B.V. All rights reserved.

AbstractThe change in the phenology of plants or animals reflects the response of living systems to climate change. Numerous studies have reported a consistent earlier spring phenophases in many parts of middle and high latitudes reflecting increasing temperatures with the exception of China. A systematic analysis of Chinese phenological response could complement the assessment of climate change impact for the whole Northern Hemisphere. Here, we analyze 1263 phenological time series (1960–2011, with 20+ years data) of 112 species extracted from 48 studies across 145 sites in China. Taxonomic groups include trees, shrubs, herbs, birds, amphibians and insects. Results demonstrate that 90.8% of the spring/summer phenophases time series show earlier trends and 69.0% of the autumn phenophases records show later trends. For spring/summer phenophases, the mean advance across all the taxonomic groups was 2.75 days decade−1 ranging between 2.11 and 6.11 days decade−1 for insects and amphibians, respectively. Herbs and amphibians show significantly stronger advancement than trees, shrubs and insect. The response of phenophases of different taxonomic groups in autumn is more complex: trees, shrubs, herbs and insects show a delay between 1.93 and 4.84 days decade−1, while other groups reveal an advancement ranging from 1.10 to 2.11 days decade−1. For woody plants (including trees and shrubs), the stronger shifts toward earlier spring/summer were detected from the data series starting from more recent decades (1980s–2000s). The geographic factors (latitude, longitude and altitude) could only explain 9% and 3% of the overall variance in spring/summer and autumn phenological trends, respectively. The rate of change in spring/summer phenophase of woody plants (1960s–2000s) generally matches measured local warming across 49 sites in China (R = −0.33, P < 0.05).

Abstract Natural gas vehicles offer the benefits of reducing oil use, CO2 emissions and air pollutants. Promoting the use of natural gas vehicles is considered as one of the most important strategies towards sustainable transportation. China made remarkable progress in promoting natural gas vehicles over recent years, and its 4.6 million natural gas vehicles in 2014 represented the world׳s largest natural gas vehicle fleet. In this paper, the development of natural gas vehicles in China is reviewed based on a triple-perspective (Fuel-Vehicle-Infrastructure) technical–economical framework. The review indicates that (a) pricing of vehicle-use Compressed Natural Gas (CNG) and Liquefied Natural Gas (LNG) is essential in determining natural gas vehicle development. A pricing principle similar to the fixed CNG/gasoline price ratio (0.75:1) should be applied to LNG/diesel price ratio; (b) for CNG passenger vehicles, the modified CNG vehicles, with ¥3000–5000 additional cost, is more attractive to consumers than originally manufactured CNG vehicles, with about ¥10,000 additional cost. Vehicle retrofit should be permitted by the government with the precondition that retrofit standards are strictly enforced; (c) for CNG/LNG transit buses, the deployment is strongly affected by local government׳s preference. In regions with sufficient natural gas supply, the government should prioritize the deployment of CNG/LNG transit buses rather than other technologies; (d) for LNG commercial vehicles, with ¥60,000–80,000 higher cost than their counterpart diesel vehicles, financial incentive is critical for their development. China׳s current vehicle subsidy scheme should be extended to cover LNG commercial vehicles; (e) regarding refueling infrastructures, interference with urban land-use planning and long-time administrative approval are the major barriers. Local governments should launch dedicated plans and strategies to support the further deployment of CNG/LNG refueling infrastructures.

The influence of compost on the growth of bean plants irrigated with As-contaminated waters and its influence on the mobility of As in the soils and the uptake of As (as NaAs(III)O2) by plant components was studied at various compost application rates (3·10(4) and 6·10(4) kg ha(-1)) and at three As concentrations (1, 2 and 3 mg kg(-1)). The biomass and As and P concentrations of the roots, shoots and beans were determined at harvest time, as well as the chlorophyll content of the leaves and nonspecific and specifically bound As in the soil. The bean plants exposed to As showed typical phytotoxicity symptoms; no plants however died over the study. The biomass of the bean plants increased with the increasing amounts of compost added to the soil, attributed to the phytonutritive capacity of compost. Biomass decreased with increasing As concentrations, however, the reduction in the biomass was significantly lower with the addition of compost, indicating that the As phytotoxicity was alleviated by the compost. For the same As concentration, the As content of the roots, shoots and beans decreased with increasing compost added compared to the Control. This is due to partial immobilization of the As by the organic functional groups on the compost, either directly or through cation bridging. Most of the As adsorbed by the bean plants accumulated in the roots, while a scant allocation of As occurred in the beans. Hence, the addition of compost to soils could be used as an effective means to limit As accumulation in crops from As-contaminated waters.