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The effect of the combined application of nano-hydroxyapatite (NHAP) or nano-carbon black (NCB) on the phytoextraction of Pb by ryegrass was investigated as an enhanced remediation technique for soils by field-scale experiment. After the addition of 0.2% NHAP or NCB to the soil, temporal variation of the uptake of Pb in aboveground parts and roots were observed. Ryegrass shoot concentrations of Pb were lower with nano-materials application than without nano-materials for the first month. However, the shoot concentrations of Pb were significantly increased with nano-materials application, in particular NHAP groups. The ryegrass root concentrations of Pb were lower with nano-materials application for the first month. These results indicated that nano-materials had significant effects on stabilization of lead, especially at the beginning of the experiment. Along with the experimental proceeding, phytotoxicity was alleviated after the incorporation of nano-materials. The ryegrass biomass was significantly higher with nano-materials application. Consequently, the Pb phytoextraction potential of ryegrass significantly increased with nano-materials application compared to the gounps without nano-materials application. The total removal rates of soil Pb were higher after combined application of NHAP than NCB. NHAP is more suitable than NCB for in-situ remediation of Pb-contaminated soils. The ryegrass translocation factor exhibited a marked increase with time. It was thought that the major role of NHP and NBA might be to alleviate the Pb phytotoxicity and increase biomass of plants.

Abstract This study investigates the possibility of using and developing hydrokinetic power to supply reliable, affordable and sustainable electricity to rural, remote and isolated loads in rural South Africa where reasonable water resource is available. Simulations are performed using the Hybrid Optimization Model for Electric Renewable (HOMER) and the results are compared to those from other supply options such as standalone Photovoltaic system (PV), wind, diesel generator (DG) and grid extension. Finally the paper points out some major challenges that are facing the development of this technology in South Africa.

Abstract Day-ahead forecasts of direct normal irradiance (DNI) from the Integrated Forecasting System (IFS), the global model of the European Centre for Medium-Range Weather Forecasts (ECMWF), are used to simulate a concentrating solar power (CSP) plant through the System Advisor Model (SAM) to assess the potential value of the IFS in the electricity market. Although DNI forecasting from the IFS still demands advances towards cloud and aerosol representation, present results show substantial improvements with the new operational radiative scheme ecRad (cycle 43R3). A relative difference of approximately 0.12% for the total annual energy availability is found between forecasts and local measurements, while approximately 10.6% is obtained for the previous version. Results of electric energy injection to the grid from a simulated linear focus parabolic-trough system shows correlations coefficients of approximately 0.87 between hourly values of electric energy based on forecasted and measured DNI, while 0.92 are obtained for the daily values. In the context of control strategy, four operational strategies are given for different weather scenarios to handle the energy management of a CSP plant, including the effect of thermal energy storage capacity. Charge and discharge operational strategies are applied accordingly to the predicted energy availability.

To assess the sustainability of waste management scenario with energy recovery, it is necessary to carry out an adequate analysis of all influential criteria. The main problem in the analysis is to determine the indicators that clearly and fully sublimate the most important influential factors. The model for the assessment of the sustainability of waste treatment scenarios based on multi-criteria analysis AHP (analytic hierarchy process) method is developed. The model predicts an increase in the number of indicators, if it found that a selected number of indicators are not sufficient to distinguish between scenarios and new criterion for the selection of indicators: the relevance of the indicator for certain waste treatment. The model is verified in the case study the city of Nis. Four scenarios were selected and examined: business as usual scenario (landfilling of waste) and the other are created as scenarios with energy recovery and recourses preserving: composting organic waste with recycling inorganic waste, incineration of waste and anaerobic digestion of waste. The assessment of the sustainability of waste treatment scenarios was made in several steps. It is found that the best sustainable scenario is composting of organic and recycling of inorganic waste.

Crop cultivation in greenhouses under semi-arid climatic conditions is subject to various stresses, in particular during the winter season at night, when the interior air is poorly controlled, leading to prolonged periods of low temperature. The aim is then to evaluate and control the heat exchanges of the enclosure in order to prevent low indoor air temperatures and reduce the thermal load of the greenhouse. The objectives of this study are to investigate the convective and radiative heat exchanges at the cover in order to establish new correlations for the convective heat transfer coefficients in semi arid regions. The climatic parameters were measured inside and outside a closed empty glasshouse without crop, for three different nights during the winter season in the semi-arid land of Algeria. A physical model for analysing the convective heat transfers was implemented, and new correlations were established, parameterised, calibrated and validated thoroughly. A significant difference was observed between the correlations obtained by this study and the models obtained for other greenhouse designs under different climatic conditions. Results show that the convection mode along the inside wall of the cover is free turbulent. Conversely, the convection mode along the outside greenhouse cover remains forced turbulent. A consistent performance of the correlations was observed, both in the calibration and validation stages.

Photoprotective mechanisms of cyanobacteria are characterized by several features associated with the structure of their water-soluble antenna complexes - the phycobilisomes (PBs). During energy transfer from PBs to chlorophyll of photosystem reaction centers, the "energy funnel" principle is realized, which regulates energy flux due to the specialized interaction of the PBs core with a quenching molecule capable of effectively dissipating electron excitation energy into heat. The role of the quencher is performed by ketocarotenoid within the photoactive orange carotenoid protein (OCP), which is also a sensor for light flux. At a high level of insolation, OCP is reversibly photoactivated, and this is accompanied by a significant change in its structure and spectral characteristics. Such conformational changes open the possibility for protein-protein interactions between OCP and the PBs core (i.e., activation of photoprotection mechanisms) or the fluorescence recovery protein. Even though OCP was discovered in 1981, little was known about the conformation of its active form until recently, as well as about the properties of homologs of its N and C domains. Studies carried out during recent years have made a breakthrough in understanding of the structural-functional organization of OCP and have enabled discovery of new aspects of the regulation of photoprotection processes in cyanobacteria. This review focuses on aspects of protein-protein interactions between the main participants of photoprotection reactions and on certain properties of representatives of newly discovered families of OCP homologs.

Abstract Improvement of the quantitative performance characterization of photovoltaic (PV) strings was investigated, based on their monitoring data during maximum power point tracking (MPPT) operation. The maximum power voltage Vmp and current Imp of the PV strings under MPPT were continuously monitored, and corrected to standard temperature of 25 °C by using the temperature correction formulas, which were recently developed for PV modules. The irradiance G was measured by using a PV module irradiance sensor. It was verified that the formulas are applicable to PV strings, enabling reproducible temperature correction of Vmp and Imp with relative standard deviation (σ) of about 0.4–0.9% under various weather conditions. Comparison of the outdoor results with indoor current–voltage curve measurements of the constituent modules in the strings showed that the maximum output power Pmax under the standard test conditions STC, i.e. 25 °C and 1 kWm−2, estimated from the temperature-corrected Vmp and Imp, agreed with the indoor result typically within ±1.5%. The experimental results also showed that other information of the string such as partial shading and activation of bypass diodes can be also sensitively detected by analyzing the temperature-corrected Vmp and Imp. The outdoor measurements and data analysis of this study can be carried out without stopping the MPPT operation of the string. The analysis is performed by using the real-time data. The present method is expected to be applicable to most kinds of crystalline silicon PV strings without modification.